DE1621304A1 - Method and device for the continuous combined annealing and coating of metal wire - Google Patents
Method and device for the continuous combined annealing and coating of metal wireInfo
- Publication number
- DE1621304A1 DE1621304A1 DE19671621304 DE1621304A DE1621304A1 DE 1621304 A1 DE1621304 A1 DE 1621304A1 DE 19671621304 DE19671621304 DE 19671621304 DE 1621304 A DE1621304 A DE 1621304A DE 1621304 A1 DE1621304 A1 DE 1621304A1
- Authority
- DE
- Germany
- Prior art keywords
- wire
- metal
- metal wire
- tin
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002184 metal Substances 0.000 title claims description 24
- 229910052751 metal Inorganic materials 0.000 title claims description 24
- 238000000034 method Methods 0.000 title claims description 17
- 238000000137 annealing Methods 0.000 title claims description 13
- 239000011248 coating agent Substances 0.000 title claims description 9
- 238000000576 coating method Methods 0.000 title claims description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 230000015271 coagulation Effects 0.000 claims description 3
- 238000005345 coagulation Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 2
- 238000007747 plating Methods 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 28
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 238000005554 pickling Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000701 coagulant Substances 0.000 description 2
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/38—Wires; Tubes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0035—Means for continuously moving substrate through, into or out of the bath
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0036—Crucibles
- C23C2/00361—Crucibles characterised by structures including means for immersing or extracting the substrate through confining wall area
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Coating With Molten Metal (AREA)
Description
Verfahren und Vorrichtung zum kontinuierlichen kombinierten Glühen und Überziehen von Metalldraht Method and apparatus for the continuous combined annealing and coating of metal wire
Die Erfindung bezieht sich auf ein Verfahren zum kontinuierlichen kombinierten Glühen und überziehen von Metalldraht, insbesondere auf ein Glüh- und Verzinnungsverfahren für Kupferdraht, demgemäss der Metalldraht mittels Hindurchleiten eines elektrischen Stromes geglüht wird, wobei der Strom an zwei im Abstand voneinander befindlichen Eontaktstellen zwecks Erhitzens des Drahtes durch Wirkung seines elektrischen Widerstandes geleitet wird, und der Metalldraht mittels Durchführen durch ein Metallbad überzogen wird. Ferner bezieht sich die Erfindung auf eine Vorrichtung zur Durchführung dieses Verfahrens. The invention relates to a method for continuous combined annealing and coating of metal wire, in particular an annealing and tinning process for copper wire, Accordingly, the metal wire is annealed by passing an electric current through it, the current being applied to two im Eontaktstellen located at a distance from one another for the purpose of heating the wire through the action of its electrical resistance and the metal wire is coated by passing it through a metal bath. Furthermore, the Invention to an apparatus for performing this method.
Bei den heutzutage allgemein üblichen Heissverzinnungsverfahren gelangt der harte Kupferdraht durch Beizungs- und Gerinnungsbäder in einen Behälter mit geschmolzenem Zinn, wo derWith the hot-tinning processes commonly used nowadays the hard copper wire passes through the pickling and coagulation baths into a container of molten tin, where the
109820/0238109820/0238
BAD ORIGINAL BATH ORIGINAL
Draht auch geglüht wird. Nach der Behandlung im Zinnbehälter wird überflüssiges- geschmolzenes Zinn von der Oberfläche· :~·'-,:-- n: des Drahtes mit verschiedenen Abstreichern, wire Korkv hitzebeständiges Gummi oder Drahtziehstein, entfernt. Danach-wird ' der Draht in Luft oder Wasser abgekühlt, getrocknet und aufgespult. " V:'"-; ■ -"'Wire is also annealed. After the treatment in tin containers überflüssiges- molten tin from the surface · is: ~ · '-, - n: the wire with various scrapers, wi r e Korkv heat-resistant rubber or the wire drawing die is removed. Then the wire is cooled in air or water, dried and wound up. " V: '"-; ■ - "'
Bei einem anderen bekannten Verfahren hat man die Forderung aufgegeben,den Draht im Zusammenhang mit der Verzinnung zu glühen. Das Glühen wird hierbei in einer besonderen Widerstandsvorrichtung entweder vor dem Heissverzinnen oder danach ausgeführt. Another known method has the requirement abandoned annealing the wire in connection with the tinning. The glow is done in a special resistance device carried out either before or after hot tinning.
Die erwähnten bekannten Verfahren weisen verschiedene Nachteile auf. Fach erstgenannten Verfahren muss aufgrund der Glühforderung des Drahtes die Temperatur des Zinns erhöht oder die Tauchstrecke verlängert, d. h. der Behälter vergr-össer-t werden, wenn man die Schnelligkeit des Drahtes steigern möchte. Die Erhöhung der Zinntemperatur führt zur vermehrten Bildung der schädlichen Kupfer-ζinnverbindung, und der Zuwachs der Behältergrösse erfordert einen grösseren Wärmeeffekt und vermehrt die Neigung der Zinriflache zum Oxydieren. Ausserdem verursacht das Einführen der Beizungs- und Gerinnungsmittel mit dem Draht in das Zinn schädliche Zinnsalze und Asche im Behälter.The known methods mentioned have various disadvantages. The first-mentioned procedure must be carried out due to the annealing requirement the wire increases the temperature of the tin or increases the immersion distance, d. H. the container is enlarged if you want to increase the speed of the wire. The increase in the tin temperature leads to increased formation the harmful copper-tin compound, and the increase in container size requires a greater heat effect and increases the tendency of the tin surface to oxidize. Also caused introducing the pickling and coagulants with the wire into the tin harmful tin salts and ash in the container.
' Bei dem anderen Verfahren treten wieder folgende Nachteile auf: Geschieht das Glühen vor dem Verzinnen, ist die VerwendungIn the other method, there are again the following disadvantages on: If the annealing is done before tinning, the use
10 98 20/0238 BADORiGtNAL10 98 20/0238 BADORiGtNAL
von Schutzgas zur Verhinderung des Oxydierens des Drahtes nötig. Ausserdem muss der Draht im Wasser nach dem Glühen abgekühlt werden, da es aus praktischen Gründen unmöglich ist, ihn völlig geschützt zum Verzinnen zu bringen. Geschieht das Glühen wieder nach dem Verzinnen, erfordert der Draht bei grösserer Schnelligkeit im Zinnbad eine längere Tauchstrecke oder höhere Zinntemperatur, da die Flächentemperatur des Drahtes wenigstens den Schmelzpunkt des Zinns erreichen muss, ehe das Zinn den Draht angreifen kann.shielding gas is necessary to prevent the wire from oxidizing. In addition, the wire has to be cooled down in the water after it has been annealed, since it is practically impossible to completely remove it to be tinned protected. If the annealing takes place again after tinning, the wire requires greater speed a longer immersion distance or higher tin temperature in the tin bath, since the surface temperature of the wire is at least the The tin must reach the melting point before the tin can attack the wire.
Die vorliegende Erfindung versucht die dargestellten Nachteile zu vermeiden. Das erfindungsgemässe Verfahren ist dadurch gekennzeichnet, dass der Metalldraht nach der ersten Kontaktstelle, jedoch vor der zweiten Kontaktstelle durch das Metallüberziehbad geführt wird.The present invention seeks to avoid the disadvantages shown. The inventive method is thereby characterized in that the metal wire passes through the metal plating bath after the first contact point, but before the second contact point to be led.
Der Vorteil des Verfahrens liegt darin, dass beim Glühen kein Schutzgas erforderlich ist, da die Zinnschicht das Kupfer vor Oxydieren schützt; Dies beruht darauf, dass die Temperatur des Metalldrahtes auf der Zwischenstrecke zwischen der ersten Kontaktstelle und dem Überziehbad noch nicht so weit angestiegen ist, dass schädliches Oxydieren vorkommen kann ,.und dass der Metalldraht auf der Strecke zwischen Überziehbad und der zweiten Kontaktstelle, wo die Temperatur des Drahtes schon genügend gestiegen ist, um ein Glühen zustandezubringen, durch den im Uberziehbad- erhaltenen Metallüberzug effektiv gegen Oxydieren geschützt ist. Die Temperatur des Zinns kann man auch so niedrigThe advantage of the process is that no protective gas is required during annealing because the tin layer is the copper protects against oxidation; This is due to the fact that the temperature of the metal wire on the intermediate distance between the first Contact point and the enrobing bath has not yet risen so far that harmful oxidation can occur, and that the metal wire on the section between the enrobing bath and the second contact point, where the temperature of the wire is already sufficient has risen to bring about a glow through which Effective against oxidation in the metal coating obtained in the coating bath is protected. The temperature of the tin can also be as low as that
109820/0238109820/0238
wie möglich und die Tauchstrecke sehr kurz halten, da die Temperatur des zu dem Zinnbehälter kommenden Drahtes annähernd dem Schmelzpunkt des Zinns entspricht. Die Bildung von schädlichen Kupferzinnverbindungen ist daher sehr gering. Ausserdem bleibt der vom -,Zinnbehälter benötigte Wärmeeffekt sehr klein, da der Draht keiner Wärmeenergie bedarf, er kann vielmehr im Gegenteil dem Zinnbehälter Wärme abgeben, statt der durch Wärmeverluste verwendeten Energie.as possible and keep the diving distance very short, as the The temperature of the wire coming to the tin container approximately corresponds to the melting point of the tin. The formation of harmful Copper tin compounds is therefore very low. Besides that the heat effect required by the tin container remains very small, Since the wire does not require any thermal energy, it can, on the contrary, give off heat to the tin container instead of through heat losses energy used.
In der Zeichnung sind Ausführungsformen der Erfindung beispielsweise dargestellt.In the drawing, embodiments of the invention are for example shown.
Es zeigen:Show it:
Fig. 1 schematisch eine kombinierte Glüh- und Metallüberziehvorrichtung, die nach dem erfindungsgemässen Verfahren arbeitet, in schematischer Darstellung, und1 schematically shows a combined annealing and metal coating device, which works according to the inventive method, in a schematic representation, and
Fig. 2 Einzelheiten des Metallbehälters nach Fig. 1 im Querschnitt.FIG. 2 shows details of the metal container according to FIG. 1 in cross section.
In Fig. i ist schematisch eine Widerstandsglühvorrichtung gezeigt, in der ein über Räder 1, 2 und 4 geleiteter Draht 3 mittels eines von einem Transformator 7 erzeugten Stromes geglüht wird. Die beiden Räder 1 und 2 besitzen verschiedene elektrische Potentiale. In einem Wasserrohr 5 zwischen den Rädern 2 und 4 wird der Draht abgekühlt. An einer Stelle zwischenIn Fig. I is a resistance annealing device schematically shown, in which a wire 3 conducted over wheels 1, 2 and 4 is annealed by means of a current generated by a transformer 7. The two wheels 1 and 2 have different ones electrical potentials. The wire is cooled in a water pipe 5 between wheels 2 and 4. At a point between
BAD ORIGiNAL BAD oRIGINAL
10 98 20/023810 98 20/0238
den Rädern 1 und 2, wo die Temperatur des Drahtes etwas über dem Schmelzpunkt des Zinns liegt, ist ein Zinnbehälter 6 angeordnet. Die Beizungs- und Gerinnungsräder können oberhalb des Zinnbehälters liegen. Andererseits hat man beim Betrieb festgestellt, dass ein Draht,der direkt von der Ziehmaschine zur Vorrichtung nach Fig. 1 geführt ist, keine Überzug- und Gerinnungsstoffe erfordert, weil das Zinn trotzdem gut den Draht angreift.wheels 1 and 2 where the temperature of the wire is slightly above is the melting point of the tin, a tin container 6 is arranged. The pickling and coagulation wheels can be placed above the Tin container. On the other hand, it has been found during operation that a wire that goes directly from the drawing machine to the Device according to Fig. 1 is performed, does not require any coating and coagulants, because the tin is still good for the wire attacks.
Der Zinnbehälter selbst ist in Fig. 2 veranschaulicht. Ein als Abstreicher arbeitender Ziehstein 8, an dem der Draht 3 vorbeiläuft, ist an einem senkrecht beweglichen Schieber 9 befestigt, der in Fig. 2 in der niedrigsten Lage dargestellt ist. Damit das geschmolzene Zinn 1 nicht aus dem Behälter austritt, sind a/us hitzebeständigem Material, z.B. Asbest, bestehende Dichtungen 10 angeordnet. Mit Hilfe eines Wärmewiderstandes 12 wird das Zinn geschmolzen, und seine Temperatur wird etwas über dem Schmelzpunkt des Zinns gehalten. Zum Durchführen des Drahtes durch den Zinnbehälter wird der Schieber 9 angehoben, so dass der Ziehstein 8 oberhalb der Zinnoberfläche zu liegen kommt. Wenn der Draht 3 nach Ingangsetzung der Maschine seine Arbeitsgeschwindigkeit erhalten hat und der Glühstrom eingeschaltet ist, schiebt man den Schieber 9 nach unten in die Lage nach Fig. 2. , . . .,,.: The tin container itself is illustrated in FIG. A drawing die 8 working as a scraper, on which the wire 3 passes, is attached to a vertically movable slide 9, which is shown in the lowest position in FIG. 2. So that the molten tin 1 does not escape from the container, existing seals 10 made of a heat-resistant material, for example asbestos, are arranged. The tin is melted with the aid of a thermal resistor 12 and its temperature is kept slightly above the melting point of the tin. To lead the wire through the tin container, the slide 9 is raised so that the drawing die 8 comes to rest above the tin surface. When the wire 3 has obtained its working speed after starting the machine and the glow current is switched on, the slide 9 is pushed down into the position according to FIG. . . ,,. :
Die Zeichnung und die dazu; gehörende Beschreibung haben nur den Zweck, die Idee der Erfindung zu veranschaulichen. InThe drawing and the one to go with it ; The purpose of this description is only to illustrate the idea of the invention. In
BADBATH
10 9820/0238 ^: 10 9820/0238 ^ :
■6" Ib^ 1304■ 6 "Ib ^ 1304
ihren Einzelheiten kann das erfindungsgemässe Verfahren und die Vorrichtung zur Durchführung desselben innerhalb des Rahmens der Patentansprüche bedeutend abgeändert werden.The method according to the invention and the device for performing the same within the Can be significantly modified within the scope of the claims.
Patentansprüche: Patent claims :
SADSAD
109820/0238109820/0238
Claims (3)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI1416/66A FI40278B (en) | 1966-05-31 | 1966-05-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1621304A1 true DE1621304A1 (en) | 1971-05-13 |
Family
ID=8505603
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19671621304 Pending DE1621304A1 (en) | 1966-05-31 | 1967-05-30 | Method and device for the continuous combined annealing and coating of metal wire |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE1621304A1 (en) |
| FI (1) | FI40278B (en) |
| GB (1) | GB1134724A (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES534131A0 (en) * | 1984-02-23 | 1985-11-01 | Australian Wire Ind Pty | METHOD AND APPARATUS FOR CLEANING BY RUBBING A WIRE OR STRIP |
| JP6048783B2 (en) * | 2011-09-29 | 2016-12-21 | 高周波熱錬株式会社 | Manufacturing method and equipment for solar cell lead wire |
| CN112126879B (en) * | 2020-09-24 | 2022-12-02 | 鹰潭市众鑫成铜业有限公司 | Tinning method of copper wire |
-
1966
- 1966-05-31 FI FI1416/66A patent/FI40278B/fi active
-
1967
- 1967-05-30 DE DE19671621304 patent/DE1621304A1/en active Pending
- 1967-05-30 GB GB24881/67A patent/GB1134724A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1134724A (en) | 1968-11-27 |
| FI40278B (en) | 1968-09-02 |
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