GB346812A - An improved process for the production of drying agents with a high metal content for use in paints - Google Patents
An improved process for the production of drying agents with a high metal content for use in paintsInfo
- Publication number
- GB346812A GB346812A GB277/30A GB27730A GB346812A GB 346812 A GB346812 A GB 346812A GB 277/30 A GB277/30 A GB 277/30A GB 27730 A GB27730 A GB 27730A GB 346812 A GB346812 A GB 346812A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oils
- acids
- soluble
- oil
- hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 5
- 239000002274 desiccant Substances 0.000 title abstract 3
- 239000003973 paint Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 abstract 6
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical class OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 4
- 240000007817 Olea europaea Species 0.000 abstract 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 4
- 239000004411 aluminium Substances 0.000 abstract 4
- 229910052782 aluminium Inorganic materials 0.000 abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 4
- 229910052797 bismuth Inorganic materials 0.000 abstract 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 abstract 4
- 229910052802 copper Inorganic materials 0.000 abstract 4
- 239000010949 copper Substances 0.000 abstract 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 4
- 229930195729 fatty acid Natural products 0.000 abstract 4
- 239000000194 fatty acid Substances 0.000 abstract 4
- 150000004665 fatty acids Chemical class 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 150000004679 hydroxides Chemical class 0.000 abstract 4
- -1 hydroxyl hydrogen Chemical compound 0.000 abstract 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 4
- 150000002736 metal compounds Chemical class 0.000 abstract 4
- 239000011701 zinc Substances 0.000 abstract 4
- 229910052725 zinc Inorganic materials 0.000 abstract 4
- 239000002253 acid Substances 0.000 abstract 3
- 239000001293 FEMA 3089 Substances 0.000 abstract 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 abstract 2
- 240000006240 Linum usitatissimum Species 0.000 abstract 2
- 235000004431 Linum usitatissimum Nutrition 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 2
- 235000019484 Rapeseed oil Nutrition 0.000 abstract 2
- 241000779819 Syncarpia glomulifera Species 0.000 abstract 2
- 150000007513 acids Chemical class 0.000 abstract 2
- 239000010775 animal oil Substances 0.000 abstract 2
- 239000004359 castor oil Substances 0.000 abstract 2
- 235000019438 castor oil Nutrition 0.000 abstract 2
- 239000010941 cobalt Substances 0.000 abstract 2
- 229910017052 cobalt Inorganic materials 0.000 abstract 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 2
- 239000003925 fat Substances 0.000 abstract 2
- 235000019197 fats Nutrition 0.000 abstract 2
- 235000021323 fish oil Nutrition 0.000 abstract 2
- 235000004426 flaxseed Nutrition 0.000 abstract 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 2
- 150000001261 hydroxy acids Chemical class 0.000 abstract 2
- 235000014655 lactic acid Nutrition 0.000 abstract 2
- 239000004310 lactic acid Substances 0.000 abstract 2
- 239000011133 lead Substances 0.000 abstract 2
- 229910000464 lead oxide Inorganic materials 0.000 abstract 2
- 235000020778 linoleic acid Nutrition 0.000 abstract 2
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical class 0.000 abstract 2
- 150000002739 metals Chemical class 0.000 abstract 2
- 239000003921 oil Substances 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 abstract 2
- 235000021313 oleic acid Nutrition 0.000 abstract 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract 2
- 239000004006 olive oil Substances 0.000 abstract 2
- 235000008390 olive oil Nutrition 0.000 abstract 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 abstract 2
- 239000001739 pinus spp. Substances 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 239000008159 sesame oil Substances 0.000 abstract 2
- 235000011803 sesame oil Nutrition 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 abstract 2
- 229940036248 turpentine Drugs 0.000 abstract 2
- 239000008158 vegetable oil Substances 0.000 abstract 2
- 235000013311 vegetables Nutrition 0.000 abstract 2
- 239000010698 whale oil Substances 0.000 abstract 2
- 239000000944 linseed oil Substances 0.000 abstract 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 abstract 1
- 229960003656 ricinoleic acid Drugs 0.000 abstract 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09F—NATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
- C09F9/00—Compounds to be used as driers, i.e. siccatives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Fats And Perfumes (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Drying agents, having a high metal content, for use in paints, are produced by substituting the hydroxyl hydrogen as well as the carboxyl hydrogen of mono- or polybasic, mono- or polyhydroxy fatty acids, or their glycerine esters, or mixtures of both, by metals such as aluminium, lead, zinc, cobalt, copper, manganese or bismuth. The metal compounds may be prepared by reacting the hydroxy acids or their glycerine esters with metal compounds such as metal oxides or hydroxides. The reaction may be effected in the presence of saturated or unsaturated non-hydroxylated fatty acids, such as oleic or linoleic acids or of vegetable or animal oils or fats, such as linseed, ,olive or sesame oils or certain train oils, or of mixtures of such acids and oils. The presence of such materials during reaction renders the products soluble in the usual solvents such as turpentine oil, heavy benzine, &c., whereas the products obtained in their absence are not always so soluble. In examples (1) recinoleic acid, lactic acid and rapeseed oil are heated together and cobaltous hydroxide is added. A solid mass soluble in turpentine, and heavy benzine is obtained. (2) To a mixture of olein, glycollic acid, castor oil and olive or fish oil, cobaltous hydroxide is added. If desired, lead oxide, manganic hydroxide or the oxides or hydroxides of aluminium, zinc, copper or bismuth may be used instead of cobaltous hydroxide.ALSO:Drying agents, having a high metal content, for use in paints, are produced by substituting the hydroxyl hydrogen as well as the carboxyl hydrogen of mono- or polybasic, mono- or polyhydroxy fatty acids, or their glycerine esters, or mixtures of both by metals such as aluminium, lead, zinc, cobalt, copper, manganese or bismuth. The metal compounds may be prepared by reacting the hydroxy acids or their glycerine esters with metal compounds such as metal oxides or hydroxides. The reaction may be effected in the presence of saturated or unsaturated nonhydroxylated fatty acids, such as oleic or linoleic acids, or of vegetable or animal oils or fats, such as linseed, olive or sesame oils or certain train oils, or of mixtures of such acids and oils. The presence of such materials during reaction renders the products soluble in the usual solvents such as turpentine oil, heavy benzine, &c., whereas the products obtained in their absence are not always so soluble. In examples (1) ricinoleic acid, lactic acid and rapeseed oil are heated together and cobaltous hydroxide is added. A solid mass soluble in turpentine and heavy benzine is obtained. (2) To a mixture of olein, glycollic acid, castor oil and olive or fish oil, cobaltous hydroxide is added. If desired, lead oxide, manganese hydroxide or the oxides or hydroxides of aluminium, zinc, copper or bismuth may be used instead of cobaltous hydroxide.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE346812X | 1929-01-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB346812A true GB346812A (en) | 1931-04-07 |
Family
ID=6255545
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB277/30A Expired GB346812A (en) | 1929-01-23 | 1930-01-03 | An improved process for the production of drying agents with a high metal content for use in paints |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE555715C (en) |
| FR (1) | FR688306A (en) |
| GB (1) | GB346812A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2732799A (en) * | 1956-01-31 | Methods for insomjbilizing coating | ||
| EP0412628A2 (en) * | 1989-08-04 | 1991-02-13 | Nikken Chemical Laboratory Co., Ltd. | Drier for offset printing ink |
| CN105504947A (en) * | 2014-10-14 | 2016-04-20 | 武汉鸿信通科技有限公司 | Drier for industrial paint |
-
0
- FR FR688306D patent/FR688306A/fr active Active
- DE DENDAT555715D patent/DE555715C/de active Active
-
1930
- 1930-01-03 GB GB277/30A patent/GB346812A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2732799A (en) * | 1956-01-31 | Methods for insomjbilizing coating | ||
| EP0412628A2 (en) * | 1989-08-04 | 1991-02-13 | Nikken Chemical Laboratory Co., Ltd. | Drier for offset printing ink |
| EP0412628A3 (en) * | 1989-08-04 | 1992-04-15 | Nikken Chemical Laboratory Co., Ltd. | Drier for offset printing ink |
| CN105504947A (en) * | 2014-10-14 | 2016-04-20 | 武汉鸿信通科技有限公司 | Drier for industrial paint |
Also Published As
| Publication number | Publication date |
|---|---|
| DE555715C (en) | |
| FR688306A (en) |
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