CN204271170U - A kind of safety lithium ion cell group - Google Patents

A kind of safety lithium ion cell group Download PDF

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Publication number
CN204271170U
CN204271170U CN201420537958.XU CN201420537958U CN204271170U CN 204271170 U CN204271170 U CN 204271170U CN 201420537958 U CN201420537958 U CN 201420537958U CN 204271170 U CN204271170 U CN 204271170U
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CN
China
Prior art keywords
battery pack
battery
cell group
lithium ion
monomer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN201420537958.XU
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Chinese (zh)
Inventor
张健
蒋宁懿
刘全兵
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Tianjin Space Power Technology Co ltd
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CETC 18 Research Institute
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Priority to CN201420537958.XU priority Critical patent/CN204271170U/en
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Publication of CN204271170U publication Critical patent/CN204271170U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Battery Mounting, Suspending (AREA)
  • Secondary Cells (AREA)

Abstract

The utility model relates to a kind of safety lithium ion cell group, comprises a plurality of lithium-ion battery monomers in battery housing, battery housing; Be positioned at positive terminal on the lithium-ion battery monomer of two ends and negative pole end is drawn respectively by the total plus end of battery pack and the total negative terminal of battery pack; Battery pack cover is equipped with exhaust apparatus, is characterized in: the vacant place in described battery housing is filled with extinguishing chemical.The utility model is by being filled with extinguishing chemical at the vacant place of internal battery pack, when cell a certain in battery pack burns, its heat can impel the ingredient breakdown of extinguishing chemical, decomposition reaction is the endothermic reaction, not only playing cooling effect makes battery pack lower the temperature rapidly, and catabolite can form glassy cover layer and makes combustible in battery and air exclusion, it is inner that combustion range is only limitted to bad monomer in battery pack, and rapidly by the fray-out of flame of bad monomer inside, both fire spreading was avoided, cell burned flame can be extinguished again, ensure that the fail safe of battery pack.

Description

A kind of safety lithium ion cell group
Technical field
The utility model belongs to power supply series technique field, particularly relates to a kind of safety lithium ion cell group.
Background technology
In recent years, increasingly extensive along with battery applications, the example of battery generation security incident is also of common occurrence.
For lithium ion battery.Lithium battery is inner when Charging state has put aside huge energy, once control improper when the ambient temperature residing for lithium battery etc. or internal short-circuit, the accidents such as lithium battery is very easily blasted, catch fire occurring.When a battery has an accident if do not adopt appropriate measures, other batteries contiguous can be involved, cause fire spreading, then cause larger accident.
Find through retrieval, application number is 201120323564.0, publication number is CN202282390U, name is called: the utility model patent of the lithium-ion battery safety box of explosion-proof flame-retardant.This utility model comprises Li-ion batteries piles and stuffing box, described stuffing box comprises casing and top cover, described top cover is connected with box sealing, described Li-ion batteries piles is positioned at described casing, described top cover is installed fin, positive conductive terminal and cathode conductive terminal, described top cover is installed to vacuumize and is filled with the gas valve of inert gas.This utility model to a certain degree improves the fail safe of lithium ion battery.But when adopting the safety box described in this utility model to store Charging state lithium battery, because battery self has the ability that redox reaction occurs, if therefore in the situation such as battery generation internal short-circuit, box interior temperature is very high, when exceeding the limit of metal cabinet self, casing will cave in, and cells burst blast etc. also can not be stoped to involve situation outside case even if be filled with inert gas in safety box.And usually lithium battery is all charged-state storage.Therefore this patent there is no practical significance.
Also find through retrieval, application number is 200920266418.1, publication number is CN201528016U, name is called: the utility model patent of oil immersion cell box.This utility model is full of transformer oil at the remaining space of battery pack except battery cell, pole.Be full of transformer oil at the remaining space of battery pack, the heat dispersion of battery can be improved, and shed by the heat radiation that contacts with transformer oil is stupefied at battery pack adstante febre heat.This method can play protection battery to a certain extent when battery pack normally uses, and battery temperature can not be raised a lot.But when there being Individual cells inside that the faults such as internal short-circuit occur in battery pack, battery can burn.Because inside battery has Oxidizing and Reducing Agents; do not need external oxygen with regard to incendivity; and the now arc extinguishing effect of transformer oil can not play a protective role to battery pack; it is contrary to the intensity of a fire increases; because transformer main body of oil is alkane; at high temperature and be flammable when having air to exist, therefore the existence of transformer oil can help to rise the intensity of a fire on the contrary.Therefore this patent there is no practical application meaning.
As can be seen here, in order to avoid the situations such as initiation fire of being exploded by a batteries caught fire, need a kind of fire control that a battery can be caused or the device limited within the specific limits, prevent fire spreading from causing larger loss.
Summary of the invention
The utility model provides a kind of and can produce the control of fire of the cell of fire in the inside of this cell for solving in known technology the technical problem that exists, avoids a kind of safety lithium ion cell group that fire spreading spreads to battery pack outside.
The utility model comprises following technical scheme:
A kind of safety lithium ion cell group, comprises a plurality of lithium-ion battery monomer of series connection all-in-one-piece in battery housing, battery housing, is isolated, be equipped with insulation board between ion battery monomer and battery housing between adjacent lithium-ion battery monomer by collets; Be arranged in positive terminal on the lithium-ion battery monomer of two ends and negative pole end to be installed in the total plus end of the battery pack of battery pack cover and the total negative terminal of battery pack on battery housing respectively by sealing and to draw; Battery pack cover is equipped with exhaust apparatus, is characterized in: the vacant place in described battery housing is filled with extinguishing chemical.
The utility model can also adopt following technical measures:
Described exhaust apparatus comprises the disappointing valve seat of seal welding on battery pack cover one hole, is fixedly mounted with an aluminum plastic film in the valve seat that loses heart by eye bolt sealing.
Described collets are polytetrafluoroethylene block.
Described insulation board is glass epoxy.
The total plus end of battery pack in described battery pack cover and all seal between the total negative terminal of battery pack and battery pack cover and be fixed with insulator seal ring.
The advantage that the utility model has and good effect:
The utility model is by being filled with extinguishing chemical at the vacant place of internal battery pack, when cell a certain in battery pack burns, its heat can impel the ingredient breakdown of extinguishing chemical, decomposition reaction is the endothermic reaction, not only playing cooling effect makes battery pack lower the temperature rapidly, and catabolite can form glassy cover layer and makes combustible in battery and air exclusion, it is inner that combustion range is only limitted to bad monomer in battery pack, and rapidly by the fray-out of flame of bad monomer inside, both fire spreading was avoided, cell burned flame can be extinguished again, ensure that the fail safe of battery pack.
Accompanying drawing explanation
Fig. 1 is safety lithium ion cell group internal structure schematic diagram prepared by the utility model.
In figure: 1-battery housing, 2-lithium ion single battery, 3-eye bolt, 4-positive terminal, 5-insulator seal ring, the total plus end of 6-battery pack, 7-battery pack cover, 8-aluminum plastic film, 9-negative pole end, the total negative terminal of 10-battery pack, 11-extinguishing chemical, 12-glass epoxy, 13-loses heart valve seat, 14-polytetrafluoroethylene block.
Embodiment
For summary of the invention of the present utility model, Characteristic can be disclosed further, be described in detail as follows especially exemplified by following instance.
A kind of safety lithium ion cell group, comprises a plurality of lithium-ion battery monomer of series connection all-in-one-piece in battery housing, battery housing, is isolated, be equipped with insulation board between ion battery monomer and battery housing between adjacent lithium-ion battery monomer by collets; Be arranged in positive terminal on the lithium-ion battery monomer of two ends and negative pole end to be installed in the total plus end of the battery pack of battery pack cover and the total negative terminal of battery pack on battery housing respectively by sealing and to draw; Battery pack cover is equipped with exhaust apparatus.
The utility model innovative point comprises:
Vacant place in described battery housing is filled with extinguishing chemical.
The utility model innovative point also comprises:
Described exhaust apparatus comprises the disappointing valve seat of seal welding on battery pack cover one hole, is fixedly mounted with an aluminum plastic film in the valve seat that loses heart by eye bolt sealing.
Described collets are polytetrafluoroethylene block.
Described insulation board is glass epoxy.
The total plus end of battery pack in described battery pack cover and all seal between the total negative terminal of battery pack and battery pack cover and be fixed with insulator seal ring.
Embodiment:
The manufacturing process of the utility model safety lithium ion cell group
(1) make 1 wide * of long * thick=102mm*102mm*1mm stainless steel substrates is as battery pack cover 7, battery pack case covers and is shaped with 3 holes, interstitial hole is welded with the disappointing valve seat 13 of band M12 internal thread, a hole in the hole at two ends is equipped with the total plus end 6 of battery pack, the total plus end material of battery pack is LY12 aluminium alloy.There is a material to be polyacrylic insulator seal ring 5 between the total plus end of battery pack and battery pack cover, make battery pack total plus end deformation extruding insulation sealing ring reach the effect of compression seal by punching press.The total negative terminal 10 of battery pack of Y2 red copper material another hole in two stomidiums is equipped with, there is a material to be polyacrylic insulator seal ring between the total negative terminal of battery pack and battery pack cover, make battery pack total negative terminal deformation extruding insulation sealing ring reach the effect of compression seal by punching press.
(2) make 1 interior minister * height * thick=the uncovered Stainless Steel Shell of 100mm*100mm*100mm as battery housing 1, the wall thickness of battery housing is 1mm; Battery housing inwall silica gel glues the glass epoxy 12 that a layer thickness is 0.2mm.
(3) select 8 case materials to be the lithium ion single battery 2 of aluminium alloy, the long * height * of each cell is thick=95mm*80mm*10mm; The capacity of each cell is 5Ah; By the positive terminal 4 after integral for 8 lithium ion single serial battery by the total plus end 6 of battery pack in ultrasonic bond welding battery pack cover, on the total negative terminal 10 of battery pack that negative pole end 9 is welded in battery pack cover by ultrasonic bond.
(4) 8 lithium ion single batteries after process (3) being connected are parallel to each other and are placed in battery housing, separate between adjacent lithium ion single battery with polytetrafluoroethylene block 14, and battery pack cover and battery housing adopt argon arc welding to weld together; By funnel, the ammonium dihydrogen phosphate in extinguishing chemical 11 and ammonium sulfate powder are injected in battery housing from the opening part of disappointing valve seat, shake battery pack gently, extinguishing chemical powder is fully distributed in each cell gap, by funnel, carbon tetrachloride is injected battery housing inside.Each component ratio of extinguishing chemical is ammonium dihydrogen phosphate 50%, ammonium sulfate 25%, carbon tetrachloride 25%, and the total amount injecting battery container inside is 100g; Be the aluminum plastic film 8 of 0.15mm by thickness, be placed on the bottom of disappointing valve seat 13, compress with a trough of belt M12 external screw thread eye bolt 3 and the periphery fixing aluminum plastic film by stack seal, complete the manufacturing process of safety lithium ion cell group as shown in Figure 1.
Operation principle of the present utility model:
When in battery pack during some monomer combustion, its heat can impel the composition of extinguishing chemical to decompose, decomposition reaction is the endothermic reaction, playing cooling effect on the one hand makes battery pack lower the temperature rapidly, and catabolite can form the barrier film that glassy cover layer makes in battery, the solid combustibles such as metal forming and air exclusion, chemically inert carbon tetrachloride at high temperature volatilizees and can dilute battery electrolyte solvent vapo(u)r on the other hand, thus combustion range can be made to be only limitted to bad monomer inside in battery pack, and other normal monomers in battery pack can not be involved, avoid fire spreading, reach the object at internal battery pack knock down the flame, drastically increase the fail safe of battery pack.
Although be described preferred embodiment of the present utility model above; but the utility model is not limited to above-mentioned embodiment; above-mentioned embodiment is only schematic; be not restrictive; those of ordinary skill in the art is under enlightenment of the present utility model; do not departing under the ambit that the utility model aim and claim protect; a lot of form can also be made, as safe Nickel-Hydrogen batteries, safe Cd Ni battery, safe lead-acid battery group etc. can also be made.These all belong within protection range of the present utility model.

Claims (5)

1. a safety lithium ion cell group, comprises a plurality of lithium-ion battery monomer of series connection all-in-one-piece in battery housing, battery housing, is isolated, be equipped with insulation board between ion battery monomer and battery housing between adjacent lithium-ion battery monomer by collets; Be arranged in positive terminal on the lithium-ion battery monomer of two ends and negative pole end to be installed in the total plus end of the battery pack of battery pack cover and the total negative terminal of battery pack on battery housing respectively by sealing and to draw; Battery pack cover is equipped with exhaust apparatus, it is characterized in that: the vacant place in described battery housing is filled with extinguishing chemical.
2. a kind of safety lithium ion cell group according to claim 1, is characterized in that: described exhaust apparatus comprises the disappointing valve seat of seal welding on battery pack cover one hole, is fixedly mounted with an aluminum plastic film in the valve seat that loses heart by eye bolt sealing.
3. a kind of safety lithium ion cell group according to claim 1, is characterized in that: described collets are polytetrafluoroethylene block.
4. a kind of safety lithium ion cell group according to claim 1, is characterized in that: described insulation board is glass epoxy.
5. a kind of safety lithium ion cell group according to claim 1, is characterized in that: the total plus end of the battery pack in described battery pack cover and all seal between the total negative terminal of battery pack and battery pack cover and be fixed with insulator seal ring.
CN201420537958.XU 2014-09-18 2014-09-18 A kind of safety lithium ion cell group Expired - Lifetime CN204271170U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201420537958.XU CN204271170U (en) 2014-09-18 2014-09-18 A kind of safety lithium ion cell group

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201420537958.XU CN204271170U (en) 2014-09-18 2014-09-18 A kind of safety lithium ion cell group

Publications (1)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107910606A (en) * 2017-10-27 2018-04-13 天津市捷威动力工业有限公司 A kind of lithium ion battery bag thermal runaway control device
WO2018126511A1 (en) * 2017-01-04 2018-07-12 益阳科力远电池有限责任公司 Fireproof battery pack
CN110393876A (en) * 2019-08-05 2019-11-01 清华大学 Lithium ion battery firebreak device
US10665909B2 (en) 2017-07-17 2020-05-26 International Business Machines Corporation Battery thermal run-away and combustion prevention system

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018126511A1 (en) * 2017-01-04 2018-07-12 益阳科力远电池有限责任公司 Fireproof battery pack
US10665909B2 (en) 2017-07-17 2020-05-26 International Business Machines Corporation Battery thermal run-away and combustion prevention system
CN107910606A (en) * 2017-10-27 2018-04-13 天津市捷威动力工业有限公司 A kind of lithium ion battery bag thermal runaway control device
CN107910606B (en) * 2017-10-27 2020-06-19 天津市捷威动力工业有限公司 Lithium ion battery package thermal runaway controlling means
CN110393876A (en) * 2019-08-05 2019-11-01 清华大学 Lithium ion battery firebreak device
CN110393876B (en) * 2019-08-05 2024-05-31 清华大学 Fireproof device for lithium ion battery

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Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20180510

Address after: 300384 Tianjin Binhai high tech Zone Huayuan Industrial Area (outside the ring) Hainai Hua five road 6, 6 buildings.

Patentee after: TIANJIN SPACE POWER TECHNOLOGY Co.,Ltd.

Address before: 300384 No. 6, Hua Ke seven road, hathai Industrial Park, Xiqing District, Tianjin

Patentee before: The 18th Research Institute of China Electronics Technology Group Corporation

TR01 Transfer of patent right
CX01 Expiry of patent term

Granted publication date: 20150415

CX01 Expiry of patent term