FR2824066B1 - Composante catalytique solide de type metallocene et son procede d'obtention - Google Patents

Composante catalytique solide de type metallocene et son procede d'obtention

Info

Publication number
FR2824066B1
FR2824066B1 FR0105805A FR0105805A FR2824066B1 FR 2824066 B1 FR2824066 B1 FR 2824066B1 FR 0105805 A FR0105805 A FR 0105805A FR 0105805 A FR0105805 A FR 0105805A FR 2824066 B1 FR2824066 B1 FR 2824066B1
Authority
FR
France
Prior art keywords
catalytic component
solid catalytic
metallocene type
obtaining same
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0105805A
Other languages
English (en)
Other versions
FR2824066A1 (fr
Inventor
Frederic Bortolussi
Christophe Boisson
Roger Spitz
Jean Malinge
Jean Pierre Broyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atofina SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina SA filed Critical Atofina SA
Priority to FR0105805A priority Critical patent/FR2824066B1/fr
Priority to EP02735509A priority patent/EP1397399A1/fr
Priority to JP2002585492A priority patent/JP2004534869A/ja
Priority to PCT/FR2002/001463 priority patent/WO2002088195A1/fr
Priority to US10/476,152 priority patent/US7060767B2/en
Publication of FR2824066A1 publication Critical patent/FR2824066A1/fr
Application granted granted Critical
Publication of FR2824066B1 publication Critical patent/FR2824066B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
FR0105805A 2001-04-30 2001-04-30 Composante catalytique solide de type metallocene et son procede d'obtention Expired - Fee Related FR2824066B1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
FR0105805A FR2824066B1 (fr) 2001-04-30 2001-04-30 Composante catalytique solide de type metallocene et son procede d'obtention
EP02735509A EP1397399A1 (fr) 2001-04-30 2002-04-26 Composante catalytique supporte de type metallocene et son procede d'obtention
JP2002585492A JP2004534869A (ja) 2001-04-30 2002-04-26 支持されたメタロセン触媒成分及びそれを得る方法
PCT/FR2002/001463 WO2002088195A1 (fr) 2001-04-30 2002-04-26 Composante catalytique supporte de type metallocene et son procede d'obtention
US10/476,152 US7060767B2 (en) 2001-04-30 2002-04-26 Supported metallocene catalytic component and method for obtaining same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0105805A FR2824066B1 (fr) 2001-04-30 2001-04-30 Composante catalytique solide de type metallocene et son procede d'obtention

Publications (2)

Publication Number Publication Date
FR2824066A1 FR2824066A1 (fr) 2002-10-31
FR2824066B1 true FR2824066B1 (fr) 2004-02-06

Family

ID=8862850

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0105805A Expired - Fee Related FR2824066B1 (fr) 2001-04-30 2001-04-30 Composante catalytique solide de type metallocene et son procede d'obtention

Country Status (5)

Country Link
US (1) US7060767B2 (fr)
EP (1) EP1397399A1 (fr)
JP (1) JP2004534869A (fr)
FR (1) FR2824066B1 (fr)
WO (1) WO2002088195A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2824066B1 (fr) 2001-04-30 2004-02-06 Atofina Composante catalytique solide de type metallocene et son procede d'obtention
WO2013118140A2 (fr) * 2012-02-08 2013-08-15 Reliance Industries Ltd Immobilisation de catalyseur monosite sur support d'oxyde inorganique pour la préparation de polyéthylène de très haute masse moléculaire

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4147664A (en) * 1975-10-24 1979-04-03 Pomogailo Anatoly D Catalyst of polymerization, copolymerization and oligomerization of olefins and drolefins
DE2727245C3 (de) * 1977-06-16 1980-06-26 Brintzinger, Hans, Prof. Dr., 7750 Konstanz Polymergebundene CyclopentadienylÜbergangsmetall-Verbindungen und ihre Ligand-Substitutions-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
CA1268754A (fr) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Catalyseur de polymerisation sur support
US5202398A (en) * 1987-06-05 1993-04-13 Hoechst Aktiengesellschaft Process for the preparation of a 1-olefin polymer
US5312938A (en) * 1990-09-20 1994-05-17 The Dow Chemical Company Homogeneous catalysts and olefin polymerization process
US5587439A (en) * 1995-05-12 1996-12-24 Quantum Chemical Corporation Polymer supported catalyst for olefin polymerization
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
FI961511A (fi) * 1996-04-03 1997-10-04 Mikrokemia Oy Menetelmä olefiinien polymerointikatalyyttien valmistamiseksi
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
KR100205738B1 (ko) 1996-07-26 1999-07-01 이정국 담지체 계류 담지 촉매 및 그 제조 방법
NO318716B1 (no) 1996-10-31 2005-05-02 Repsol Quimica Sa Katalysatorsystem for polymerisering
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
FR2824066B1 (fr) 2001-04-30 2004-02-06 Atofina Composante catalytique solide de type metallocene et son procede d'obtention

Also Published As

Publication number Publication date
JP2004534869A (ja) 2004-11-18
WO2002088195A1 (fr) 2002-11-07
EP1397399A1 (fr) 2004-03-17
US20040147692A1 (en) 2004-07-29
US7060767B2 (en) 2006-06-13
FR2824066A1 (fr) 2002-10-31

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Legal Events

Date Code Title Description
TP Transmission of property
ST Notification of lapse

Effective date: 20141231