GB905074A - Improvements relating to the heat stabilization of polyvinylchloride - Google Patents
Improvements relating to the heat stabilization of polyvinylchlorideInfo
- Publication number
- GB905074A GB905074A GB3549460A GB3549460A GB905074A GB 905074 A GB905074 A GB 905074A GB 3549460 A GB3549460 A GB 3549460A GB 3549460 A GB3549460 A GB 3549460A GB 905074 A GB905074 A GB 905074A
- Authority
- GB
- United Kingdom
- Prior art keywords
- calcium
- zinc
- phosphite
- sodium
- lauryl sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920000915 polyvinyl chloride Polymers 0.000 title abstract 3
- 239000004800 polyvinyl chloride Substances 0.000 title abstract 3
- 230000006641 stabilisation Effects 0.000 title 1
- 238000011105 stabilization Methods 0.000 title 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 6
- 239000011575 calcium Chemical group 0.000 abstract 6
- 229910052791 calcium Inorganic materials 0.000 abstract 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 abstract 6
- 229910052725 zinc Chemical group 0.000 abstract 5
- 239000011701 zinc Chemical group 0.000 abstract 5
- 239000000203 mixture Substances 0.000 abstract 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 abstract 3
- 239000004141 Sodium laurylsulphate Substances 0.000 abstract 3
- -1 alkali metal derivative of saccharin Chemical class 0.000 abstract 3
- 229910052751 metal Chemical class 0.000 abstract 3
- 239000002184 metal Chemical class 0.000 abstract 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000011591 potassium Chemical group 0.000 abstract 2
- 239000003381 stabilizer Substances 0.000 abstract 2
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- YEQHNTCMAVPEKP-UHFFFAOYSA-N 6-methylheptyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCC(C)C)OC1=CC=CC=C1 YEQHNTCMAVPEKP-UHFFFAOYSA-N 0.000 abstract 1
- 239000004606 Fillers/Extenders Substances 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 abstract 1
- 229920001944 Plastisol Polymers 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- RQWYLUWQZLBHGQ-UHFFFAOYSA-N [Ca].C(C1=CC=CC=C1)(=O)OCCCC Chemical compound [Ca].C(C1=CC=CC=C1)(=O)OCCCC RQWYLUWQZLBHGQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 159000000007 calcium salts Chemical class 0.000 abstract 1
- ZMRQTIAUOLVKOX-UHFFFAOYSA-L calcium;diphenoxide Chemical compound [Ca+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 ZMRQTIAUOLVKOX-UHFFFAOYSA-L 0.000 abstract 1
- NDWWLJQHOLSEHX-UHFFFAOYSA-L calcium;octanoate Chemical compound [Ca+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O NDWWLJQHOLSEHX-UHFFFAOYSA-L 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000000 cycloalkoxy group Chemical group 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- 150000008301 phosphite esters Chemical class 0.000 abstract 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 239000004999 plastisol Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000012260 resinous material Substances 0.000 abstract 1
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- WSFQLUVWDKCYSW-UHFFFAOYSA-M sodium;2-hydroxy-3-morpholin-4-ylpropane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(O)CN1CCOCC1 WSFQLUVWDKCYSW-UHFFFAOYSA-M 0.000 abstract 1
- WWJAQYAUWBSHAP-UHFFFAOYSA-M sodium;2-sulfohexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCC(C(O)=O)S([O-])(=O)=O WWJAQYAUWBSHAP-UHFFFAOYSA-M 0.000 abstract 1
- 230000003019 stabilising effect Effects 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- ILLOBGFGKYTZRO-UHFFFAOYSA-N tris(2-ethylhexyl) phosphite Chemical compound CCCCC(CC)COP(OCC(CC)CCCC)OCC(CC)CCCC ILLOBGFGKYTZRO-UHFFFAOYSA-N 0.000 abstract 1
- 150000003751 zinc Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Plasticized polyvinyl chloride compositions containing in intimate admixture therewith means for stabilising said resinous material comprise, by weight of the resin, (1) 0,01 to 3% of either an alkali metal derivative of saccharin or a metal salt of formula RSO3M wherein M is sodium, potassium, lithium, calcium or zinc and R is alkyl, alkenyl, aryl, aralkyl, aralkenyl, alkaryl, cycloalkyl, alkoxy, aroxy, cycloalkoxy, alkaroxy, aralkoxy or alkenoxy; (2) 0,01 to 0,5% of calcium calculated as metal and included as a calcium salt of a C6-C30 carboxylic acid or calcium phenate; (3) 0,01 to 0,5% of zinc calculated as metal and included as a zinc salt of a C6-C30 carboxylic acid; and (4) 0,005 to 0,5% by weight of phosphorus calculated as element and included as a phosphite ester. Where the polyvinyl chloride has been prepared by emulsion polymerization component (1) may be derived partly or wholly from emulsifier residues. Many suitable compounds for use in the stabilizers of the invention are listed and examples describe compositions comprising polyvinyl chloride, di-(2-ethylhexyl) phthalate, epoxidized soya bean oil and optionally titanium dioxide and calcium carbonate stabilized with (3, 4, 6 and 7) calcium and zinc naphthenates and triphenyl phosphite, together with (9 and 11) sodium lauryl sulphate; (15 and 18) calcium and zinc octoates and triphenyl phosphite with (12) sodium lauryl sulphate; (13) calcium and zinc naphthenates, diphenyl monoisooctyl phosphite and sodium lauryl sulphate; (14) calcium butyl benzoate, zinc octoate, tri-(2-ethylhexyl) phosphite and potassium oleyl sulphonate; (16) calcium octoate, zinc naphthenate, tricresyl phosphite and sodium saccharin; and (17) calcium p-octylphenate, zinc octoate, triphenyl phosphite and sodium sulphopalmitate. The compositions may also comprise vinyl chloride copolymers, e.g. copolymers of vinyl chloride with vinyl acetate and vinylidene chloride, fillers, extenders, pigments and auxiliary stabilizers and may be used in the formulation of plastisols.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4249260A | 1960-07-13 | 1960-07-13 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB905074A true GB905074A (en) | 1962-09-05 |
Family
ID=21922217
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3549460A Expired GB905074A (en) | 1960-07-13 | 1960-10-17 | Improvements relating to the heat stabilization of polyvinylchloride |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB905074A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2308225A1 (en) * | 1972-03-03 | 1973-09-06 | Akzo Gmbh | PVC BLEND |
| FR2423510A1 (en) * | 1978-04-17 | 1979-11-16 | Argus Chem | COMPOSITION PREVENTING YELLOWING, ESPECIALLY POLY (VINYL CHLORIDE) |
| EP2711162A3 (en) * | 2012-09-19 | 2018-04-25 | VPW Nink GmbH | PVC profile panel embossed on one side with sun screen function |
-
1960
- 1960-10-17 GB GB3549460A patent/GB905074A/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2308225A1 (en) * | 1972-03-03 | 1973-09-06 | Akzo Gmbh | PVC BLEND |
| FR2423510A1 (en) * | 1978-04-17 | 1979-11-16 | Argus Chem | COMPOSITION PREVENTING YELLOWING, ESPECIALLY POLY (VINYL CHLORIDE) |
| EP2711162A3 (en) * | 2012-09-19 | 2018-04-25 | VPW Nink GmbH | PVC profile panel embossed on one side with sun screen function |
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