FR2811864A1 - Textile material containing encapsulated antiparasitic agent, useful e.g. as part of a collar or harness to provide long-lasting protection of animals against fleas and ticks - Google Patents

Textile material containing encapsulated antiparasitic agent, useful e.g. as part of a collar or harness to provide long-lasting protection of animals against fleas and ticks Download PDF

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Publication number
FR2811864A1
FR2811864A1 FR0009536A FR0009536A FR2811864A1 FR 2811864 A1 FR2811864 A1 FR 2811864A1 FR 0009536 A FR0009536 A FR 0009536A FR 0009536 A FR0009536 A FR 0009536A FR 2811864 A1 FR2811864 A1 FR 2811864A1
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FR
France
Prior art keywords
textile material
collar
microcapsules
ticks
harness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
FR0009536A
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French (fr)
Inventor
Xavier Joubert
Thierry Joubert
Pierre Delvoye
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Joubert Productions
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Joubert Productions
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Filing date
Publication date
Application filed by Joubert Productions filed Critical Joubert Productions
Priority to FR0009536A priority Critical patent/FR2811864A1/en
Publication of FR2811864A1 publication Critical patent/FR2811864A1/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K27/00Leads or collars, e.g. for dogs
    • A01K27/007Leads or collars, e.g. for dogs with insecticide-dispensing means
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/26Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
    • A01N25/28Microcapsules or nanocapsules
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12Processes in which the treating agent is incorporated in microcapsules

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Textile Engineering (AREA)
  • Zoology (AREA)
  • Dentistry (AREA)
  • Toxicology (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Animal Husbandry (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

A textile material for releasing antiparasitic agents (A) (specifically insect repellents or bacteria repellents) contains (A) in capsules or microcapsules, incorporated by impregnation with an aqueous medium also containing a binder.

Description

MATERIAU TEXTILE A PROPRIETES ANTI-PARASITAIRESTEXTILE MATERIAL WITH PEST CONTROL PROPERTIES

L'invention concenle un matériau textile susceptible de libérer des substances  The invention relates to a textile material capable of releasing substances

insectiflugcs, bactérifuges et dc manière générale anti-parasitaires.  insect repellents, bactericides and generally anti-parasitic.

Plus spécifiquement, l'invention trouve son application tout particulièrement dans le domaine animal, o les problèmes liés à l'éradication des parasites de toute nature sont  More specifically, the invention finds its application very particularly in the animal field, where the problems linked to the eradication of parasites of all kinds are

le plus aigus.the most acute.

A ce jour, un certain nombre de solutions existe pour tenter de lutter contre ces parasites. Tout d'abord, ont été développés des colliers antitiques et anti-puces, placés  To date, a number of solutions exist to try to fight against these parasites. First, anti-flea and anti-flea collars were developed, placed

au niveau du cou, notamment des chiens et des chats.  at the neck, especially dogs and cats.

Ces colliers sont imprégnés d'une substance visant à éloigner les parasites. Tout d'abord, si ce type de collier est efficace, cette efficacité est limitée dans le temps, compte-tenu que le matériau constitutif du collier, en général en plastique ou polyuréthanne est simplement imprégné de la substance active, de sorte qu'afin de disposer d'un effet actif durable dans le temps, il est nécessaire de procéder au renouvellement périodique de celui-ci, typiquement de deux mois. Par ailleurs, l'action de tels colliers est souvent très localisée, notamment dans les zones voisines du cou, et  These collars are impregnated with a substance intended to repel the parasites. First of all, if this type of collar is effective, this effectiveness is limited in time, given that the constituent material of the collar, generally plastic or polyurethane is simply impregnated with the active substance, so that in order to have an active effect lasting over time, it is necessary to periodically renew it, typically two months. Furthermore, the action of such collars is often very localized, in particular in the areas adjacent to the neck, and

n'assurent donc pas une protection intégrale de l'animal.  therefore do not provide full protection for the animal.

On a également proposé des tapis pour animaux, doués de propriétés antipuces et anti-  We have also proposed carpets for animals, endowed with flea and anti

tiques (voir par exemple FR-A-2 608 368) consistant à mélanger un produit insecticide avec du latex, assurant de la sorte la réalisation d'une mousse, générant un certain nombre de pores saturés par le produit actif. De tels tapis ont également été décrits  ticks (see for example FR-A-2 608 368) consisting in mixing an insecticide product with latex, thereby ensuring the production of a foam, generating a certain number of pores saturated with the active product. Such carpets have also been described

dans le document US-A-3 565 040.in document US-A-3,565,040.

Une nouvellc fois, on déplore avec ce genre de tapis le caractère limité dans le temps  Once again, we deplore with this kind of carpet the character limited in time

et donc tout particulièrement éphémère de l'activité du principe actif.  and therefore particularly ephemeral of the activity of the active principle.

L'objet de l'invention est de proposer un dispositif tout aussi simple à mettre en oeuvre que les solutions proposées de l'art antérieur, mais présentant une pérennité bien  The object of the invention is to provide a device which is just as simple to implement as the solutions proposed in the prior art, but which has a good durability.

supérieure dans le temps.superior in time.

2 28118642 2811864

Cc matériau textile susceptible de libérer des substances insectifuges ou bactérifuges, et dc manière plus générale, anti-parasitaires, se caractérise en ce que lesdites substances sont intégrées au sein de capsules ou microcapsules imprégnées sur ledit  Cc textile material capable of releasing insect repellant or bacterifuge substances, and more generally, anti-parasitic, is characterized in that said substances are integrated within capsules or microcapsules impregnated on said

matériau au moyen d'une solution aqueuse, additionnée d'un liant.  material by means of an aqueous solution, added with a binder.

De la sorte, le principe actif contenu dans les microcapsules ne se libère que lors d'actions spécifiques du porteur du matériau, notamment par grattage, frottement, cisaillement, induisant la rupture desdites microcapsules et partant la libération du  In this way, the active principle contained in the microcapsules is only released during specific actions of the carrier of the material, in particular by scraping, friction, shearing, inducing the rupture of said microcapsules and consequently the release of the

principc actif considéré.principal active considered.

Selon une caractéristique de l'invention, ces microcapsules ont un diamètre typique  According to a characteristic of the invention, these microcapsules have a typical diameter

compris entre 0,5 et 20 micromètres.  between 0.5 and 20 micrometers.

Par ailleurs, la membrane d'encapsulation est réalisée en aminoplaste, c'est à dire à  Furthermore, the encapsulation membrane is made of aminoplast, that is to say

base d'un complexe urée/formaldehydes ou mélamine/formaldehyde.  base of a urea / formaldehydes or melamine / formaldehyde complex.

Le support textile peut être de toute nature, notamment tissée, tricotée voire tressée.  The textile support can be of any kind, in particular woven, knitted or even braided.

Il va être décrit ci-après plus en détail un mode de réalisation particulier d'une sangle  A particular embodiment of a strap will be described below in more detail.

tissée conforme à la présente invention.  woven according to the present invention.

Une telle sangle est réalisée sur un métier classique à aiguilles, de type MULLER,  Such a strap is produced on a conventional needle loom, of the MULLER type,

voire, lorsqu'on souhaite y ajouter un motif décoratif sur un métier type Jacquard.  or even, when you want to add a decorative motif on a Jacquard type loom.

Cette technique est largement éprouvée, et tout à fait à la portée de l'homme du métier de sorte qu'il n'y a pas lieu de la décrire ici plus en détail. Cette sangle est par exemple  This technique is widely proven, and quite within the reach of the skilled person so there is no need to describe it here in more detail. This strap is for example

réalisée cn polyamide 6, 6, et présente une largeur typique de deux centimètres.  made of polyamide 6, 6, and has a typical width of two centimeters.

Parallèlement, la sauce d'enduction comprenant les microcapsules renfermant un  At the same time, the coating sauce comprising the microcapsules containing a

principe actif, notamment destiné à lutter contre les puces et les parasites, est réalisée.  active ingredient, in particular intended to fight against fleas and parasites, is produced.

Ce principe actif est lui-même réalisé à base d'huile esentielle de citronnelle, d'huile  This active ingredient is itself made from essential oil of lemongrass, oil

essentielle de géranium, d'allethrine et d'huile végétale QSP.  essential oil of geranium, allethrine and vegetable oil QSP.

Ce mélange est dispersé selon une solution aqueuse contenant les précurseurs d'une résine aminoplaste, typiquement constitué d'un complexe formaldéhyde - urée ou  This mixture is dispersed in an aqueous solution containing the precursors of an aminoplast resin, typically consisting of a formaldehyde - urea or

formaldéhyde - mélamine.formaldehyde - melamine.

L'addition d'un acide catalyseur démarre la polycondensation des précurseurs d'aminioplastc. Il se fonnme autour des gouttelettes de produit actif une membrane solide et résistance, susceptible dc présenter un diamètre compris entre 0,5 et 20 micromètres. Les microcapsules ainsi obtenues sont dispersées dans une solution aqueuse, à laquelle est ajouté un liant d'apprêt, dont la composition est fonction de la nature du matériau  The addition of a catalyst acid starts the polycondensation of the precursors of aminioplastc. It forms around the droplets of active product a solid and resistant membrane, capable of having a diameter of between 0.5 and 20 micrometers. The microcapsules thus obtained are dispersed in an aqueous solution, to which a primer binder is added, the composition of which depends on the nature of the material.

constitutif de la sangle.constituting the strap.

Dans l'exemple décrit, dans lequel ladite sangle est réalisée en polyamide 6,6, on peut par exemple mettre en oeuvre un liant commercialisé sous la marque déposée  In the example described, in which said strap is made of polyamide 6,6, it is possible for example to use a binder sold under the registered trademark

RHENAPPRET/AS par la société THOR.  RHENAPPRET / AS by the company THOR.

Ainsi, le bain d'apprêt présente-t'il dans l'exemple décrit la composition suivante en poids: * microcapsules 13.5 % * liant d'apprêt 4, 5 % * eau 82 % La sangle réalisée précédemment est imprégnée, de manière continue, par trempage dans le bain de solution d'imprégnation ainsi réalisé, selon une vitesse typique de 2.000 mètres linéaires à l'heure, puis elle subit un foulardage puis une étape de séchage, par exemple sur tambour, dans un four à air chaud, à rayonnement infra rouge, voire par induction. Ce séchage induit l'évaporation de l'cau et corollairement  Thus, in the example described, the primer bath presents the following composition by weight: * microcapsules 13.5% * primer binder 4, 5% * water 82% The strap produced previously is continuously impregnated , by soaking in the impregnation solution bath thus produced, at a typical speed of 2,000 linear meters per hour, then it undergoes a padding then a drying step, for example on a drum, in a hot air oven, with infrared radiation, or even by induction. This drying induces the evaporation of the water and consequently

la tixation des microcapsules sur la sangle par polymérisation du liant d'apprêt.  the fixing of the microcapsules on the strap by polymerization of the primer binder.

On obtient de fait, après séchage, une sangle à laquelle adhère une certaine quantité de microcapsules (dans l'exemple décrit, la quantité de produit sec emporté après les différentes phases de traitement est de l'ordre de 2 à 4 % en poids du mélange d'apprêt), dont la rupture, notamment par contact, par friction, par écrasement, cisaillement, provoque la libération du principe actif, permettant ainsi de disposer  In fact, after drying, a strap is obtained to which a certain quantity of microcapsules adheres (in the example described, the quantity of dry product carried away after the various treatment phases is of the order of 2 to 4% by weight of the primer mixture), the rupture of which, in particular by contact, by friction, by crushing, shearing, causes the release of the active principle, thus allowing to have

d'une plus grande péremfité, donc une plus grande efficacité du produit dans le temps.  greater durability, therefore greater product efficiency over time.

En effet, de par le mode de " stockage " du principe actif mis en oeuvre, il n'y a plus libération permanente, continue et non contrôlée de celuici, mais diffusion discrète,  Indeed, by the mode of "storage" of the active principle used, there is no longer permanent, continuous and uncontrolled release of it, but discreet diffusion,

fonction du nombre et de l'instant de rupture desdites microcapsules.  depending on the number and the instant of rupture of said microcapsules.

4 28118644 2811864

Compte tenu en outre de la diminution importante des coûts inhérents à la réalisation des microcapsules d'une part. et de la simplicité de la technique d'imprégnation d'autre part, on aboutit à la réalisation de supports de matériaux doués de propriétés  In addition, given the significant reduction in costs inherent in the production of microcapsules on the one hand. and the simplicity of the impregnation technique, on the other hand, it results in the production of supports for materials endowed with properties

anti parasitaires à très lfaiblc coûts et selon des cadences élevées.  anti parasitic at very low costs and at high rates.

Lcs applications envisagées sont notamment constituées par les colliers, laisses, couvertures et manteaux pour animaux, sangles, etc. Elles concernent également les  The applications envisaged are in particular constituted by collars, leashes, blankets and coats for animals, straps, etc. They also relate to

harnais, brides, licols, et autres éléments équivalents.  harnesses, straps, halters, and the like.

28118642811864

Claims (5)

REVENDICATIONS 1. Matériau textile susceptible d(le libérer des substances insectifuges ou bacténrifuges, et de manière plus générale, susceptible de développer des propriétés anti-parasitaires, caractérisé en ce que lesdites substances sont intégrées au sein de capsules ou microcapsules imprégnées sur ledit matériau au  1. Textile material capable of releasing it from insect repellent or bacteria-repellent substances, and more generally, capable of developing anti-parasitic properties, characterized in that said substances are integrated within capsules or microcapsules impregnated on said material with moyen d'une solution aqueuse, additionnée d'un liant.  using an aqueous solution, added with a binder. 2. Matériau textile selon la revendication 1, caractérisé en ce que les microcapsules  2. Textile material according to claim 1, characterized in that the microcapsules ont un diamètre typique compris entre 0,5 et 20 micromètres.  have a typical diameter between 0.5 and 20 micrometers. 3. Matériau textile selon l'une des revendications I et 2, caractérisé en ce que la  3. Textile material according to one of claims I and 2, characterized in that the membrane d'encapsulation des microcapsules est réalisée en résine aminoplaste.  microcapsule encapsulation membrane is made of aminoplast resin. 4. Matériau textile selon l'une des revendications I à 3, caractérisé en ce que le  4. Textile material according to one of claims I to 3, characterized in that the support textile est un tissé, un tricoté voire un tressé.  textile support is a woven, knitted or even braided. 5. Matériau textile selon l'une des revendications I à 4, caractérisé en ce qu'il  5. Textile material according to one of claims I to 4, characterized in that it constitue la base d'éléments appartenant au groupe comprenant les colliers,  constitutes the basis of elements belonging to the group including the necklaces, laisses, sangles, brides, licols, harnais.  leashes, straps, straps, halters, harnesses.
FR0009536A 2000-07-20 2000-07-20 Textile material containing encapsulated antiparasitic agent, useful e.g. as part of a collar or harness to provide long-lasting protection of animals against fleas and ticks Pending FR2811864A1 (en)

Priority Applications (1)

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FR0009536A FR2811864A1 (en) 2000-07-20 2000-07-20 Textile material containing encapsulated antiparasitic agent, useful e.g. as part of a collar or harness to provide long-lasting protection of animals against fleas and ticks

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FR0009536A FR2811864A1 (en) 2000-07-20 2000-07-20 Textile material containing encapsulated antiparasitic agent, useful e.g. as part of a collar or harness to provide long-lasting protection of animals against fleas and ticks

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FR2811864A1 true FR2811864A1 (en) 2002-01-25

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2385789A (en) * 2002-02-25 2003-09-03 Celessence Internat Ltd Frangible, insect repellent containing microcapsules
WO2003071871A1 (en) * 2002-02-26 2003-09-04 Terra Nostra Produkte Mit Naturextrakten Gmbh Substrate, especially textile substrate, and method for producing the same
WO2005005712A2 (en) * 2003-07-14 2005-01-20 Koninklijke Philips Electronics N.V. Compound and method of applying additives to fabrics, microcapsule, and method for preparing said compound
GB2434592A (en) * 2006-01-27 2007-08-01 Intelligent Fabric Technologie Fabrics comprising insect repellent containing microcapsules
WO2010088745A2 (en) * 2009-02-06 2010-08-12 Rudiger Cruysberghs Textile with biocontrolling properties
US10479963B2 (en) 2009-06-09 2019-11-19 Devan Chemicals Nv Microcapsules containing microorganisms

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH023602A (en) * 1988-06-14 1990-01-09 Kanebo Ltd Vermin-proofing microcapsule and vermin-proofing fiber
JPH032101A (en) * 1989-05-31 1991-01-08 Hosokawa Kigyo Kk Insecticidal cloth
JPH0390682A (en) * 1989-09-01 1991-04-16 Toyobo Co Ltd Fiber product having moth-proof property
WO1991010772A1 (en) * 1990-01-18 1991-07-25 British Textile Technology Group Treating materials
WO1998023149A1 (en) * 1996-11-26 1998-06-04 Stephen Baker Mosquito-repellent band

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH023602A (en) * 1988-06-14 1990-01-09 Kanebo Ltd Vermin-proofing microcapsule and vermin-proofing fiber
JPH032101A (en) * 1989-05-31 1991-01-08 Hosokawa Kigyo Kk Insecticidal cloth
JPH0390682A (en) * 1989-09-01 1991-04-16 Toyobo Co Ltd Fiber product having moth-proof property
WO1991010772A1 (en) * 1990-01-18 1991-07-25 British Textile Technology Group Treating materials
WO1998023149A1 (en) * 1996-11-26 1998-06-04 Stephen Baker Mosquito-repellent band

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch Week 199107, Derwent World Patents Index; Class A87, AN 1991-048801, XP002165542 *
DATABASE WPI Section Ch Week 199121, Derwent World Patents Index; Class A87, AN 1991-154081, XP002165541 *
PATENT ABSTRACTS OF JAPAN vol. 014, no. 126 (C - 0699) 9 March 1990 (1990-03-09) *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2385789A (en) * 2002-02-25 2003-09-03 Celessence Internat Ltd Frangible, insect repellent containing microcapsules
WO2003071871A1 (en) * 2002-02-26 2003-09-04 Terra Nostra Produkte Mit Naturextrakten Gmbh Substrate, especially textile substrate, and method for producing the same
WO2005005712A2 (en) * 2003-07-14 2005-01-20 Koninklijke Philips Electronics N.V. Compound and method of applying additives to fabrics, microcapsule, and method for preparing said compound
WO2005005712A3 (en) * 2003-07-14 2005-05-12 Koninkl Philips Electronics Nv Compound and method of applying additives to fabrics, microcapsule, and method for preparing said compound
GB2434592A (en) * 2006-01-27 2007-08-01 Intelligent Fabric Technologie Fabrics comprising insect repellent containing microcapsules
GB2434592B (en) * 2006-01-27 2009-06-24 Intelligent Fabric Technologies Plc Fabrics and Materials Comprising Insect Repellent-Containing Microcapsules
US7887826B2 (en) 2006-01-27 2011-02-15 Intelligent Fabic Technologies PLC Insect repellent fabric
WO2010088745A2 (en) * 2009-02-06 2010-08-12 Rudiger Cruysberghs Textile with biocontrolling properties
WO2010088745A3 (en) * 2009-02-06 2010-12-16 Rudiger Cruysberghs Textile with biocontrolling properties
US10479963B2 (en) 2009-06-09 2019-11-19 Devan Chemicals Nv Microcapsules containing microorganisms

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