GB1276326A - Production of monocarboxylic acids - Google Patents

Production of monocarboxylic acids

Info

Publication number
GB1276326A
GB1276326A GB4088469A GB4088469A GB1276326A GB 1276326 A GB1276326 A GB 1276326A GB 4088469 A GB4088469 A GB 4088469A GB 4088469 A GB4088469 A GB 4088469A GB 1276326 A GB1276326 A GB 1276326A
Authority
GB
United Kingdom
Prior art keywords
rhodium
iridium
iodide
hydrogen
promotor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4088469A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1276326A publication Critical patent/GB1276326A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1276326 Carbonylation catalysts MONSANTO CO 15 Aug 1969 [15 Aug 1968] 40884/69 Addition to 1234641 Heading B1E [Also in Division C2] Catalysts comprising rhodium or iridium compounds with halogens or halogen containing substances as promotors are used in the preparation of monocarboxylic acids or esters by reacting carbon monoxide with an alcohol or halide (see Division C2). The catalyst may be in solution (liquid phase operation) or solid (vapour phase operation). The halogen may be present as a salt or co-ordination compound of the rhodium and iridium or supplied as hydrogen, alkyl, aryl, metal, ammonium, phosphonium, arsonium and stibonium halides. Inert supports such as alumina, activated carbon, clays, silica-alumina ceramics are used. Examples describe the use of rhodium chloride, [Rh(CO) 2 Cl 2 ) 2 , [Ir(CO) 2 Cl] 2 , [Rh(CO) 2 Br] 2 and Rh(PÏ 3 ) 3 Cl with hydrogen iodide as promotor, Rh(P° 3 ) 2 CoCl with methyl iodide and Rh(NO 3 ) 3 .2H 2 O with calcium iodide as promotor, and the preparation of iridium chloride with hydrogen iodide supported upon activated carbon.
GB4088469A 1968-08-15 1969-08-15 Production of monocarboxylic acids Expired GB1276326A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US75279468A 1968-08-15 1968-08-15

Publications (1)

Publication Number Publication Date
GB1276326A true GB1276326A (en) 1972-06-01

Family

ID=25027874

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4088469A Expired GB1276326A (en) 1968-08-15 1969-08-15 Production of monocarboxylic acids

Country Status (3)

Country Link
DE (1) DE1941449C3 (en)
FR (1) FR2015741A1 (en)
GB (1) GB1276326A (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989004294A1 (en) * 1987-11-02 1989-05-18 Eastman Kodak Company Process for the co-production of aromatic carboxylate and alkyl iodides
US5510524A (en) * 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
EP0728729A1 (en) 1995-02-21 1996-08-28 BP Chemicals Limited Process for purifying a carboxylic acid
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
WO2005009939A1 (en) * 2003-07-17 2005-02-03 Bp Chemicals Limited Catalyst and process for the production of acetic acid
EP2060553A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the conversion of hydrocarbons into alcohol
EP2060555A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the production of alcohol from a carbonaceous feedstock
EP2072486A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2072488A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbon to ethanol
EP2072489A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons into ethanol
EP2072487A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2186787A1 (en) 2008-11-13 2010-05-19 BP p.l.c. Hydrogenation of ethanoic acid to produce ethanol
WO2012039841A1 (en) 2010-02-02 2012-03-29 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6054334A (en) * 1983-09-02 1985-03-28 Daicel Chem Ind Ltd Preparation of carboxylic acid
DE102010040921A1 (en) 2010-09-16 2012-03-22 Basf Se Process for the preparation of acrylic acid from methanol and acetic acid
US20140121403A1 (en) 2012-10-31 2014-05-01 Celanese International Corporation Integrated Process for the Production of Acrylic Acids and Acrylates
US9120743B2 (en) 2013-06-27 2015-09-01 Celanese International Corporation Integrated process for the production of acrylic acids and acrylates

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1989004294A1 (en) * 1987-11-02 1989-05-18 Eastman Kodak Company Process for the co-production of aromatic carboxylate and alkyl iodides
US5672743A (en) * 1993-09-10 1997-09-30 Bp Chemicals Limited Process for the production of acetic acid
US5942460A (en) * 1993-09-10 1999-08-24 Bp Chemicals Limited Catalyst system
US5510524A (en) * 1995-02-21 1996-04-23 Bp Chemicals Limited Process for the production of a carboxylic acid
EP0728729A1 (en) 1995-02-21 1996-08-28 BP Chemicals Limited Process for purifying a carboxylic acid
EP0728726A1 (en) 1995-02-21 1996-08-28 BP Chemicals Limited Process for the production of a carboxylic acid
US5663430A (en) * 1995-02-21 1997-09-02 Bp Chemicals Limited Process for purifying a carboxylic acid
US5696284A (en) * 1995-06-21 1997-12-09 Bp Chemicals Limited Process for the carbonylation of alkyl alcohols and/or reactive derivatives thereof
WO2005009939A1 (en) * 2003-07-17 2005-02-03 Bp Chemicals Limited Catalyst and process for the production of acetic acid
US7915446B2 (en) 2003-07-17 2011-03-29 Bp Chemicals Limited Catalyst and process for the production of acetic acid
EP2060555A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the production of alcohol from a carbonaceous feedstock
EP2060553A1 (en) 2007-11-14 2009-05-20 BP p.l.c. Process for the conversion of hydrocarbons into alcohol
EP2746247A1 (en) 2007-11-14 2014-06-25 BP p.l.c. An improved process for the production of alcohol from a carbonaceous feedstock
EP2072486A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2072488A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbon to ethanol
EP2072489A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons into ethanol
EP2072487A1 (en) 2007-12-17 2009-06-24 BP p.l.c. Process for the conversion of hydrocarbons to ethanol
EP2186787A1 (en) 2008-11-13 2010-05-19 BP p.l.c. Hydrogenation of ethanoic acid to produce ethanol
US8524954B2 (en) 2008-11-13 2013-09-03 Bp P.L.C. Hydrogenation of ethanoic acid to produce ethanol
WO2012039841A1 (en) 2010-02-02 2012-03-29 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed

Also Published As

Publication number Publication date
DE1941449B2 (en) 1978-11-23
FR2015741A1 (en) 1970-04-30
DE1941449A1 (en) 1970-03-19
DE1941449C3 (en) 1979-07-26

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years