CN209431412U - Abraum salt high-temperature fusion oxygen blast kiln - Google Patents

Abraum salt high-temperature fusion oxygen blast kiln Download PDF

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Publication number
CN209431412U
CN209431412U CN201821946863.8U CN201821946863U CN209431412U CN 209431412 U CN209431412 U CN 209431412U CN 201821946863 U CN201821946863 U CN 201821946863U CN 209431412 U CN209431412 U CN 209431412U
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molten bath
abraum salt
kiln
flue gas
changeover portion
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CN201821946863.8U
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Inventor
郑文敬
张琦
金余其
张月辉
欧阳璐
戴斌
陈建
杨文�
李晓芬
于学洋
李小杰
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ZHEJIANG WUHUA TIANBAO ENERGY ENVIRONMENTAL PROTECTION CO Ltd
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ZHEJIANG WUHUA TIANBAO ENERGY ENVIRONMENTAL PROTECTION CO Ltd
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Abstract

The utility model discloses a kind of abraum salt high-temperature fusion oxygen blast kilns, including kiln body, oxygen lance, changeover portion, air outlet;The kiln body is horizontal type structure, feed inlet and slag-drip opening are provided on the kiln body, kiln body top is flue gas chamber, centre is quirk, lower part is molten bath, weir is equipped among molten bath, changeover portion is arranged obliquely, the entrance of changeover portion is connected with flue gas chamber, and abraum salt burns the air needed and enters in kiln body from air outlet, and the oxygen lance is passed through in the fuse salt in molten bath.The utility model is the engineering problem occurred when solving saliferous solid waste using high temperature incineration technology, improve medicine and chemical company because runing time it is short caused by frequent blowing out status, the loss that long period is cleared up caused by reducing because of abraum salt corrosion heating surface, and utilizability of the saliferous dangerous waste after high temperature incineration is improved, it is final to realize the innoxious of saliferous solid waste, minimizing, recycling.

Description

Abraum salt high-temperature fusion oxygen blast kiln
Technical field
The utility model relates to saliferous solid waste burning technical field more particularly to a kind of abraum salt high-temperature fusion oxygen blast kilns.
Background technique
Currently, many enterprises can all generate a large amount of saliferous solid wastes, need of the market to saliferous solidification disposal of waste in process of production Ask very huge, numerous chemical industry or synthesis pharmaceutical manufacturer cause to stop production due to can not rationally dispose saliferous solid waste.Meanwhile the solid salt Often because organic matter therein can not be reused in industrial production, usually go to focus in the form of solid waste, both waste of resource, simultaneously Processing cost is also high.
For comprehensive utilization and security landfill technology, high temperature incineration more can effectively destroy nuisance in saliferous dangerous waste Matter formula.During the burning process, the solid residue that saliferous dangerous waste is converted to gas in incinerator and can not fire again.High temperature incineration The organic component in saliferous organic waste residues can be effectively destroyed, the poisonous and harmful organic component contained in waste residue passes through high temperature incineration It is degraded to CO2、H2O、NOx、SO2It can directly be arranged after the processing of tail flue gas purification device is up to standard Deng, incineration flue gas It puts.
For high temperature incineration technology, core is that incinerator to the adaptability of different saliferous dangerous wastes, handles dangerous waste at present Incinerator mainly have molten slag type rotary kiln, liquid injection incinerator, fluidized bed etc..According to actual experience, above-mentioned three kinds of furnaces There is the limitation and operation of processing in type.
1. the operating of molten slag type rotary kiln is extremely difficult, if temperature control is improper, different shape may be adhered on kiln wall Salt slag, slag exit is easy blocking, and inner liner of rotary kiln refractory material is easily corroded by the alkali metal fusion salt of low melting point and shelled It falls;If sodium, potassium compound containing low melting point in charging, slag may generate the danger of physical explosion in rapid cooling.
2. liquid injection incinerator can not handle the waste liquid for being difficult to be atomized and solid semisolid waste.
3. the stable operation of fluidized bed depends on the fluidization of bed material, the bed when handling the material of the alkali metal salt containing low melting point Material easily slagging causes fluidisation to fail, the blowing out so that system is had to.
The problem that high temperature incineration disposition saliferous solid waste encounters is the shadow that the component of inorganic salts in waste residue runs incinerator It rings.Since component of inorganic salts fusing point is low, molten condition is formed vulnerable to heat in high temperature incineration disposal process, leads to Boiler Heating Surfaces And difficult cleaning, runing time is short, and cleaning cycle is long, continuous difficult deslagging, and blowing out can be even directly resulted in when serious;Some saliferous are solid The pollution elements such as S, N, Cl, Br content is high in useless, has a special requirement to melting disposing technique or flue gas purification system, investment at This is big, and flue gas qualified discharge difficulty is big.
Utility model content
The utility model is the engineering problem occurred when solving saliferous solid waste using high temperature incineration technology, improves medicine and changes Work enterprise because runing time it is short caused by frequent blowing out status, reduce because abraum salt corrode heating surface caused by long period clear up damage It loses, and improves utilizability of the saliferous dangerous waste after high temperature incineration, it is final to realize the innoxious of saliferous solid waste, minimizing, resource Change, provides a kind of abraum salt high-temperature fusion oxygen blast kiln.
The utility model technical scheme applied to solve the technical problem is as follows: a kind of abraum salt high-temperature fusion oxygen blast kiln, Including kiln body, oxygen lance, changeover portion, air outlet;The kiln body is horizontal type structure, be provided on the kiln body into Material mouth and slag-drip opening, kiln body top is flue gas chamber, centre is quirk, lower part is molten bath, is equipped with weir among molten bath, Changeover portion arranges that the entrance of changeover portion is connected with flue gas chamber obliquely, abraum salt burn need air from air outlet into Enter kiln body, the oxygen lance is passed through in the fuse salt in molten bath.
Further, diversion pipe is connected on the slag-drip opening.
Further, the kiln is heated by neat gas burner.
Further, the neat gas burner opposite direction dislocation is arranged in the two sides of kiln body.
Further, fuse salt temperature is 1200-1400 DEG C in the molten bath, flue-gas temperature >=1100 of changeover portion import DEG C, gas residence time >=2 second in flue gas chamber.
Further, the molten bath successively pours syphon as fire resisting using insulating brick, clay brick, kaolin from the inside to the outside And thermal insulation material.
Further, from the inside to the outside successively using silica brick, insulating brick as fire resisting and heat preservation at the top of the flue gas chamber Material.
Further, below changeover portion, abraum salt burns the air needed and is sent into from air outlet the air outlet facility, high Warm flue gas is discharged from changeover portion, forms a kind of open circulation.
Further, the oxygen lance is passed directly into the fuse salt in molten bath by molten bath lower part flame-proof thermal insulation material, When burning, pure oxygen is uniformly blown into molten bath by oxygen lance.
The utility model has the beneficial effect that
1. intermediate zone of the flue gas chamber of the kiln internal upper part as gaseous organic substance, abraum salt are fed through material inlet Afterwards, it first passes through high temperature molten bath the combustible in waste gasifies, non-flammable salt and carbon residue are stayed in molten bath and further removed.
2. having oxygen lance below molten bath, it is uniformly blown into oxygen, keeps the elements such as the residual sulphur of carbon residue in molten bath in fused salt complete It blows down, reduces original pollutant SO2Concentration of emission, make discharge purity salt it is higher.
3. being equipped with weir among molten bath, the residence time of fuse salt in molten bath can be effectively increased, and to unburned in molten bath Most particulate form abraum salt plays the role of interception, while having certain buffering effect to continuous discharging slag.
4. fuse salt is after high temperature clean incineration, physical and chemical index: the elements such as carbon, hydrogen, oxygen, nitrogen, sulphur, phosphorus, which can meet, to be less than 1ppm。
5. fuse salt is no longer belong to danger wastes after high temperature clean incineration, benefit may be recovered by break process With sodium chloride, sodium sulphate, sodium metaphosphate etc. can reach corresponding product standard, have certain economic benefit.
6. the refractory material in molten bath considers fuse salt high-melting-point, the characteristic of the easy slagging of low temperature, refractory material is using brick The form built can increase service life.
7. the quirk is heat insulating construction, and radiant heat is strong, is conducive to gas by refractory material laying at quirk above molten bath After-flame.The structure design of quirk can ensure that flue gas in 1100 DEG C or more of high-temperature region residence time is more than 3 seconds.
8. the device changeover portion is structure obliquely, during high-temperature flue gas ramps up, the inner wall of changeover portion is encountered, Being separated in flue gas containing salt particle and droplet falls into progress second-time burning in high temperature molten bath.
9. the kiln is a kind of form of horizontal flame furnace, heat transfer type is not only the reflection by flame, and main Be radiant heat transfer by furnace roof, furnace wall and hot gases.
10. in the case where being continuously fed to air and continuous discharge flue gas, it can be ensured that kiln is constantly in an open type Circulation reduces the risk that equipment uses.
Detailed description of the invention
Fig. 1 is that the master of the abraum salt high-temperature fusion oxygen blast kiln of the utility model cuts open schematic diagram;
Fig. 2 is sectional view along A-A in Fig. 1;
In figure: feed inlet 1, slag-drip opening 2, molten bath 3, weir 4, flue gas chamber 5, quirk 6, oxygen lance 7, combustion of natural gas Device 8, changeover portion 9, air outlet 10, diversion pipe 11, double roller lag cooler 12, insulating brick 13, clay brick 14, kaolin pour syphon 15, silica brick 16.
Specific embodiment
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description and attached When figure, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.In following exemplary embodiment Described embodiment does not represent all embodiments consistent with the utility model.On the contrary, they be only with such as It is described in detail in attached middle school, institute claims, the example of the consistent device of some aspects of the utility model.This specification Various embodiments are described in a progressive manner.
It is to be appreciated that the directional instruction (such as up, down, left, right, before and after ...) of institute in the utility model embodiment It is only used for explaining in relative positional relationship, the motion conditions etc. under a certain particular pose (as shown in the picture) between each component, such as When the fruit particular pose changes, then directionality instruction also correspondingly changes correspondingly.
In addition, the description for being related to " first ", " second " etc. in the present invention is used for description purposes only, and cannot understand For its relative importance of indication or suggestion or implicitly indicate the quantity of indicated technical characteristic.Define as a result, " first ", The feature of " second " can explicitly or implicitly include at least one of the features.In addition, the technical side between each embodiment Case can be combined with each other, but must be based on can be realized by those of ordinary skill in the art, when the combination of technical solution Conflicting or cannot achieve when occur will be understood that the combination of this technical solution is not present, also not in the requires of the utility model Protection scope within.
As depicted in figs. 1 and 2, a kind of abraum salt high-temperature fusion oxygen blast kiln provided by the utility model, including kiln body, Oxygen lance 7, changeover portion 9, air outlet 10;The kiln body is horizontal type structure, and feed inlet 1 and row are provided on the kiln body Cinder notch 2, kiln body top are that (as the intermediate zone of gaseous organic substance, abraum salt is fed flue gas chamber 5 through material inlet Afterwards, it first passes through high temperature molten bath the combustible in waste gasifies, non-flammable salt and carbon residue are stayed in molten bath and further taken off Except), centre be quirk 6 (wall actually in the middle part of kiln body), lower part is molten bath 3, kiln is equipped among molten bath Bank 4 (can effectively increase the residence time of fuse salt in molten bath, and play interception to particulate form abraum salt uncombusted in molten bath Effect, while having certain buffering effect to continuous discharging slag), kiln is divided into molten bath 3 and the cigarette on top of lower part by the quirk 6 Gas chamber 5, fuse salt are in flowable state, high-temperature flue gas further combustion decomposition in flue gas chamber 5 in molten bath 3.Transition Section 9 arranges that the entrance of changeover portion 9 is connected with flue gas chamber 5 obliquely, during high-temperature flue gas ramps up, encounters The inner wall of section is crossed, being separated in flue gas containing salt particle and droplet falls into progress second-time burning in high temperature molten bath;Abraum salt It burns the air needed to enter in kiln body from air outlet 10, the oxygen lance 7 is passed through in the fuse salt in molten bath 3, oxygen blast Pipe 7 is uniformly blown into oxygen, blows down the elements such as the residual sulphur of the carbon residue in molten bath in fused salt completely, reduces original pollutant SO2's Concentration of emission keeps the purity salt of discharge higher.
The kiln is heated by neat gas burner 15, and the dislocation of neat gas burner opposite direction is arranged in kiln Two sides.
Fuse salt temperature is 1200-1400 DEG C in the molten bath 3, flue-gas temperature >=1100 DEG C of 9 import of changeover portion, quirk Structure design so that gas residence time >=3 second in flue gas chamber 5.
The molten bath 3 from the inside to the outside successively using insulating brick 13, clay brick 14, kaolin pour syphon 15 as fire resisting and Thermal insulation material;5 top of flue gas chamber is successively used as fire resisting and thermal insulating material using silica brick 16, insulating brick 13 from the inside to the outside Material.
10 facility of air outlet is below changeover portion 9, and abraum salt burns the air needed and is sent into from air outlet 10, high temperature cigarette Gas is discharged from changeover portion 9, forms a kind of open circulation, reduces the risk that equipment uses.
The oxygen lance 7 is passed directly into the fuse salt in molten bath 3 by 3 lower part flame-proof thermal insulation material of molten bath, when burning, Pure oxygen is uniformly blown into molten bath by oxygen lance 7.
For kiln in deslagging, fuse salt flows through weir 4 to slag-drip opening 2, is connected with diversion pipe 11 on the slag-drip opening 2, leads Flow tube 11 connects slag-drip opening 2 and double roller lag cooler 12, and fuse salt feeds from the centre of double roller lag cooler 12 and cooled down.
Kiln 9, which first puts into neat gas burner 15 before operating normally, makes kiln 9 heat up, and temperature, which reaches 1000 DEG C or more, to throw Entering saliferous solid waste, liquid level slowly increases and gradually covered oxygen lance 7 in molten bath 3, a good gas-liquid separation interface is formed, this When flue gas constantly from changeover portion 9 be discharged, air constantly from air outlet 10 be sent into.It is normal fortune when reaching above-mentioned state in kiln Row state can gradually decrease the aperture of neat gas burner 15, meet flue gas chamber 5 and maintain 1100 DEG C, while to oxygen blast Pure oxygen is passed through in pipe 7, liquid level bubble occurs and is in flowable state in molten bath 3, illustrates that the melting oxygen blast atmosphere in molten bath has had been established At.Slag-drip opening 2 is opened, flowable state fuse salt falls into double roller lag cooler 12 through diversion pipe 11 and cooled down, and salt after cooling can be into Row recycles.

Claims (9)

1. a kind of abraum salt high-temperature fusion oxygen blast kiln, which is characterized in that including kiln body, oxygen lance (7), changeover portion (9), give Air port (10);The kiln body is horizontal type structure, is provided with feed inlet (1) and slag-drip opening (2), kiln sheet on the kiln body Body top is flue gas chamber (5), centre is quirk (6), lower part is molten bath (3), is equipped with weir (4) among molten bath, changeover portion (9) it arranges obliquely, the entrance of changeover portion (9) is connected with flue gas chamber (5), and abraum salt burns the air needed from air outlet (10) enter in kiln body, the oxygen lance (7) is passed through in the fuse salt in molten bath (3).
2. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1, which is characterized in that on the slag-drip opening (2) It is connected with diversion pipe (11).
3. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1, which is characterized in that the kiln passes through natural Air burner (8) is heated.
4. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 3, which is characterized in that the neat gas burner (8) opposite dislocation is arranged in the two sides of kiln body.
5. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1, which is characterized in that melted in the molten bath (3) Melting salt temperature is 1200-1400 DEG C, flue-gas temperature >=1100 DEG C of changeover portion (9) import, and the interior flue gas of flue gas chamber (5) stops Time >=3 second.
6. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1, which is characterized in that molten bath (3) lower part Syphon (15) are successively poured as fire resisting and thermal insulation material using insulating brick (13), clay brick (14), kaolin from the inside to the outside.
7. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1 or 6, which is characterized in that the flue gas stops Fire resisting and thermal insulation material are successively used as using silica brick (16), insulating brick (13) from the inside to the outside at the top of room (5).
8. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1, which is characterized in that the air outlet (10) sets It applies below changeover portion (9), abraum salt burns the air needed and is sent into from air outlet (10), and high-temperature flue gas is discharged from changeover portion (9), Form a kind of open circulation.
9. a kind of abraum salt high-temperature fusion oxygen blast kiln according to claim 1, which is characterized in that the oxygen lance (7) is logical It is passed directly into the fuse salt in molten bath (3) after crossing molten bath (3) lower part flame-proof thermal insulation material, when burning, pure oxygen passes through oxygen lance (7) it is uniformly blown into molten bath.
CN201821946863.8U 2018-11-23 2018-11-23 Abraum salt high-temperature fusion oxygen blast kiln Active CN209431412U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109404924A (en) * 2018-11-23 2019-03-01 浙江物华天宝能源环保有限公司 A kind of abraum salt high-temperature fusion oxygen blast kiln
CN114409213A (en) * 2022-01-13 2022-04-29 东北石油大学 Molten salt-oily sludge thermochemical conversion fluidized bed reactor, system and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109404924A (en) * 2018-11-23 2019-03-01 浙江物华天宝能源环保有限公司 A kind of abraum salt high-temperature fusion oxygen blast kiln
CN114409213A (en) * 2022-01-13 2022-04-29 东北石油大学 Molten salt-oily sludge thermochemical conversion fluidized bed reactor, system and application thereof
CN114409213B (en) * 2022-01-13 2023-01-24 东北石油大学 Molten salt-oily sludge thermochemical conversion fluidized bed reactor, system and application thereof

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