GB571591A - Improvements in or relating to diamides and method of producing same - Google Patents

Improvements in or relating to diamides and method of producing same

Info

Publication number
GB571591A
GB571591A GB458/43A GB45843A GB571591A GB 571591 A GB571591 A GB 571591A GB 458/43 A GB458/43 A GB 458/43A GB 45843 A GB45843 A GB 45843A GB 571591 A GB571591 A GB 571591A
Authority
GB
United Kingdom
Prior art keywords
oil
acids
carbon atoms
diamides
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB458/43A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wyeth Holdings LLC
Original Assignee
American Cyanamid Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Cyanamid Co filed Critical American Cyanamid Co
Publication of GB571591A publication Critical patent/GB571591A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/004Organic compounds
    • B03D1/01Organic compounds containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00Preparation of carboxylic acid amides
    • C07C231/02Preparation of carboxylic acid amides from carboxylic acids or from esters, anhydrides, or halides thereof by reaction with ammonia or amines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/405Acylated polyalkylene polyamines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02Ores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02Ores
    • B03D2203/04Non-sulfide ores
    • B03D2203/06Phosphate ores
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08Amides
    • C10M2215/082Amides containing hydroxyl groups; Alkoxylated derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26Amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/46Textile oils

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Diamides having the general formula RCONH(XNH)n.XNH.COR1, wherein R is an alkyl radical having from 1 to 5 carbon atoms, R1 is an alkyl radical having from 9 to 20 carbon atoms, X is an ethylene radical and n is a small whole number, are prepared by reacting a polyethylene polyamine with a molecular proportion of a fatty acid acylating agent at a temperature between 110 DEG and 220 DEG C. so as to introduce an acyl group having not more than 6 carbon atoms and then reacting the product with another fatty acid acylating agent at 110 DEG to 220 DEG C., in molecular proportions so as to introduce an acyl group having from 10 to 21 carbon atoms, each step involving the removal of one molecular proportion of water or its equivalent per molecular proportion of amine or acylated amine used. In a modification, the higher fatty acid acylating agent may be reacted first. The acylating agents employed are the fatty acids themselves and the corresponding acyl halides and anhydrides and the acid esters. The compounds form salts readily with acids, e.g. acetic, formic, hydrochloric. The compounds and their salts are used as wetting, emulsifying and dispersing agents, detergents, dyeing assistants, textile lubricants and for breaking of petroleum emulsions of the oil-in-water type, and similar purposes. They are very useful as promoters for flotation of acidic minerals, e.g. feldspar, quartz, pyroxenes, the spineles, biotite, muscovite, clays, etc.; and particularly for the flotation of silica from phosphates. In examples, a mixture of polyethylene polyamines obtained by reacting ethylene dichloride with ammonia is condensed with acetic acid and cottonseed oil, palm oil, coconut oil, or oleic acid; the acetates of these diamides are described. Other reactants mentioned are: butyric, propionic and valeric acids, and as the higher acylating agents capric, lauric, myristic, palmitic, margaric, stearic, din-octyl acetic, arachidic, ricinoleic, naphthenic, abietic and pimaric acids and the esters of such acids occurring in animal and vegetable fats and oils such as palm kernel oil, linseed oil, olive oil, peanut oil, soya bean oil, castor oil, perilla oil, corn oil, sardine oil, shark oil, whale oil, seal oil, tall oil, and tallow; the esters of monohydric and polyhydric alcohols such as, for example, methyl stearate and glycol stearate, may also be used. The Specification as open to inspection under Sect. 91 includes the preparation of diamides having the above general formula in which R1 may also be a cycloalkyl radical and X may be an alkylene radical having 2 to 8 carbon atoms. Thus, in addition to polyethylene polyamines, there may be used propylene polyamines obtained by reacting propylene dichloride with ammonia, dibutylene triamine, tributylene tetramine, and diamylene triamine; and the higher acylating agents specified include hydrobenzoic and tetrahydrotoluic acids. This subject-matter does not appear in the Specification as accepted.
GB458/43A 1942-02-14 1943-01-09 Improvements in or relating to diamides and method of producing same Expired GB571591A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US571591XA 1942-02-14 1942-02-14

Publications (1)

Publication Number Publication Date
GB571591A true GB571591A (en) 1945-08-31

Family

ID=22008859

Family Applications (1)

Application Number Title Priority Date Filing Date
GB458/43A Expired GB571591A (en) 1942-02-14 1943-01-09 Improvements in or relating to diamides and method of producing same

Country Status (1)

Country Link
GB (1) GB571591A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2733455A1 (en) * 1977-07-25 1979-02-08 Barmag Barmer Maschf STORAGE CHAMBER TEXTURING PROCESS
GB2118964A (en) * 1982-04-26 1983-11-09 Dow Chemical Co Use of heterocyclic ammonium polyamidoamines as demulsifiers
WO2016180745A3 (en) * 2015-05-11 2016-12-22 Akzo Nobel Chemicals International B.V. Nitrogen-containing anti-agglomerants for preserving the fluidity of fluids containing gas hydrates

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2733455A1 (en) * 1977-07-25 1979-02-08 Barmag Barmer Maschf STORAGE CHAMBER TEXTURING PROCESS
GB2118964A (en) * 1982-04-26 1983-11-09 Dow Chemical Co Use of heterocyclic ammonium polyamidoamines as demulsifiers
WO2016180745A3 (en) * 2015-05-11 2016-12-22 Akzo Nobel Chemicals International B.V. Nitrogen-containing anti-agglomerants for preserving the fluidity of fluids containing gas hydrates
US10876033B2 (en) 2015-05-11 2020-12-29 Nouryon Chemicals International B.V. Nitrogen-containing anti-agglomerants for preserving the fluidity of fluids containing gas hydrates

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