DE18068C - Process to prevent the coagulation of the protein in the presence of alkaline earth or metal salts in protein substance solutions that have been prepared with caustic alkalis - Google Patents
Process to prevent the coagulation of the protein in the presence of alkaline earth or metal salts in protein substance solutions that have been prepared with caustic alkalisInfo
- Publication number
- DE18068C DE18068C DENDAT18068D DE18068DA DE18068C DE 18068 C DE18068 C DE 18068C DE NDAT18068 D DENDAT18068 D DE NDAT18068D DE 18068D A DE18068D A DE 18068DA DE 18068 C DE18068 C DE 18068C
- Authority
- DE
- Germany
- Prior art keywords
- protein
- prevent
- coagulation
- prepared
- alkaline earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 150000003839 salts Chemical class 0.000 title claims description 8
- 102000004169 proteins and genes Human genes 0.000 title claims description 5
- 108090000623 proteins and genes Proteins 0.000 title claims description 5
- 229910052751 metal Inorganic materials 0.000 title claims description 4
- 239000002184 metal Substances 0.000 title claims description 4
- 239000003518 caustics Substances 0.000 title claims description 3
- 230000015271 coagulation Effects 0.000 title claims description 3
- 238000005345 coagulation Methods 0.000 title claims description 3
- 238000000034 method Methods 0.000 title claims description 3
- 239000000126 substance Substances 0.000 title description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 7
- PRORZGWHZXZQMV-UHFFFAOYSA-N azane;nitric acid Chemical compound N.O[N+]([O-])=O PRORZGWHZXZQMV-UHFFFAOYSA-N 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 102000009027 Albumins Human genes 0.000 description 2
- 108010088751 Albumins Proteins 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000013372 meat Nutrition 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 102000009123 Fibrin Human genes 0.000 description 1
- 108010073385 Fibrin Proteins 0.000 description 1
- BWGVNKXGVNDBDI-UHFFFAOYSA-N Fibrin monomer Chemical compound CNC(=O)CNC(=O)CN BWGVNKXGVNDBDI-UHFFFAOYSA-N 0.000 description 1
- 241000322338 Loeseliastrum Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 229910052601 baryte Inorganic materials 0.000 description 1
- 239000010428 baryte Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 229950003499 fibrin Drugs 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- -1 leiokom Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
- D06M15/155—Treatment in the presence of salts derived from amphoteric metal hydroxides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
PATENTSCHRIFTPATENT LETTERING
KLASSE 8: Bleichen, Färben, Zeugdruck und Appretur.CLASS 8: Bleaching, dyeing, fabric printing and finishing.
EMIL Ritter von PORTHEIM in SMICHOW bei PRAG.EMIL Ritter von PORTHEIM in SMICHOW near PRAGUE.
Patentirt im Deutschen Reiche vom 20. April 1881 ab.Patented in the German Empire on April 20, 1881.
Dieses Verfahren dient zur Herstellung von Verdickimgs- und Klebemitteln, sowie Appreturmassen im allgemeinen, welche Stärke, Dextrin, Leiokom, Gummi u. dergL in der Zeugdruckerei, Papierfabrikation etc. ersetzen sollen, aus den Lösungen, welche von animalischen oder vegetabilischen Protemstoffen mit Aetzkalien bereitet sind, durch Zusatz der Salze von alkalischen Erden und Metallen unter Hinzugabe von oxalsaurem Alkali oder salpetersaurem Ammon.This process is used for the production of thickeners and adhesives, as well as finishing compounds in general, which starch, dextrin, leiokom, gum and the like in the stuff printing shop, To replace paper production, etc., from the solutions, which of animal or vegetable Protem substances with caustic substances are prepared by adding the salts of alkaline substances Earths and metals with the addition of oxalic acid alkali or nitric acid ammonium.
1000 g trockene Prote'instoffe, und zwar Fleisch, Fleischrückstände, Casein, Fibrin, Kleber, Protein des Erdnufs- und Rapskuchenmehls etc., werden mit 10 1 Wasser und 54 g Natronhydrat ca. 18 Stunden lang im Wasserbade erhitzt'. Die erhaltene Lösung läfst man durch ein Sieb laufen; sollte die Lösung nicht vollkommen neutral sein, so neutralisirt man sie unter fleifsigem Umrühren mit verdünnter Essigsäure oder Salzsäure, so lange sie noch warm ist.1000 g of dry protein substances, namely Meat, meat residues, casein, fibrin, Glue, protein from peanut and rapeseed cake flour, etc., are mixed with 10 l of water and 54 g Sodium hydrate heated in a water bath for about 18 hours'. The solution obtained is run pass through a sieve; if the solution is not perfectly neutral, it is neutralized while carefully stirring with dilute acetic acid or hydrochloric acid, while it is still warm.
Das so erhaltene Product kann direct in Lösung verwendet oder auf Zinkblechen oder Porcellanplatten bei 25 bis 300 eingetrocknet werden. Das getrocknete Product bleibt vollkommen löslich, und sind beim Auflösen dieselben Vorsichtsmafsregeln zu beachten wie beim Lösen des Blutalbumins.The product thus obtained can be directly used in solution or can be dried onto plates or zinc Porcellanplatten at 25 to 30 0th The dried product remains completely soluble, and the same precautions should be observed when dissolving as when dissolving the blood albumin.
Anstatt des Natronhydrats kann man auch Kalihydrat benutzen.Instead of sodium hydrate, you can also use potassium hydrate.
Die Verwendung dieses Productes sichert bei niedrigem Preise der Lösung und geringerem Trockengehalt dieselbe voluminöse Beschaffenheit, Klebkraft und Elasticität wie die bisher zu gleichem Zwecke verwendeten Materialien und giebt als Appreturmittel den Geweben einen bedeutend höheren Glanz. Gleich der Stärke ist es bei sauren Farben nicht verwendbar.The use of this product secures the solution at a low price and less Dry content the same voluminous consistency, adhesive strength and elasticity as before materials used for the same purpose and gives the fabrics a finishing agent significantly higher gloss. Like its strength, it cannot be used with acidic colors.
Bei Gegenwart von Kalk-, Baryt-, Thonerde, Zinksalzen und den löslichen Salzen der schweren Metalle setzt man, um ein Coaguliren zu verhindern, solche Salze hinzu, welche, wie in der analytischen Chemie bekannt, die Fällung dieser Salze durch zweibasische Säuren oder deren lösliche Salze verlangsamen oder verhindern, oder solche Salze, welche in der Kattundruckerei allgemein als lösende Reservagen unter Albuminfarben verwendet werden. Als solche Zusätze lassen sich beispielsweise verwenden oxalsaures Alkali bei Gegenwart von Thonerde, Ammonsalze wie salpetersaures Ammon bei Gegenwart von Kalk etc.In the presence of lime, barite, alumina, zinc salts and the soluble salts of the heavy ones To prevent coagulation of metals, salts are added which, as in the analytical chemistry known, the precipitation of these salts by dibasic acids or their Soluble salts slow down or prevent, or those salts which are used in calico printing generally used as solvent reserves under albumin paints. As such additives For example, oxalate can be used in the presence of alumina, ammonium salts like ammonium nitric acid in the presence of lime etc.
Die weitere \rerwendung ist ganz dieselbe wie bei Stärke, Gummi etc.The more \ r Before Using is quite the same as starch, gum etc.
Das Product wird in der Zeugdruckerei zum Verdicken und Appretiren, zum Leimen von Papier, in der Tapetendruckerei, zum Glasiren von Papier, in der Lederfärberei, Buchbinderei etc. angewendet.The product is used in the stuff printing shop for thickening and finishing, for gluing Paper, in wallpaper printing, for glazing paper, in leather dyeing, bookbinding, etc. applied.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE18068C true DE18068C (en) |
Family
ID=294967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT18068D Active DE18068C (en) | Process to prevent the coagulation of the protein in the presence of alkaline earth or metal salts in protein substance solutions that have been prepared with caustic alkalis |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE18068C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2996531A (en) * | 1957-07-01 | 1961-08-15 | American Cyanamid Co | Preparation of alkylcarbamoylmethyl dimethylphosphorodithioates |
| US3013940A (en) * | 1957-06-03 | 1961-12-19 | Montedison Spa | Organo-mercapto-methyleneamides of o, o-dialkyl-thio(or dithio)-phosphorylacetic acids having pesticidal activity |
-
0
- DE DENDAT18068D patent/DE18068C/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3013940A (en) * | 1957-06-03 | 1961-12-19 | Montedison Spa | Organo-mercapto-methyleneamides of o, o-dialkyl-thio(or dithio)-phosphorylacetic acids having pesticidal activity |
| US2996531A (en) * | 1957-07-01 | 1961-08-15 | American Cyanamid Co | Preparation of alkylcarbamoylmethyl dimethylphosphorodithioates |
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