GB2475324A - Boiling sensor for water-boiling appliances - Google Patents
Boiling sensor for water-boiling appliances Download PDFInfo
- Publication number
- GB2475324A GB2475324A GB0920033A GB0920033A GB2475324A GB 2475324 A GB2475324 A GB 2475324A GB 0920033 A GB0920033 A GB 0920033A GB 0920033 A GB0920033 A GB 0920033A GB 2475324 A GB2475324 A GB 2475324A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- kettle
- boiling
- appliance
- sensor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000009835 boiling Methods 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 238000001514 detection method Methods 0.000 claims abstract description 20
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 230000000007 visual effect Effects 0.000 claims description 4
- 238000005286 illumination Methods 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 239000012777 electrically insulating material Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000001012 protector Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J27/00—Cooking-vessels
- A47J27/21—Water-boiling vessels, e.g. kettles
- A47J27/21008—Water-boiling vessels, e.g. kettles electrically heated
- A47J27/21058—Control devices to avoid overheating, i.e. "dry" boiling, or to detect boiling of the water
- A47J27/21091—Control devices to avoid overheating, i.e. "dry" boiling, or to detect boiling of the water of electronic type
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J27/00—Cooking-vessels
- A47J27/21—Water-boiling vessels, e.g. kettles
- A47J27/21008—Water-boiling vessels, e.g. kettles electrically heated
- A47J27/21158—Devices to detect overheating or boiling with a single control element or unit
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01F—MEASURING VOLUME, VOLUME FLOW, MASS FLOW OR LIQUID LEVEL; METERING BY VOLUME
- G01F23/00—Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm
- G01F23/22—Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm by measuring physical variables, other than linear dimensions, pressure or weight, dependent on the level to be measured, e.g. by difference of heat transfer of steam or water
- G01F23/26—Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm by measuring physical variables, other than linear dimensions, pressure or weight, dependent on the level to be measured, e.g. by difference of heat transfer of steam or water by measuring variations of capacity or inductance of capacitors or inductors arising from the presence of liquid or fluent solid material in the electric or electromagnetic fields
- G01F23/263—Indicating or measuring liquid level or level of fluent solid material, e.g. indicating in terms of volume or indicating by means of an alarm by measuring physical variables, other than linear dimensions, pressure or weight, dependent on the level to be measured, e.g. by difference of heat transfer of steam or water by measuring variations of capacity or inductance of capacitors or inductors arising from the presence of liquid or fluent solid material in the electric or electromagnetic fields by measuring variations in capacitance of capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Electromagnetism (AREA)
- Thermal Sciences (AREA)
- Fluid Mechanics (AREA)
- General Physics & Mathematics (AREA)
- Cookers (AREA)
Abstract
A water-boiling sensor usable in electric kettles, or other water-boiling appliances incorporating an electrically powered heating element, is designed to reliably detect when the water boils. It utilises a capacitive detection element comprising electrodes 10, 12, which disposed in contact with water in the appliance and are connected to an oscillator 16 or other circuit, which generates electrical signals that are influenced by the capacitance between the electrodes, and which exhibit a peculiar and repeatable characteristic response when the water boils. Electrical circuitry 18 is provided to recognise electrical signals having the aforementioned characteristic response and to then develop control signals which disconnect the power from the heating element when the water boils. The sensor is wholly electronic and preferably can also be used to detect the water level, and calculate the expected boiling time. A warning device may also be included to alert to an extended boiling time, which may be indicative of an issue with the appliance.
Description
BOILING SENSOR
This invention relates to a boiling sensor, and it relates more particularly to such a sensor usable in electric kettles, or other water-boiling appliances, to reliably detect when the water boils.
Preferably, and in accordance with an aspect of this invention, a detection element of the sensor is also usable to detect the level of water in the kettle or other appliance.
Electric kettles are widely used in domestic kitchens in preference to kettles that require an external source of heat. By and large, such appliances are reliable and speedy in operation, and, being electrically powered, can readily be provided with control circuitry to detect when the water boils and/or to detect the onset of potentially damaging boil-dry situations and to disconnect the supply of electrical power to the heating element when appropriate. Various circuit arrangements are known for effecting such detection and control, and many of these are proven and highly reliable, though most require quite complex electro-mechanical arrangements; boiling detection, for example, typically requiring the provision of a duct to carry steam from the region above the water line down to an electrical circuit in or near the base of the kettle which responds to the ducted steam by throwing a switch that disconnects the kettle's heating element from the mains power supply.
One object of this invention is to provide a boiling sensor, for an electric kettle or other electrically powered water-boiling appliance, that is wholly electronic, and thus economic to incorporate into a kettle or other appliance. In preferred embodiments of the invention, a detection element of the sensor provides, when the water boils, electrical signals having a particular characteristic and there is provided electronic circuitry capable of recognising signals having said characteristic and to develop a switching signal in response to such recognition; the switching signal being usable, for example, to disconnect electrical power from a heating element of the kettle or other appliance.
A particularly preferred embodiment of the invention utilises capacitive means as said detection element.
Another object of the invention is to utilise, as a detection element of such a sensor, componentry used, or usable, to detect or monitor at least one other criterion or parameter associated with the kettle or other appliance, such as a level of water to which the kettle or other appliance is filled.
A particularly preferred form of the invention utilises capacitive means as such a detection element; the capacitive element providing electrical output signals with one characteristic indicative of water level and with another characteristic indicative of boiling. Electrical circuitry is provided to differentiate between electrical signals having the two characteristics and to provide as outputs appropriate control signals, such as switching signals, and parameter magnitude signals.
According to the invention there is provided an electronic boiling sensor, for an electric kettle or other electrically powered water-boiling appliance, the sensor comprising a detection element configured to provide, when the water boils, electrical signals having a particular characteristic, and electronic circuitry capable of recognising signals having said characteristic and developing, in response to such recognition, a control signal usable to control an operating function of the kettle or other appliance.
In a preferred embodiment of the invention, the control signal comprises a switching signal usable to disconnect electrical power from a heating element of the kettle or other appliance.
It is further preferred that said detection element is also usable, to detect or monitor at least one other criterion or parameter associated with the kettle or other appliance, such as a level of water to which the kettle or other appliance is filled.
Most preferably, said detection element comprises capacitive means.
In some preferred embodiments of the invention, said capacitive means is configured to provide electrical output signals with one characteristic indicative of boiling and with another characteristic indicative of water level, and electronic circuitry may be provided to differentiate between electrical signals having the two characteristics and to provide as outputs both switching signals, derived from said control signal, and parameter magnitude signals.
Typically, some embodiments of the invention further comprise means for utilising signals indicative of a detected water level and of the known power of a heating element of the kettle or other appliance, to predict the time it should take to boil the water, and for comparing the predicted time with the actual time taken to boil the water, and means for generating a warning if the compared times differ by more than a predetermined amount, indicative of a possible need for descaling the kettle or other appliance.
Said warning may conveniently comprise a visual warning provided by illumination of a light-emitting device.
The invention also encompasses an electric kettle or other water-heating appliance incorporating any of the aforesaid electronic boiling sensors.
In order that the invention may be clearly understood and readily carried into effect, one embodiment thereof will now be described, with reference to the accompanying drawings, of which: Figure 1 shows a graph indicative of the operation of the detecting element of a sensor in accordance with one example of the invention; Figure 2 shows, in block diagrammatic form certain elements of the sensor; and Figure 3 shows in more detail the circuitry utilised in a sensor comprising one embodiment of the invention.
The use of capacitive means for detecting the water level in electric kettles has already been proposed, for example in US-A-5756876 and GB-A- 2358789, and the latter publication describes the use of associated circuitry to detect (inter alia) excessive or insufficient water in the kettle, and to prevent the element from receiving power in either case.
The present invention can, of course, perform such functions.
Surprisingly, however, it has been found that, if the output signals from a capacitive detection element are monitored during operation of a kettle or other appliance, they exhibit a peculiar and repeatable characteristic response when the water boils. The present invention utilises this surprising effect to develop control signals usable to disconnect the power from the heating element reliably and precisely when the water boils.
Referring now to the drawings, Figure 1 shows a graph indicative of the measured characteristics of electrical signals derived from a capacitive detecting element used in a boiling sensor according to one example of the invention. It will be appreciated in this respect that the kettle element was switched off when boiling was detected, and then repeatedly re-energised once the water temperature had fallen by a predetermined amount.
In this example, as will be described in more detail hereinafter, capacitive detection means, provided on or otherwise incorporated into an internal surface of a kettle in any convenient format, for example as plate-like or linear electrodes, are coupled to an electronic oscillator circuit. The oscillator is set up, in this instance, to generate a square wave, the frequency of which is influenced by the capacitance between the electrodes of the detection means, and a microprocessor is provided to monitor the frequency, or a derivative of the frequency, such as its rate of change.
Figure 1 shows, as a solid line 1, the actual temperature of the water in the kettle and, as a dashed line 2, the frequency of the oscillator. It will be observed that the frequency drops sharply and recognisably each time the water temperature reaches boiling point and then recovers as the water temperature cools following the disconnection of power from the heating element. The rate of change of the oscillator frequency is also shown on the graph of Figure 1, as a solid line 3. It will be observed that either or both characteristics (i.e. frequency 2 and rate of change of frequency 3) can be detected by the microprocessor and used to develop control signals that can be employed to reliably switch off the heater when boiling occurs.
It will be appreciated that the use of an all-electronic boiling sensor of this kind provides important advantage over, for example conventional boiling cut-outs based on the use of steam tubes to duct steam down to circuitry located in the base of a kettle. Notably, the steam ducts tend to become obstructed with lime deposits over extended use, thus rendering the cut-out (or so-called "steam-stat") less efficient over time and leading to over-long boiling times, which wastes energy and stresses the elements.
The capacitive detection means can, of course, still be used to sense the water level in the kettle, and this example of the invention thus provides useful duality of purpose, functioning as an efficient level sensor and boiling sensor. Moreover, this duality of purpose leads to further flexibility in operation of the kettle, as it is possible, based upon the detected water level and the known power of the heating element, to predict the time it should take to boil the water. If the predicted time does not correspond (within reasonable tolerance) to the time it actually takes the water to boil, as measured by the capacitive detection means and its associated circuitry, the microprocessor can be caused to generate a signal which illuminates an LED, or stimulates some other form of display (audible and/or visual) to warn the user that the kettle may require descaling.
Referring now to Figures 2 and 3, electrodes 10 and 12 forming the detection elements of a boiling sensor in accordance with one example of the invention are applied to the internal wall of a kettle body 14. The electrodes 10 and 12 may be attached or deposited in any convenient manner upon, or incorporated into, the body 14; the attachment or deposition technique being determined at least to a degree by the materials of which the kettle body is made. For example, where the body 14 is of plastics material, the electrodes 10 and 12 may be provided directly upon the interior surface of the body 14. Where the kettle is metal bodied, it is necessary either to pre-form one or more electrically insulating layers on at least the electrode-bearing regions of the internal surface of the kettle body 14 to support the electrodes 10 and 12, or to provide the electrodes 10 and 12 with respective backings of electrically insulating material prior to attaching them to the metal body.
The electrodes can be of any convenient shape, such as the rectangular plate format shown and, in general, they may be "tuned" in shape and/or dimensions to achieve a desired electrical performance from any given body 14. The electrodes need not be plate-like or widely separated, however, and can be configured, for example, into nested spirals, or elongated, sinuous forms.
The electrodes 10 and 12 are coupled to an oscillator circuit 16 and a microprocessor 18 is connected to monitor the performance of the oscillator 16, for example by monitoring its frequency or a rate of change of its frequency, in order to sense when the water in the kettle boils.
When a performance variation, such as the aforementioned drop in frequency, that is indicative of boiling is sensed, microprocessor 18 provides an output signal on line 20 which is usable to disconnect the heating element of the kettle from the electrical power supply.
In this particular embodiment of the invention, the oscillator 16, as shown in Figure 3, comprises a group of three inverted Schmitt trigger circuits 24a, 24b and 24c (each of the type designated 401 06N), interconnected in known manner in series with a pair of resistors 22a and 22b, to generate (with the capacitance of the electrodes 10 and 12, the leads from which are connected into the circuit at connection points 1 Oa and 1 2a respectively as shown in Figure 3) a square wave, the frequency of which is influenced by the capacitance, i.e. the dielectric, between the electrodes 10 and 12. The oscillator 16 is connected to pin 7 of the microprocessor 18 which, in this example, is an integrated circuit of the type designated 1 6F676D1L, and the microprocessor 18 measures the period of the square wave, using a timer, or counts the number of rising or falling edges in a predetermined time to determine the oscillator frequency. The frequency may be used as the measured parameter, as aforesaid, or the period of one sample may be compared with that of the previous sample to calculate any gradient of a frequency change.
The level sensing operation uses the same electrodes 10 and 12, and the same microprocessor 18, and can be implemented in any convenient manner, such as those disclosed in the aforementioned GB-A-2358789.
Usefully, the level-sensing output can be used to iiihibit the application of power to the heating element if the kettle does not contain sufficient water and/or if the kettle contains too much water. In some embodiments, level sensing is carried out only when the kettle is first connected to the power source; i.e. when the water is cold, simply to check that the kettle has not been under-or over-filled at the outset.
In other embodiments, however, the water level is sensed throughout the operation of the kettle, or is switched in to operation again after boiling has been detected by the circuit of Figures 2 and 3, to ensure that the kettle is not allowed to boil dry. This facility can avoid the need for a separate boil-dry protector of the kind usually employed.
The application of the electrodes to the kettle body 14 may be used to provide additional visual features, such as a volume capacity bar.
Claims (10)
- Claims: 1. An electronic boiling sensor, for an electric kettle or other electrically powered water-boiling appliance, the sensor comprising a detection element configured to provide, when the water boils, electrical signals having a particular characteristic, and electronic circuitry capable of recognising signals having said characteristic and developing, in response to such recognition, a control signal usable to control an operating function of the kettle or other appliance.
- 2. A sensor according to claim 1, wherein the control signal comprises a switching signal usable to disconnect electrical power from a heating element of the kettle or other appliance.
- 3. A sensor according to claim 1 or claim 2, wherein said detection element is also usable, to detect or monitor at least one other criterion or parameter associated with the kettle or other appliance, such as a level of water to which the kettle or other appliance is filled.
- 4. A sensor according to any preceding claim, wherein said detection element comprises capacitive means.
- 5. A sensor according to claim 4, wherein said capacitive means is configured to provide electrical output signals with one characteristic indicative of boiling and with another characteristic indicative of water level.
- 6. A sensor according to claim 5, wherein electronic circuitry is provided to differentiate between electrical signals having the two characteristics and to provide as outputs both switching signals, derived from said control signal, and parameter magnitude signals.
- 7. A sensor according to claim 5 or claim 6, further comprising means for utilising signals indicative of a detected water level and of the known power of a heating element of the kettle or other appliance, to predict the time it should take to boil the water, and for comparing the predicted time with the actual time taken to boil the water, and means for generating a warning if the compared times differ by more than a predetermined amount, indicative of a possible need for descaling the kettle or other appliance.
- 8. A sensor according to claim 7, wherein said warning is a visual warning provided by illumination of a light-emitting device.
- 9. An electronic boiling sensor substantially as herein described with reference to and/or as shown in the accompanying drawings.
- 10. An electric kettle incorporating an electronic boiling sensor according to any preceding claim.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0920033A GB2475324A (en) | 2009-11-17 | 2009-11-17 | Boiling sensor for water-boiling appliances |
PCT/GB2010/002106 WO2011061482A1 (en) | 2009-11-17 | 2010-11-16 | Boiling sensor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0920033A GB2475324A (en) | 2009-11-17 | 2009-11-17 | Boiling sensor for water-boiling appliances |
Publications (2)
Publication Number | Publication Date |
---|---|
GB0920033D0 GB0920033D0 (en) | 2009-12-30 |
GB2475324A true GB2475324A (en) | 2011-05-18 |
Family
ID=41509443
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB0920033A Withdrawn GB2475324A (en) | 2009-11-17 | 2009-11-17 | Boiling sensor for water-boiling appliances |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB2475324A (en) |
WO (1) | WO2011061482A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2498823A (en) * | 2012-07-03 | 2013-07-31 | Robert Hill | A water heater which is controllable through a wireless network |
US10418723B1 (en) | 2017-12-05 | 2019-09-17 | Rockwell Collins, Inc. | Dual polarized circular or cylindrical antenna array |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106289449B (en) * | 2015-06-11 | 2023-04-07 | 陈俊平 | Capacitance type water level and water amount detection device, water boiling kettle and detection method |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3784788A (en) * | 1971-05-04 | 1974-01-08 | Belling & Co Ltd | Electric liquid boiling apparatus having an electronic temperature sensor control |
GB2194107A (en) * | 1986-06-23 | 1988-02-24 | Proctor Silex Canada Inc | Electronic kettle |
GB2344045A (en) * | 1997-10-10 | 2000-05-31 | Bsh Bosch Siemens Hausgeraete | Electrical kettle with means to inhibit heating if over filled |
GB2358530A (en) * | 2000-01-24 | 2001-07-25 | Otter Controls Ltd | Temperature responsive control circuit for an electric kettle |
GB2358789A (en) * | 2000-02-07 | 2001-08-08 | Otter Controls Ltd | Liquid heating device with excessive or insufficient water level protection means. |
US20040149729A1 (en) * | 2001-06-09 | 2004-08-05 | Frank Kressmann | Method for heating liquid in an electric kettle |
GB2407478A (en) * | 2003-10-28 | 2005-05-04 | Tarquin Andrew Richard Stehle | Electronically-controlled domestic kettle |
GB2432212A (en) * | 2005-11-15 | 2007-05-16 | Crastal Technology | Method of detecting boil condition in a kettle |
WO2007131271A1 (en) * | 2006-05-12 | 2007-11-22 | Sunbeam Corporation Limited | Improved temperature sensor for an electric heating vessel |
US20090001070A1 (en) * | 2007-06-28 | 2009-01-01 | Strix Limited | Liquid heating vessels |
US20090114637A1 (en) * | 2006-06-05 | 2009-05-07 | Seb S.A. | Household appliance for heating liquid |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19536199C2 (en) | 1995-09-28 | 1997-11-06 | Endress Hauser Gmbh Co | Procedure for setting the switching point in a capacitive level switch |
GB2429124B (en) * | 2005-08-11 | 2010-10-20 | Otter Controls Ltd | Scale detection on water heating elements |
CN102187292A (en) * | 2007-11-07 | 2011-09-14 | 奥特控制有限公司 | Liquid heating vessel and control |
CN101561307B (en) * | 2009-05-21 | 2011-10-26 | 晶辉电器(深圳)有限公司 | Electronic device for detecting and displaying liquid position and application method thereof |
-
2009
- 2009-11-17 GB GB0920033A patent/GB2475324A/en not_active Withdrawn
-
2010
- 2010-11-16 WO PCT/GB2010/002106 patent/WO2011061482A1/en active Application Filing
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3784788A (en) * | 1971-05-04 | 1974-01-08 | Belling & Co Ltd | Electric liquid boiling apparatus having an electronic temperature sensor control |
GB2194107A (en) * | 1986-06-23 | 1988-02-24 | Proctor Silex Canada Inc | Electronic kettle |
GB2344045A (en) * | 1997-10-10 | 2000-05-31 | Bsh Bosch Siemens Hausgeraete | Electrical kettle with means to inhibit heating if over filled |
GB2358530A (en) * | 2000-01-24 | 2001-07-25 | Otter Controls Ltd | Temperature responsive control circuit for an electric kettle |
GB2358789A (en) * | 2000-02-07 | 2001-08-08 | Otter Controls Ltd | Liquid heating device with excessive or insufficient water level protection means. |
US20040149729A1 (en) * | 2001-06-09 | 2004-08-05 | Frank Kressmann | Method for heating liquid in an electric kettle |
GB2407478A (en) * | 2003-10-28 | 2005-05-04 | Tarquin Andrew Richard Stehle | Electronically-controlled domestic kettle |
GB2432212A (en) * | 2005-11-15 | 2007-05-16 | Crastal Technology | Method of detecting boil condition in a kettle |
WO2007131271A1 (en) * | 2006-05-12 | 2007-11-22 | Sunbeam Corporation Limited | Improved temperature sensor for an electric heating vessel |
US20090114637A1 (en) * | 2006-06-05 | 2009-05-07 | Seb S.A. | Household appliance for heating liquid |
US20090001070A1 (en) * | 2007-06-28 | 2009-01-01 | Strix Limited | Liquid heating vessels |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2498823A (en) * | 2012-07-03 | 2013-07-31 | Robert Hill | A water heater which is controllable through a wireless network |
GB2498823B (en) * | 2012-07-03 | 2013-12-11 | Robert Hill | A water heater |
US9516968B2 (en) | 2012-07-03 | 2016-12-13 | Appkettle Limited | Water heater |
US10418723B1 (en) | 2017-12-05 | 2019-09-17 | Rockwell Collins, Inc. | Dual polarized circular or cylindrical antenna array |
Also Published As
Publication number | Publication date |
---|---|
WO2011061482A1 (en) | 2011-05-26 |
GB0920033D0 (en) | 2009-12-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
WAP | Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1) |