JP3384507B2 - Processing method of mirror material with micro holes - Google Patents
Processing method of mirror material with micro holesInfo
- Publication number
- JP3384507B2 JP3384507B2 JP06180694A JP6180694A JP3384507B2 JP 3384507 B2 JP3384507 B2 JP 3384507B2 JP 06180694 A JP06180694 A JP 06180694A JP 6180694 A JP6180694 A JP 6180694A JP 3384507 B2 JP3384507 B2 JP 3384507B2
- Authority
- JP
- Japan
- Prior art keywords
- holes
- mirror
- mirror surface
- large number
- processing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Metal Rolling (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
- Welding Or Cutting Using Electron Beams (AREA)
Description
【0001】[0001]
【産業上の利用分野】本発明は、微細穴を有する鏡面材
の加工法とこれに用いる圧延ロールに係わり、更に詳し
くは、プレス加工における潤滑性が良く、かつ見掛け上
は鏡面であるが規則正しい微細な凹孔を有する鏡面材の
加工方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for processing a mirror-finished material having fine holes and a rolling roll used for the same. More specifically, it has good lubricity in press working and has a regular but apparently mirror surface. The present invention relates to a method for processing a mirror surface material having fine concave holes.
【0002】[0002]
【従来の技術】自動車ボディの外板や家庭電気製品の外
装板などの成形加工に用いられる薄板材(例えば鋼板)
では、特に塗装面の乱反射が少なく光沢性に優れている
こと、および写像の歪みが少なく写像性に優れているこ
とが重要であり、これらの光沢性と写像性をあわせて一
般に鮮映性と称している。2. Description of the Related Art Thin plate materials (for example, steel plates) used for forming outer plates of automobile bodies and exterior plates of household electric appliances.
In particular, it is important that the diffused reflection on the painted surface is small and the gloss is excellent, and the distortion of the image is small and the image clarity is excellent. I am calling it.
【0003】従来、プレス成形時における耐焼付性等を
向上させるため、ショットブラスト法や放電加工法によ
りダル仕上げされた圧延ロールを用いて鋼板表面に粗面
を形成することが一般的に行われている。しかし、かか
る粗面化処理により鋼板表面は不規則な山と谷で構成さ
れた粗面を呈し、この表面に塗装をおこなっても山と谷
の間に塗膜が形成されるにすぎず水平な塗膜は少なく、
結果として粗面化処理により鮮映性が悪化してしまう問
題点があった。Conventionally, in order to improve seizure resistance and the like during press forming, a rough surface is generally formed on the surface of a steel sheet by using a rolling roll dull-finished by a shot blast method or an electric discharge machining method. ing. However, the roughening treatment causes the steel plate surface to have a rough surface composed of irregular peaks and valleys, and even if painting is performed on this surface, a coating film is only formed between the peaks and valleys and the surface is horizontal. Few coatings,
As a result, there is a problem that the sharpness deteriorates the image clarity.
【0004】かかる問題点を解決するために、レーザー
ビームをチョッパーでパルスビームに変換し、これをレ
ンズを通して回転している圧延ロールの表面に集光し、
ロールの集光部を瞬間的に加熱溶融させて溶融金属のプ
ールを形成し、レーザービームの斜め横から吹き付ける
アシストガスの圧力によって溶融プールを凹状に形成し
て冷却する加工手段が提案され一部で実施されている
(例えば、特開昭62-168602号、特開昭62-2
24405号)。In order to solve such a problem, a laser beam is converted into a pulse beam by a chopper, which is focused through a lens on the surface of a rotating rolling roll,
A processing means has been proposed in which the condensing part of the roll is instantaneously heated and melted to form a pool of molten metal, and the molten pool is formed into a concave shape by the pressure of the assist gas blown obliquely from the side of the laser beam and cooled. (For example, JP-A-62-168602 and JP-A-62-2).
24405).
【0005】[0005]
【発明が解決しようとする課題】しかし、特開昭62-
168602号、特開昭62-224405号の手段で
は、圧延時に有効に作用する突起の形状を十分に制御で
きず、この圧延ロールで表面が鏡面の素材(以下、鏡面
材)を圧延加工すると、潤滑に有効に作用する凹孔が効
率よく形成されない問題点があった。このため、かかる
鏡面材(製品)をプレス加工する際に、鏡面材表面に潤
滑油を保持することが困難であり、プレス加工における
潤滑性が悪い問題点があった。However, Japanese Patent Application Laid-Open No. 62-
No. 168602 and Japanese Patent Laid-Open No. 62-224405 cannot sufficiently control the shape of the protrusion that effectively works during rolling, and when a material having a mirror surface on this rolling roll (hereinafter, mirror surface material) is rolled, There is a problem that the concave holes that effectively act on lubrication are not efficiently formed. Therefore, it is difficult to retain the lubricating oil on the surface of the mirror surface material when the mirror surface material (product) is pressed, and there is a problem of poor lubricity in the press processing.
【0006】本発明はかかる問題点を解決するために創
案されたものである。すなわち、本発明の目的は、プレ
ス加工における潤滑性が良く、かつ鏡面としての優れた
特性(光沢、写像性)を損なうことなく、見掛け上は鏡
面であるが規則正しい微細穴を有する鏡面材の加工法を
提供することにある。The present invention was devised to solve such problems. That is, an object of the present invention is to process a mirror-finished material having good lubricity in press working and not spoiling excellent characteristics as a mirror surface (gloss, image clarity), but having an apparently mirror surface but having regular fine holes. To provide the law.
【0007】[0007]
【課題を解決するための手段】本発明によれば、超硬合
金平面工具(1)の表面に互いに間隔を隔てた多数の微
細な凹孔(2)を形成し、該工具の圧印により圧延ロー
ル(3)の外表面に、前記凹孔に対応し互いに間隔を隔
てた凸部(4)を形成し、該圧延ロールにより鏡面材
(5)を圧延加工して該表面に多数の微細な凹孔を形成
する、ことを特徴とする微細穴を有する鏡面材の加工法
が提供される。According to the present invention, a cemented carbide
A large number of minute recessed holes (2) spaced apart from each other are formed on the surface of the gold flat tool (1), and the outer surface of the rolling roll (3) is spaced from each other corresponding to the recessed holes by the coining of the tool. Forming a convex portion (4) separated from each other and rolling the mirror surface material (5) with the rolling roll to form a large number of fine recessed holes on the surface. Processing methods are provided.
【0008】本発明の好ましい実施例によれば、前記多
数の微細な凹孔(2)を互いに一定の間隔を隔てて独立
に形成し、この凹孔に対応した凸部(4)を形成し、前
記多数の微細な凹孔(6)を互いに一定の間隔を隔てて
独立に形成する。また、前記超硬合金平面工具(1)の
凹孔の形成はイオンビーム加工による。According to a preferred embodiment of the present invention, the large number of minute concave holes (2) are independently formed at regular intervals and the convex portions (4) corresponding to the concave holes are formed. The plurality of minute recessed holes (6) are independently formed at regular intervals. Further, the formation of the concave hole of the cemented carbide flat tool (1) is performed by ion beam processing.
【0009】[0009]
【作用】上記本発明の方法によれば、圧延ロールの外表
面に、互いに間隔を隔てた多数の微細な凸部(4)が形
成されるので、この圧延ロールにより表面が鏡面の素材
(鏡面材)を圧延加工することにより、鏡面材の表面に
多数の微細な凹孔を形成することができる。従って、か
かる鏡面材(製品)をプレス加工する際に、鏡面材表面
の凹孔に潤滑油を保持することができ、プレス加工にお
ける潤滑性を高めることができる。また、前記多数の微
細な凹孔(2)を互いに一定の間隔を隔てて独立に形成
し、この凹孔に対応した凸部(4)を形成するので、こ
の圧延ロールにより表面が鏡面の素材(鏡面材)を圧延
加工することにより、鏡面材の表面に互いにほぼ一定の
間隔を隔てて独立した多数の微細な凹孔(6)を形成す
ることができる。従って、かかる鏡面材(製品)をプレ
ス加工する際に、鏡面材表面の凹孔(6)に潤滑油を保
持することができ、プレス加工における潤滑性を高める
ことができる。According to the method of the present invention described above, since a large number of minute projections (4) spaced apart from each other are formed on the outer surface of the rolling roll, the rolling roll produces a material having a mirror surface (mirror surface). By rolling the material, a large number of fine concave holes can be formed on the surface of the mirror surface material. Therefore, when the mirror surface material (product) is pressed, the lubricating oil can be retained in the concave hole on the surface of the mirror surface material, and the lubricity in the press processing can be improved. In addition, since the large number of minute concave holes (2) are independently formed at regular intervals and the convex portions (4) corresponding to the concave holes are formed, the material having a mirror-finished surface by the rolling roll. By rolling the (mirror surface material), it is possible to form a large number of minute recesses (6) that are independent of each other at substantially constant intervals on the surface of the mirror surface material. Therefore, when pressing such a mirror surface material (product), the lubricating oil can be retained in the concave hole (6) on the surface of the mirror surface material, and the lubricity in the press processing can be improved.
【0010】また、本発明の好ましい実施例によれば、
イオンビーム加工により超硬合金平面工具に凹孔を形成
し、これを圧印により圧延ロールへ転写し、この圧延ロ
ールにより圧延加工することにより、広い面積の鏡面材
に微細な凹孔(例えば直径、約50μm以下、中心間距
離、約150μm以下)を効率よく形成することができ
る。According to a preferred embodiment of the present invention,
By forming a concave hole in the cemented carbide flat tool by ion beam processing, transfer it to the rolling roll by coining, by rolling with this rolling roll, a minute concave hole (for example, diameter, (About 50 μm or less, center-to-center distance, about 150 μm or less) can be efficiently formed.
【0011】[0011]
【実施例】以下、本発明の好ましい実施例を図面を参照
して説明する。図1は、本発明の微細穴を有する鏡面材
の加工法を模式的に示す図である。図1において、本発
明の方法は、超硬合金平面工具1の表面に互いに間隔を
隔てた多数の微細な凹孔2を形成する第1ステップ10
と、工具1の圧印により圧延ロール3の外表面に、凹孔
2に対応し互いに間隔を隔てた凸部4を形成する第2ス
テップ12と、圧延ロール3により鏡面材5を圧延加工
してその表面に多数の微細な凹孔6を形成する第3ステ
ップ14とからなる。またこの例では、多数の微細な凹
孔2を互いに一定の間隔を隔てて独立に形成し、この凹
孔に対応した凸部4を形成し、多数の微細な凹孔6を互
いに一定の間隔を隔てて独立に形成する。図1の第1ス
テップ10において、超硬合金平面工具1の微細な凹孔
2は、イオンビーム加工により形成される。すなわち、
図1において、真空チャンバー内に超硬合金平面工具1
を保持し、マスク7の微細孔を通してイオンビーム8を
照射する。かかるイオンビーム加工により、イオンビー
ム8の照射位置を原子・分子のオーダで除去加工(イオ
ンスパッタ除去加工)することができ、照射位置が発熱
することなく多数の微細な凹孔2を形成することができ
る。なお、本発明の第1ステップ12は、イオンビーム
加工に限定されるものではなく、電子ビーム加工、レー
ザエッチング等であってもよい。また、超硬合金平面工
具1には、工具鋼のような高硬度の材料(例えばWC-
Co)を用い、表面は予め鏡面加工し、かつ十分な硬化
処理を行っておくのがよい。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT A preferred embodiment of the present invention will be described below with reference to the drawings. FIG. 1 is a diagram schematically showing a method of processing a mirror-finished material having fine holes according to the present invention. Referring to FIG. 1, the method of the present invention includes a first step 10 of forming a large number of minute concave holes 2 spaced from each other on a surface of a cemented carbide flat tool 1.
And a second step 12 of forming convex portions 4 corresponding to the concave holes 2 and spaced apart from each other on the outer surface of the rolling roll 3 by the coining of the tool 1, and the mirror surface material 5 is rolled by the rolling roll 3. The third step 14 of forming a large number of fine recessed holes 6 on the surface thereof. In addition, in this example, a large number of minute concave holes 2 are independently formed with a constant interval therebetween, and a convex portion 4 corresponding to this concave hole is formed, and a large number of minute concave holes 6 are formed at a constant interval. To be formed independently. In the first step 10 of FIG. 1, the minute concave holes 2 of the cemented carbide flat tool 1 are formed by ion beam processing. That is,
In FIG. 1, a cemented carbide flat tool 1 is placed in a vacuum chamber.
And the ion beam 8 is irradiated through the fine holes of the mask 7. By such ion beam processing, the irradiation position of the ion beam 8 can be removed (atomic sputter removal processing) on the order of atoms and molecules, and a large number of minute concave holes 2 can be formed without heat generation at the irradiation position. You can The first step 12 of the present invention is not limited to ion beam processing, but may be electron beam processing, laser etching, or the like. Further, the cemented carbide flat tool 1 is made of a high hardness material such as tool steel (for example, WC-
It is preferable to use Co) for the surface, and to mirror-finish the surface in advance and to perform sufficient hardening treatment.
【0012】次いで、図1の第2ステップ12におい
て、工具1に圧延ロール3を押付けながら回転させて、
圧印により圧延ロール3の外表面に凹孔2に対応した凸
部4を形成し、更に、第3ステップ14において、圧延
ロール3により鏡面材5を圧延加工する。Next, in the second step 12 of FIG. 1, the rolling roll 3 is rotated while being pressed against the tool 1,
A convex portion 4 corresponding to the concave hole 2 is formed on the outer surface of the rolling roll 3 by coining, and further, in a third step 14, the mirror surface material 5 is rolled by the rolling roll 3.
【0013】図2は、図1のA部を拡大して示す模式図
である。本発明の方法に用いる圧延ロール3は、図2に
示すように外表面に互いに間隔を隔てた多数の微細な凸
部4を有する。この圧延ロール3の凸部4は、互いに間
隔を隔てた多数の微細な凹孔2を有する超硬合金平面工
具1の圧印により形成され、超硬合金平面工具1の凹孔
2はイオンビーム加工により形成され、直径は約50μ
m以下であり中心間距離は約150μm以下であるのが
好ましく、最大直径が約30μmであり中心間距離が約
130μmであることが更に好ましい。なお、図2のよ
うに、鏡面材5の両面に凹孔6を圧延加工してもよく、
或いは片面のみに加工してもよい。FIG. 2 is a schematic view showing an enlarged part A of FIG. The rolling roll 3 used in the method of the present invention has a large number of fine convex portions 4 spaced from each other on the outer surface as shown in FIG. Protrusions 4 of the rolling rolls 3, is formed by coining a cemented carbide flat tool 1 having a large number of fine concavities 2 spaced from each other, concavity 2 of cemented carbide plane tool 1 ion beam processing Formed with a diameter of about 50μ
m or less and the center-to-center distance is preferably about 150 μm or less, more preferably the maximum diameter is about 30 μm and the center-to-center distance is about 130 μm. As shown in FIG. 2, the concave holes 6 may be rolled on both surfaces of the mirror-like material 5,
Alternatively, it may be processed on only one side.
【0014】上記本発明の方法によれば、圧延ロール3
の外表面に互いに間隔を隔てた多数の微細な凸部4が形
成されるので、この圧延ロール3により表面が鏡面の素
材(鏡面材5)を圧延加工することにより、鏡面材5の
表面に多数の微細な凹孔6を形成することができる。従
って、かかる鏡面材5(製品)をプレス加工する際に、
鏡面材表面の凹孔6に潤滑油を保持することができ、鏡
面材のプレス加工における潤滑性を高めることができ
る。また、多数の微細な凹孔2を互いに一定の間隔を隔
てて独立に形成し、この凹孔に対応した凸部4を形成す
るので、この圧延ロールにより表面が鏡面の素材(鏡面
材)を圧延加工することにより、鏡面材の表面に互いに
ほぼ一定の間隔を隔てて独立した多数の微細な凹孔6を
形成することができる。従って、かかる鏡面材(製品)
をプレス加工する際に、鏡面材表面の凹孔6に潤滑油を
保持することができ、プレス加工における潤滑性を高め
ることができる。According to the above method of the present invention, the rolling roll 3
Since a large number of minute convex portions 4 spaced from each other are formed on the outer surface of the, the surface of the mirror-finished material 5 is rolled by rolling the material whose surface is mirror-finished (mirror-finished material 5) with this rolling roll 3. A large number of fine recessed holes 6 can be formed. Therefore, when pressing such a mirror surface material 5 (product),
Lubricating oil can be retained in the concave holes 6 on the surface of the mirror surface material, and the lubricity in the press working of the mirror surface material can be improved. In addition, since a large number of minute concave holes 2 are independently formed at regular intervals and the convex portions 4 corresponding to the concave holes are formed, a material having a mirror surface (mirror surface material) is formed by this rolling roll. By rolling, it is possible to form a large number of independent fine concave holes 6 on the surface of the mirror-finished material at substantially regular intervals. Therefore, such mirror surface material (product)
When press working, the lubricating oil can be retained in the concave holes 6 on the surface of the mirror surface material, and the lubricity in the press working can be enhanced.
【0015】また、本発明の好ましい実施例によれば、
イオンビーム加工により超硬合金平面工具に凹孔2を形
成し、これを圧印により圧延ロール3へ転写し、この圧
延ロール3により圧延加工することにより、広い面積の
鏡面材に微細な凹孔6(例えば直径、約50μm以下、
中心間距離、約150μm以下)を効率よく形成するこ
とができる。According to a preferred embodiment of the present invention,
A concave hole 2 is formed in a cemented carbide flat tool by ion beam processing, this is transferred to a rolling roll 3 by coining, and rolling is performed by this rolling roll 3 to form a fine concave hole 6 in a mirror surface material having a large area. (For example, the diameter is about 50 μm or less,
The center-to-center distance, about 150 μm or less) can be efficiently formed.
【0016】図3は、本発明の方法により製作した鏡面
を有する超硬合金平面工具1の表面拡大図である。この
図において、(A)(B)は、同一の超硬合金平面工具
の表面であり、(A)は200倍、(B)は100倍の
場合を示している。また図中短い横線(黒線)は100
μmの長さを示す。工具の材料には超硬材であるWC-
Coを用い、適当なマスクを用いてイオンビーム加工に
より凹孔を形成した。この図から明らかなように、凹孔
の直径は約30μmであり、かつその中心間距離は約1
30μmであった。また、この図からは明らかでない
が、この超硬合金平面工具を拡大せずに目視した場合に
は、凹孔のまったくない鏡面と区別することができず、
見掛け上は鏡面であるが規則正しい微細な凹凸を有して
いる。FIG. 3 is an enlarged view of the surface of the cemented carbide flat tool 1 having a mirror surface manufactured by the method of the present invention. In this figure, (A) and (B) are the surfaces of the same cemented carbide flat tool, (A) shows a case of 200 times, and (B) shows a case of 100 times. The short horizontal line (black line) in the figure is 100.
The length of μm is shown. WC- which is a super hard material for the material of the tool
A concave hole was formed by ion beam processing using Co using a suitable mask. As is clear from this figure, the diameter of the concave holes is about 30 μm, and the center-to-center distance is about 1 μm.
It was 30 μm. Also, although it is not clear from this figure, when visually inspecting this cemented carbide flat tool without enlarging it, it is not possible to distinguish it from a mirror surface with no concave holes at all,
Although it is a mirror surface in appearance, it has regular fine irregularities.
【0017】なお、本発明は上述した実施例に限定され
ず、本発明の要旨を逸脱しない範囲で種々変更できるこ
とは勿論である。The present invention is not limited to the above-mentioned embodiments, and it goes without saying that various modifications can be made without departing from the gist of the present invention.
【0018】[0018]
【発明の効果】上述したように、本発明の微細穴を有す
る鏡面材の加工法は、プレス加工における潤滑性が良
く、かつ鏡面としての優れた特性(光沢、写像性)を損
なうことなく、見掛け上は鏡面であるが規則正しい微細
穴を有する鏡面材を加工することができる、等の優れた
効果を有する。As described above, the method for processing a mirror surface material having fine holes according to the present invention has good lubricity in press working and does not impair the excellent characteristics (gloss, image clarity) as a mirror surface. Although it is apparently a mirror surface, it has an excellent effect that a mirror surface material having regular fine holes can be processed.
【図1】本発明の微細穴を有する鏡面材の加工法を模式
的に示す図である。FIG. 1 is a diagram schematically showing a processing method of a mirror surface material having microscopic holes according to the present invention.
【図2】図1のA部を拡大して示す模式図である。FIG. 2 is a schematic view showing an enlarged part A of FIG.
【図3】本発明の方法により製作した超硬合金平面工具
の表面拡大図である。FIG. 3 is an enlarged view of the surface of a cemented carbide flat tool manufactured by the method of the present invention.
1 超硬合金平面工具 2 工具の凹孔 3 圧延ロール 4 凸部 5 鏡面材(製品) 6 鏡面材の凹孔 7 マスク 8 イオンビーム 10 第1ステップ 12 第2ステップ 14 第3ステップ1 Cemented Carbide Flat Tool 2 Tool Cavity 3 Rolling Roll 4 Convex 5 Mirror Surface Material (Product) 6 Mirror Surface Cavity 7 Mask 8 Ion Beam 10 First Step 12 Second Step 14 Third Step
フロントページの続き (58)調査した分野(Int.Cl.7,DB名) B21B 1/00 - 11/00 B21B 27/00 B23K 15/00 B23K 15/08 Continuation of front page (58) Fields surveyed (Int.Cl. 7 , DB name) B21B 1/00-11/00 B21B 27/00 B23K 15/00 B23K 15/08
Claims (3)
間隔を隔てた多数の微細な凹孔(2)を形成し、該工具
の圧印により圧延ロール(3)の外表面に、前記凹孔に
対応し互いに間隔を隔てた凸部(4)を形成し、該圧延
ロールにより鏡面材(5)を圧延加工して該表面に多数
の微細な凹孔(6)を形成する、ことを特徴とする微細
穴を有する鏡面材の加工法。1. A surface of a cemented carbide flat tool (1) is provided with a large number of minute recessed holes (2) spaced apart from each other, and the impression of the tool is applied to the outer surface of a rolling roll (3), Forming convex portions (4) corresponding to the concave holes and spaced from each other, and rolling the mirror surface material (5) by the rolling roll to form a large number of fine concave holes (6) on the surface; A method for processing a mirror surface material having fine holes.
定の間隔を隔てて独立に形成し、この凹孔に対応した凸
部(4)を形成し、前記多数の微細な凹孔(6)を互い
に一定の間隔を隔てて独立に形成する、ことを特徴とす
る請求項1に記載の微細穴を有する鏡面材の加工法。2. The large number of minute recessed holes (2) are independently formed at regular intervals and a convex portion (4) corresponding to the recessed holes is formed, and the large number of minute recessed holes are formed. 2. The method for processing a mirror-finished material having microscopic holes according to claim 1, wherein (6) are independently formed at a constant interval.
成はイオンビーム加工による、ことを特徴とする請求項
1又は2に記載の微細穴を有する鏡面材の加工法。3. The method for processing a mirror-finished material having fine holes according to claim 1 or 2, wherein the concave holes of the cemented carbide flat tool (1) are formed by ion beam processing.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP06180694A JP3384507B2 (en) | 1994-03-31 | 1994-03-31 | Processing method of mirror material with micro holes |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP06180694A JP3384507B2 (en) | 1994-03-31 | 1994-03-31 | Processing method of mirror material with micro holes |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH07265906A JPH07265906A (en) | 1995-10-17 |
JP3384507B2 true JP3384507B2 (en) | 2003-03-10 |
Family
ID=13181710
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP06180694A Expired - Fee Related JP3384507B2 (en) | 1994-03-31 | 1994-03-31 | Processing method of mirror material with micro holes |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP3384507B2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6138490A (en) * | 1998-07-17 | 2000-10-31 | Pechiney Rolled Products Llc | Process for rendering a metal sheet suitable for lighting applications and sheet produced thereby |
-
1994
- 1994-03-31 JP JP06180694A patent/JP3384507B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JPH07265906A (en) | 1995-10-17 |
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