CN1917853A - Conditioning compositions comprising hydrophobically modified crosslinked cationic thickening polymers - Google Patents
Conditioning compositions comprising hydrophobically modified crosslinked cationic thickening polymers Download PDFInfo
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Abstract
Disclosed are conditioning compositions comprising by weight: (a) from about 0.01% to about 6.0% of a hydrophobically modified crosslinked cationic thickening polymer; (b) from about 0.1% to about 8.0% of a surfactant system; (c) from about 0.1% to about 10% of a silicone compound; and (d) an aqueous carrier. The conditioning compositions of the present invention have a suitable rheology for conditioning compositions, and provides conditioning benefits. The compositions are especially suitable for hair care products such as hair conditioning products for rinse-off use.
Description
Invention field
The present invention relates to care composition, described care composition comprises crosslinked cationic thickening polymers, surfactant system and the silicone compounds of hydrophobically modified.Care composition of the present invention has the rheological behavior that is suitable for care composition and the conditioning beneficial effect is provided.Described compositions is particularly suited for hair care product, for example is used for the hair-conditioning product of washing-off type purposes.
Background of invention
Multiple care composition, for example hair care composition, skin conditioning composition and fabric softener have been used to multiple substrate, as hair, skin and fabric.A kind of common method that the conditioning beneficial effect is provided is by using conditioner, as cationic surfactant and polymer, hard fat compounds of group, low melting point oil, silicone compounds, and their mixture.These conditioners of known great majority provide various conditioning beneficial effects.For example, when using with some hard fat compounds of group, it is believed that some cationic surfactant can form gel-type vehicle, this substrate has the rheological behavior that is suitable for care composition and is suitable for providing multiple conditioning beneficial effect, especially when being used for hair care product, it provides as the wet smooth feeling of sending out, flexibility and minimizing and twines, and beneficial effects such as dried flexibility of sending out and moist feeling.
Need in the conditioning beneficial effect that keeps described gel-type vehicle, use other method to obtain to be suitable for the rheological behavior of care composition, rather than form above-mentioned gel-type vehicle.
In addition, also known most of above-mentioned conditioner can make compositions become opaque.Therefore, need care composition to have clarifying product appearance, promptly transparent or semitransparent product appearance.
Known in addition, when comprising these conditioners in hair care composition, most of above-mentioned conditioners can force down hair.For those consumers (consumer thinner as hair) that wish maintenance or increase hair volume, it is undesirable forcing down hair.Therefore, need when being provided, the conditioning beneficial effect not force down the hair care composition of hair.
Also need such care composition: when said composition was used with the form of rinse-off products, especially washing-off type hair conditioner product, when the conditioning beneficial effect was provided, consumer felt easy rinsing.The conditioner composition that comprises above-mentioned gel-type vehicle also provides persistent smooth feeling when rinsing, this is undesirable for some consumers of liking clean sense.Therefore, need such care composition: when it can leave hair easily, produce clean sensation when hair rinses said composition, conditioning agent deposit that simultaneously will q.s is on hair.
Described based on preamble, need such care composition: when this care composition is used for hair care product for example during the hair-conditioning product, it can have suitable rheological behavior by the gel-type vehicle that uses other method rather than be made up of cationic surfactant and hard fat compounds of group, the conditioning beneficial effect is provided simultaneously, and the especially wet flexibility of sending out is twined with reducing.Also need such care composition: it is suitable for providing more beneficial effect, as transparent product appearance, the sensation not forcing down hair and be easy to rinsing, provides above-mentioned rheology beneficial effect and conditioning beneficial effect simultaneously.
Can provide whole advantage of the present invention and beneficial effect without any prior art.
Summary of the invention
The present invention relates to compositions, described compositions comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% surfactant system;
(c) about 0.1% to about 10% silicone compounds; With
(d) aqueous carrier.
By reading following detailed and appending claims, can understand these and other feature, aspect and advantage of the present invention better.
Detailed Description Of The Invention
Although this description it is believed that by following explanation to understand the present invention better to particularly point out and clearly claimed claims of the present invention are drawn a conclusion.
In this article, " comprise " and be meant and add other step of not influencing final result and other composition.This term comprise term " by ... form " and " basically by ... composition ".
Except as otherwise noted, all percentage ratio, umber and ratio are all by the gross weight of the present composition.All weight that relate to listed composition all are in its activity substance content, and therefore do not comprise the carrier or the by-product that may be included in the commercially available material.
This paper " mixture " is meant the simple combination that comprises material and by the issuable any chemical compound of they combinations.
Compositions
Compositions A of the present invention comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% the surfactant system that comprises cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds; With
(d) aqueous carrier.
Compositions B of the present invention comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% surfactant system, described system comprise the HLB value and are about 11 to about 20 non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds; With
(d) aqueous carrier.
Compositions C of the present invention comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% surfactant system, described system is selected from cationic surfactant, non-ionic surface active agent, and their mixture;
(c) about 0.1% to about 10% silicone compounds, wherein said silicone compounds is selected from mean diameter in the described compositions and is 300nm or littler those, is dissolvable in water those of described compositions substantially, and their mixture, and wherein said soluble substantially silicone compounds is selected from the amino silicone polyol of amino silicone, amino silicone polyol, hydrophobically modified, the amido silicone copolyol of hydrophobically modified, and their mixture; With
(d) aqueous carrier.
Care composition A to C of the present invention is being used for hair care product, for example during the hair-conditioning product, has the rheological behavior that is suitable for care composition and the conditioning beneficial effect is provided, especially wet send out flexibility and reduce twine.In addition, care composition A to C of the present invention is suitable for providing more beneficial effect, as transparent product appearance, the sensation not forcing down hair and be easy to rinsing, provides above-mentioned rheology beneficial effect and conditioning beneficial effect simultaneously.When being used for hair care product, compositions A to C of the present invention provides above-mentioned rheological behavior and conditioning beneficial effect, does not force down hair simultaneously.In addition, when using with the rinse-off products form, compositions A to C of the present invention can provide the sensation that is easy to rinsing, and above-mentioned rheology beneficial effect and conditioning beneficial effect are provided simultaneously.
It is believed that when being used for hair care product such as hair-conditioning product, utilize the crosslinked cationic thickening polymers of (a) hydrophobically modified, (b) surfactant system, (c) combination of silicone compounds, compositions A to C of the present invention can provide the rheological behavior that is suitable for care composition, and do not have the gel-type vehicle of forming by cationic surfactant and hard fat compounds of group, and the conditioning beneficial effect is provided simultaneously, the especially wet flexibility of sending out is twined with reducing.Also it is believed that, preferred feature of the present invention, as use preferred thickening polymer, preferred surfactants and/or preferred silicone compounds, can help compositions of the present invention that more beneficial effect is provided, as transparent product outward appearance, do not force down hair, and the sensation of easy rinsing, above-mentioned rheology and conditioning beneficial effect are provided simultaneously.
Preferred compositions of the present invention is substantially free of water-insoluble oiliness compound, and described chemical compound is selected from hydrocarbon, aliphatic compound, and their mixture.In the present invention, the compositions of " being substantially free of water-insoluble oiliness compound " is meant that described compositions comprises 1.0% or still less, preferred 0.5% or still less, more preferably 0.1% or still less, and more preferably 0% water-insoluble oiliness chemical compound also.When the water-insoluble oiliness compound of this paper is 25 ℃ in the water dissolubility preferably less than about 0.5g/100g water, be more preferably less than those of about 0.1g/100g water less than about 1g/100g water.These water-insoluble oiliness chemical compounds are selected from hydrocarbon, aliphatic compound and their mixture.These hydrocarbon comprise for example α-polyolefin oil, paraffin, wax, and their mixture.These aliphatic compounds comprise for example aliphatic alcohol such as spermol and stearyl alcohol, fatty acid such as stearic acid, fatty alcohol derivative and derivative of fatty acid such as their ester and ether, and their mixture.
Compositions of the present invention preferably transparent or translucent, more preferably transparent.In the present invention, the compositions of " transparent " is meant that described compositions has about 50% or higher, and is preferred about 65% or higher, more preferably from about 80% or higher transmittance.In the present invention, " translucent " compositions is meant that described compositions has about 25% to about 50%, preferred about 35% to about 50% transmittance.Described transmittance uses the ultraviolet-uisible spectrophotometer UV-1601 available from Shimadzu to measure in the 600nm place.
Preferred compositions of the present invention is substantially free of anionic compound.The anionic compound of this paper comprises anion surfactant and anionic polymer.In the present invention, the compositions of " being substantially free of anionic compound " is meant that described compositions comprises 1% or still less, preferred 0.5% or still less, more preferably 0% anionic compound.
The crosslinked cationic thickening polymers of hydrophobically modified
Care composition of the present invention comprises the crosslinked cationic thickening polymers of hydrophobically modified, the cross-linked cationic acrylate thickening polymer of preferred hydrophobically modified.Described cationic thickening polymer is included in content in the present composition by weight for about 0.01% to about 6.0%, and preferred about 0.1% to about 5.0%, and more preferably from about 0.3% to about 4.0%, and also more preferably from about 0.4% to about 3.0%.
The crosslinked cationic thickening polymers that can be used for hydrophobically modified of the present invention is to can be described compositions to provide suitable viscosity and rheological properties so that compositions of the present invention has those of following character: (i) suitable viscosity, be preferably about 0.1Pas (100cps) to about 100Pas (100,000cps), more preferably from about 1Pas (1,000cps) to about 50Pas (50,000cps), 2Pas (2 more preferably from about also, 000cps) to about 50Pas (50,000cps), even more preferably from about 5Pas (5,000cps) to about 20Pas (20,000cps); (ii) suitable rheological properties makes the shear thinning index (STI) of described compositions for preferred about 30 or higher, more preferably from about 50 or higher, also more preferably from about 70 or higher, even more preferably from about 90 or higher.The viscosity of this paper be adapted at 26.7 ℃ with BrookfieldRVT with 2s
-1Shear rate measure.Shear thinning index (STI) is according to following Equation for Calculating:
Shear thinning index (STI)=first viscosity/second viscosity;
Wherein first viscosity is with 2s
-1Shear rate measure, and second viscosity is with 950s
-1Shear rate measure, the both increases progressively the flow measurement method with shear rate to use the AR 2000 available from TAInstruments to carry out under 26.7 ℃.
The crosslinked cationic thickening polymers that can be used for hydrophobically modified of the present invention can comprise that hereinafter title is the disclosed polymer of " cationic conditioning polymer " part.
The crosslinked cationic thickening polymers that can be used for hydrophobically modified of the present invention under the pH value of the present composition mainly be cationic those.These polymer are to contain those of amido, and described amido is selected from primary, the second month in a season, uncle, quaternary ammonium, and their mixture.When polymer contains primary, when the second month in a season and/or tertiary amine, described polymer is used to its pH to be made in these amine moieties or the protonated fully compositions.Therefore, these contain primary when using, during the polymer of the second month in a season and/or tertiary amine, and the pH of described compositions is preferably about 2 to about 8, and more preferably from about 3 to about 7, and also more preferably from about 4 to about 6.
The crosslinked cationic thickening polymers that can be used for hydrophobically modified of the present invention is to contain those of hydrophobic group.The form that described hydrophobic group can be connected to the hydrophobic substituent on the main polymer chain is attached in the described polymer.Can be used for the alkyl that hydrophobic group of the present invention is selected from straight or branched, saturated or unsaturated chain, preferred about 5 to about 40 carbon atoms, and more preferably from about 8 to about 35 carbon atoms, also more preferably from about 10 to about 30 carbon atoms.
The crosslinked cationic thickening polymers that preferably can be used for hydrophobically modified of the present invention contains hydrophilic group.The form that described hydrophilic group can be connected to the hydrophilic substituent of main polymer chain is attached in the described polymer.This hydrophilic group and above-mentioned hydrophobic group can be present in identical monomeric unit or the different monomeric unit.Can be used for hydrophilic group of the present invention comprises and for example comprises about 1 polyoxyalkylenes to about 50 alkylene oxides.Described alkylene oxide is preferably selected from oxirane, expoxy propane, and their mixture.
Preferably, the crosslinked cationic thickening polymers that can be used for hydrophobically modified of the present invention is hydrophilic, and is 0.25g/100g water at least in 25 ℃ of dissolubility in water, more preferably 2g/100g water at least, more preferably 5g/100g water at least also, even more preferably 15g/100g water at least.
Can be used for main polymer chain of the present invention and be comprising those of synthon.Can be used for preferred synthon of the present invention and comprise for example vinyl monomer, acrylate monomer, methacrylate monomer, and their mixture.
In the present invention, it is highly preferred that and comprise described monomeric unit and have formula (A)
m(B)
n(C)
p(D)
qThe cross-linked cationic acrylate thickening polymer of hydrophobically modified, wherein: (A) be acrylate monomer; (B) for containing the monomer of amine; (C) be hydrophilic monomer; (D) for comprising the monomer of hydrophobic substituent; M, n and q are one or bigger independently, and p is zero or bigger, is preferably one or bigger; And wherein said polymer also comprises crosslinked group.
Can be used for monomer of the present invention (A) and comprise those that for example are selected from alkyl acrylate, alkylmethacrylate, acrylamide, MAAm and their mixture.Preferably be selected from those of alkyl acrylate, alkylmethacrylate or their mixture.The moieties of monomer (A) is preferably short-chain alkyl, as C
1-C
8, more preferably C
1-C
5, more preferably C also
1-C
3, even more preferably C also
1-C
2
Can be used for monomer of the present invention (B) comprises and for example is selected from one or two (C
1-C
4) alkylamino (C
1-C
4) alkyl (methyl) acrylate, one or two (C
1-C
4) alkylamino (C
1-C
4) alkyl (methyl) acrylamide, quaternised two (C
1-C
4) alkylamino (C
1-C
4) those of alkyl (methyl) acrylate and their mixture.One or two (C preferably
1-C
4) alkylamino (C
1-C
4) alkyl (methyl) acrylate.Exemplary monomer (b) comprises N, N-dimethylamino methyl ethyl acrylate (DMAEMA), N, N-lignocaine ethyl acrylate, N, N-lignocaine ethyl methacrylate, uncle's N-fourth aminoacrylic acid ethyl ester, uncle's N-fourth amino methyl ethyl acrylate, N, N-dimethyl aminopropyl acrylamide, N, N-dimethyl aminopropyl MAAm, N, N-diethyl amino propyl group acrylamide and N, N-diethyl amino propyl group MAAm.
Can be used for monomer of the present invention (C) and comprise those that for example contain polyoxyalkylenes, described polyoxyalkylenes comprises about 1 to about 50, and preferred about 5 to about 45, more preferably from about 10 to about 40 alkylene oxides.Described alkylene oxide is preferably selected from oxirane, expoxy propane, and their mixture.Preferably be selected from those of vinyl alkoxy thing, PEG 10-40 (methyl) acrylate and their mixture.
Monomer (D) is optional from containing any monomer of above-mentioned hydrophobic group, and promptly preferred about 5 to about 40 carbon atoms, and more preferably from about 8 to about 35 carbon atoms, also more preferably from about 10 straight or brancheds to about 30 carbon atoms, saturated or unsaturated chain alkyl.Preferred monomer (D) also contains hydrophilic group except that hydrophobic substituent.Preferred hydrophilic group is a 10-40 ethylene glycol.Highly preferred monomer (D) contains above-mentioned hydrophobic group and hydrophilic group a substituent group, but described substituent group is connected to alkylene undersaturated copolymerization main chain group such as acrylate and methacrylate.Even preferred monomer (D) has the backbone groups that is replaced by hydrophobic group by hydrophilic group.
Except above-mentioned required preferred monomers, that also can use relatively small amount provides crosslinked monomer for described polymer, with the w/w is benchmark, the about 10ppm that is preferably described total polymer weight is to about 10,000ppm, more preferably from about 10ppm is to about 1,000ppm, also more preferably from about 10ppm to about 250ppm.Cross-linking monomer comprises aliphatic monomers such as diene, triolefin and the tetraene of the alicyclic monomer of the aromatic monomer of many vinyl substituted, many vinyl substituted, the difunctionality ester of phthalic acid, the difunctionality ester of methacrylic acid, acrylic acid polyfunctional polyisocyanate, N-methylene-bisacrylamide and many vinyl substituted.Exemplary cross-linking monomer comprises divinylbenzene, trivinylbenzene, 1,2,4-trivinyl cyclohexylamine, 1,5-hexadiene, 1,5,9-triolefin in the last of the ten Heavenly stems, 1,9-decadinene, 1,5-heptadiene, diallyl phthalate, ethylene glycol bisthioglycolate (methacrylate), Polyethylene Glycol two (methacrylate), five-and four-acrylate, triallyl tetramethylolmethane, eight allyl sucroses, cycloalkane, cycloolefin and N-methylene-bisacrylamide.
The cross-linked cationic acrylate thickening polymer that can be used for highly preferred hydrophobically modified of the present invention comprises: INCI called after acrylate/amino acrylates/vinyl alcoxyl acid esters (Vinylalkyoxylate)/C
10-30Those of alkyl PEG-25 methacrylate copolymer are available from Noveon.
Surfactant system
Compositions of the present invention comprises surfactant system.Described surfactant system is included in content in the described compositions by weight for about 0.1% to about 8.0%, and preferred about 0.2% to about 5.0%, and more preferably from about 0.4% to about 4.0%.
Preferably, because the transparent or semitransparent outward appearance of expectation, surfactant system is dissolvable in water in the described compositions under used content substantially." soluble substantially " surfactant system is meant that described compositions has 50% or more when 25 ℃ comprise described surfactant system with used content, and is preferred about 65% or more, more preferably from about 80% or more transmittance.
Can be used for surfactant system of the present invention and be selected from cationic surfactant, non-ionic surface active agent, and their mixture.When comprising, cationic surfactant is preferably united use with non-ionic surface active agent.
Cationic surfactant
Comprise one and the multiple cationic surfactant of two long alkyl chain cationic surfactant can as described belowly be used for compositions of the present invention.Wherein, a long alkyl chain cationic surfactant preferably is as a long alkyl chain quaternary ammonium salt.Can be used for a long alkyl chain quaternary ammonium salt of the present invention is that wherein a long alkyl chain contains 12 to 28 carbon atoms, those of preferred 16 to 22 carbon atoms.A highly preferred long alkyl chain quaternary ammonium salt is for example cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride.Although these long alkyl chain cationic surfactants are preferred, but other cationic surfactant such as two long alkyl chain cationic surfactant also can use separately, or unite use with a long alkyl chain cationic surfactant and/or non-ionic surface active agent.
Can be used for cationic surfactant of the present invention and comprise those of general molecular formula (I) for example:
R wherein
71, R
72, R
73And R
74In at least one be selected from aliphatic group or have at most aromatics, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or kiki fang alkyl group of about 22 carbon atoms, remaining R with 8 to 30 carbon atoms
71, R
72, R
73And R
74Be independently selected from and have 1 to the aliphatic group of about 22 carbon atoms or have aromatics, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the kiki fang alkyl group of about 22 carbon atoms at most; X is into salt anionic as being selected from those of halogen (as chloride ion, bromide ion), acetate, citrate, lactate, glycolate, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl sulfonic acid foundation.Except carbon atom and hydrogen atom, aliphatic group also can comprise ehter bond and other group such as amino.Than the aliphatic group of long-chain, as have about 12 carbon atoms or more those, can be saturated or unsaturated.Preferably work as R
71, R
72, R
73And R
74Be independently selected from C
1To about C
22During alkyl.
In the middle of the cationic surfactant of general formula (I), preferably those comprise the surfactant of at least one alkyl chain in molecule, and described alkyl chain has at least 16 carbon atoms.The non-limiting example of above-mentioned preferred cationic surfactants comprises: INCROQUAT TMC-80 ECONOL TM22, for example with trade name Genamine KDMP available from Clariant, with trade name INCROQUATTMC-80 available from Croda and with trade name ECONOL TM22 available from Sanyo Kasei; The cetyl trimethyl ammonium chloride, for example with trade name CTAC 30KC available from KCI and with trade name CA-2350 available from Nikko Chemicals; The stearyl trimethyl ammonium chloride, for example with trade name Genamine STACP available from Clariant; The oil base dimethyl benzyl ammonium chloride, for example with trade name Incroquat O-50 available from Croda; Hydrogenated tallow alkyl trimethyl ammonium chloride, dialkyl group (14-18) alkyl dimethyl ammonium chloride, two tallow alkyl alkyl dimethyl ammonium chlorides, dihydro tallow alkyl alkyl dimethyl ammonium chloride, VARISOFT TA100 and Varisoft 432PPG.
The cationic surfactant that preferably also has hydrophilic replacement, wherein at least one substituent group comprises one or more aromatics that exist with substituent group or coupling part, ether, ester, amide or amino part, wherein R in the group chain
71To R
74At least one contains one or more hydrophilic segments in the base, and described hydrophilic segment is selected from alkoxyl (preferred C
1To C
3Alkoxyl), polyoxyalkylenes (preferred C
1To C
3Polyoxyalkylenes), alkyl amido, hydroxy alkyl, Arrcostab, and their combination.Preferably, the cationic conditioning surfactant of this hydrophilic replacement contains 2 to about 10 nonionic hydrophilic segments that are positioned at above-mentioned scope.Highly preferred hydrophilic replacement cationic surfactant comprises dialkyl group acylamino-ethyl-hydroxyethyl ammonium salt, dialkyl group acylamino-ethyl di-ammonium salts, two alkanoyl ethyl-hydroxyethyl ammonium salts, two alkanoyl second di-ammonium salts, and their mixture; For example commercially available with following trade name: VARISOFT 110, VARISOFT 222, VARIQUAT K1215 and VARIQUAT 638 (available from Witco Chemical), MACKPRO KLP, MACKPRO WLW, MACKPROMLP, MACKPRO NSP, MACKPRO NLW, MACKPRO WWP, MACKPRONLP, MACKPRO SLP (available from McIntyre), ETHOQUAD 18/25, ETHOQUADO/12PG, ETHOQUAD C/25, ETHOQUAD S/25 and ETHODUOQUAD (available from Akzo), DEHYQUAT SP (available from Henkel) and ATLAS G265 (available from ICIAmericas).Also be preferred in the said composition available from the babassu base acylamino-propyl-dimethyl benzyl ammonium chloride of Croda with trade name Incroquat BA-85.
Amine is suitable for as cationic surfactant.Primary aliphatic amine, secondary fatty amine and uncle's fatty amine are useful.What be particularly useful is uncle's amidoamines, and this uncle's amidoamines has about 12 alkyl to about 22 carbon atoms.Exemplary uncle's amidoamines comprises: the amino propyl group dimethylamine of stearoyl, the amino propyl group diethylamide of stearoyl, the amino ethyl diethylamide of stearoyl, the amino ethyl dimethyl amine of stearoyl, palmityl aminopropyl dimethyl amine, palmityl aminopropyl diethylamide, palmityl amino-ethyl diethylamide, palmityl amino-ethyl dimethyl amine, docosane acylamino-propyl-dimethyl amine, docosane acylamino-propyl group diethylamide, docosane acylamino-ethyl diethylamide, docosane acylamino-ethyl dimethyl amine, eicosane acylamino-propyl-dimethyl amine, eicosane acylamino-propyl group diethylamide, eicosane acylamino-ethyl diethylamide, eicosane acylamino-ethyl dimethyl amine, diethylamino ethyl stearmide.Useful amine is disclosed in people's such as Nachtigal the United States Patent (USP) 4,275,055 among the present invention.These amine also can be united use with acid, as l-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, l-glutamic acid hydrochloride, maleic acid, and their mixture; More preferably l-glutamic acid, lactic acid, citric acid.Preferably with any one the part neutralization in these acid, wherein amine is about 1: 0.3 to about 1: 2 with the mol ratio of acid to amine herein, more preferably from about 1: 0.4 to about 1: 1.
Described cationic surfactant can be included in content in the described compositions by weight for about 0.1% to about 2.0%, and preferred about 0.2% to about 1.2%, and more preferably from about 0.4% to about 1.0%.
Non-ionic surface active agent
Multiple non-ionic surface active agent can be used for the present composition.The non-limiting example of non-ionic surface active agent for example comprise following these:
(1) the polyoxyethylene alkene condensate of alkyl phenol, the condensation substance of the alkyl phenol of straight or branched configuration (containing about 6 in the alkyl) and oxirane for example to about 20 carbon atoms, the content of described oxirane equals every mole of alkyl phenol about 10 to about 60 moles of ethylene oxide.
(2) those that obtain by oxirane and propylene oxide and the condensation of ethylenediamine product reaction products therefrom.
(3) the straight or branched configuration contains about 8 to the aliphatic alcohol of about 18 carbon atoms and the condensation product of oxirane, as the coconut alcohol ethylene oxide condensate, wherein the content of oxirane be every mole of coconut alcohol about 10 to about 30 moles of ethylene oxide, described coconut alcohol partly has about 10 to about 14 carbon atoms.
(4) formula is R
1R
2R
3The long chain tertiary amine oxide of N → O, wherein R
1Comprise have about 8 alkyl, alkenyl or monohydroxy alkyl to about 18 carbon atoms, about 0 to about 10 ethylene oxide moieties and 0 to about 1 glyceryl; R
2And R
3Comprise about 1 to about 3 carbon atoms and 0 to about 1 hydroxyl, for example methyl, ethyl, propyl group, ethoxy or hydroxypropyl.
(5) formula is the long chain tertiary phosphine oxide of [RR ' R " P → O]; wherein to comprise chain length be about 8 alkyl to about 18 carbon atoms, alkenyl or monohydroxy alkyl to R; 0 to about 10 ethylene oxide moieties; and 0 to 1 glyceryl part, " each is to comprise about 1 alkyl or monohydroxy alkyl to about 3 carbon atoms for R ' and R.
(6) long-chain dialkyl sulphoxide, it contains one and has 1 short-chain alkyl or hydroxy alkyl (being generally methyl) and long-chain hydrophobic chain to about 3 carbon atoms, this hydrophobic chain comprises and contains have an appointment 8 alkyl to about 20 carbon atoms, alkenyl, hydroxyalkyl or ketone alkyl that about 0 to about 10 ethylene oxide groups and 0 to 1 glyceryl.
(7) alkyl polysaccharide (APS) surfactant (as alkyl polyglycoside), embodiment is described in United States Patent (USP) 4,565, in 647, this full patent texts is introduced the present invention for your guidance, it discloses to contain has an appointment 6 to the hydrophobic group of about 30 carbon atoms and with the APS surfactant of polysaccharide (as, poly glucoside) as hydrophilic group; Optional can have a polyalkylene oxide groups to connect described hydrophobic and hydrophilic segment; And described alkyl (that is, hydrophobic part) can be saturated or unsaturated, side chain or non-side chain and unsubstituted or replace (as, replaced by hydroxyl or cyclic ring); Preferred material is an alkyl polyglucoside, and its city is sold by Henkel, ICI Americas and Seppic; With
(8) polyoxyethylene alkyl ether is suc as formula being RO (CH
2CH
2O)
nThose of H, and Polyethylene Glycol (PEG) glyceryl aliphatic ester are suc as formula being R (O) OCH
2CH (OH) CH
2(OCH
2CH
2)
nThose of OH, wherein n is 1 to about 200, preferred about 20 to about 100, and R contains about 8 alkyl to about 22 carbon atoms.
Can be used for of the present invention as above-mentioned (8) described glycerin ether polyethyleneglycol derivative and comprise the derivant of glycerol one, two and three esters and their mixture.The glycerin ether polyethyleneglycol derivative that one class is suitable for this paper is those of general molecular formula (I):
Wherein degree of ethoxylation n is about 4 to about 200, and preferred about 5 to about 150, and more preferably from about 20 to about 120, and wherein R comprises having about 5 to about 25 carbon atoms, preferred about 7 aliphatic groups to about 20 carbon atoms.Suitable glyceride polyethyleneglycol derivative can be the polyethyleneglycol derivative of castor oil hydrogenated.This polyethyleneglycol derivative of castor oil hydrogenated comprises for example PEG-20 castor oil hydrogenated, PEG-30 castor oil hydrogenated, PEG-40 castor oil hydrogenated, PEG-45 castor oil hydrogenated, PEG-50 castor oil hydrogenated, PEG-54 castor oil hydrogenated, PEG-55 castor oil hydrogenated, PEG-60 castor oil hydrogenated, PEG-80 castor oil hydrogenated and PEG-100 castor oil hydrogenated.
Other suitable glyceride polyethyleneglycol derivative can be stearic polyethyleneglycol derivative.Stearic this polyethyleneglycol derivative comprises for example PEG-30 stearate, PEG-40 stearate, PEG-50 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate and PEG-150 stearate.
Can be used for the glycol ether that of the present invention as above-mentioned (3) or (8) described aliphatic alcohol second diether comprise any aliphatic alcohol, it is applicable in the hair care composition.The non-limiting example of aliphatic alcohol glycol ether comprises: the ceteth series compound, to ceteth-45, preferred ceteth-7 is to ceteth-20 as ceteth-1; Isocetyl polyoxyethylene ether series compound is as Arlasolve 200; Stearyl polyoxyethylene ether series compound, as stearyl polyoxyethylene ether-1 to 100; Cetearyl polyoxyethylene ether 1 is to cetearyl polyoxyethylene ether-50; The laureth series compound, preferred laureth-7 is to laureth-12; Alkanol polyether series chemical compound, preferred alkanol polyethers-9 is to alkanol polyethers-15; The propylene glycol of above-mentioned ceteth, stearyl polyoxyethylene ether, cetearyl polyoxyethylene ether and laureth series compound, the propylene glycol of these ceteth series compounds comprise for example PPG-5-ceteth-20; The polyoxyethylene ether of branched-chain alcoho or polyoxyethylene polyoxypropylene ether, these branched-chain alcohos comprise for example octyl dodecanol, decyl tetradecyl alchohol, dodecyl pentadecanol and isooctadecanol, and the polyoxyethylene polyoxypropylene ether of these branched-chain alcohos comprises for example POE (20) POP (6) decyl ten tetraethers; And their mixture.
Can be used for other ionic surfactant pack of the present invention, to draw together HLB value for example be 16.7 polysorbate such as polysorbate-20 (POE (20) sorbitan one lauric acid ester), the HLB value is 13.3 polysorbate-21 (POE (4) sorbitan one lauric acid ester), the HLB value is 15.6 polysorbate-40 (POE (20) sorbitan monopalmitin), the HLB value is 14.9 polysorbate-60 (POE (20) monostearate Isosorbide Dinitrate), and the HLB value is 9.6 polysorbate-61 (POE (4) monostearate Isosorbide Dinitrate), the HLB value is that 15.0 polysorbate-80 (POE (20) dehydrated sorbitol mono-fatty acid ester) and HLB value are 10.0 polysorbate-81 (POE (4) dehydrated sorbitol mono-fatty acid ester).
The HLB value that preferably can be used for non-ionic surface active agent of the present invention is for about 8 to about 22, and more preferably from about 11 to about 20, and also preferred about 13 to about 15.
In above-mentioned multiple non-ionic surface active agent, it is highly preferred that to be selected from Arlasolve 200, PPG-5-ceteth-20, PEG-40 castor oil hydrogenated, polysorbate-20, laureth-20, ceteth-10, ceteth-20, and those of their mixture.
Non-ionic surface active agent can be included in content in the described compositions by weight for about 0.1% to 6.0%, and preferred about 0.4% to about 5.0%, and more preferably from about 1.0% to about 4.0%.
Silicone compounds
Compositions of the present invention comprises silicone compounds.The content of silicone compounds in described compositions is about 0.1% to about 10% by weight, and more preferably from about 0.5% to about 8%, also more preferably from about 1% to about 6%, even more preferably from about 2% to about 5%.
Because the outward appearance that expectation is transparent or semitransparent, in multiple silicone compounds, preferably be selected from (i) siloxanes nanoemulsions, when it is contained in the compositions, mean diameter is 300nm or littler, preferred 200nm or littler, more preferably 100nm or littler, (ii) be dissolvable in water the silicone compounds in the described compositions substantially, and (iii) their those of mixture." soluble substantially " silicone compounds is meant when when 25 ℃ comprise silicone compounds with used content to have 50% or bigger, and is preferred about 65% or bigger, more preferably from about 80% or the compositions of bigger transmittance.
Can be used for commercially available siloxanes nanoemulsions of the present invention comprises for example with the siloxanes nanoemulsions of trade name SiliconeDC-8177 available from Dow Corning; With the quaternized siloxanes nanoemulsions of trade name DC5-7133 available from Dow Corning; And with the amino-terminated polydimethylsiloxane nanoemulsions of trade name XS65-B6413 available from General Electric.
For soluble substantially silicone compounds, for example, following material can be soluble substantially, and this depends on the content of hydrophilic group in their structures: silicone copolyol is as being called the dimethicone copolyol of Silicone DC-5330 available from Dow Corning with commodity; Amino silicone as the content of amine enough high so that as described in amino silicone soluble substantially those; The amino-terminated polydimethylsiloxane of amino silicone polyol such as INCI called after two (C13-15 alkoxyl) PG, can trade name DC2-8500 available from those of Dow Corning; The amino silicone polyol of hydrophobically modified; The amido silicone copolyol of hydrophobically modified; With quaternized siloxanes.In these soluble substantially silicone compounds, more preferably be selected from the amino silicone polyol of amino silicone, amino silicone polyol, hydrophobically modified, the amido silicone copolyol of hydrophobically modified, and those of their mixture, the amido silicone copolyol of hydrophobically modified more preferably also, because the silicone deposition of improvement is provided, thereby the conditioning performance of improvement is provided, satisfies the needs of transparent or semitransparent outward appearance simultaneously.The amino methyl silicone copolyol of these hydrophobically modifieds has general formula:
R wherein
1, R
2, R
4Be respectively the C1-C3 alkyl, preferred ethyl; R
3For having 8 to 22 carbon atoms, preferred 10 to 20 carbon atoms, more preferably 12 to 16 carbon atoms, even the more preferably alkyl of 12 carbon atoms; R
5Be H or C1-C3 alkyl, preferable methyl; R
6Be OH or CH
3, preferable methyl; N is 1 to 10, highly preferred 5 integer; M is 2 to 20, highly preferred 12 integer; N+m=3 to 30, preferred 5 to 25, more preferably 8 to 20, even more preferably 17; X is 200 to 500, preferred 300 to 400 integer; Y is 5 to 40, preferred 10 to 30 integer; And z is 0 or 1 to 30, preferred 5 to 20 integer.The amido silicone copolyol of commercially available hydrophobically modified for for example have INCI called after PEG-12 methyl ether/Laurel oxygen base PEG-5 amido propyl polydimethylsiloxane can trade name Silicone BY16-906 available from those of Dow Corning.
Because the conditioning beneficial effect of improvement is provided, and preferred compositions of the present invention provides improved silicone deposition, though with compositions from hair after the flush away.For example, preferred said composition provides about 50ppm or more behind flush away from hair, 100ppm or more more preferably from about, more preferably 200ppm or more also, even more preferably 400ppm or more silicone deposition.The silicone deposition amount can be measured by the method that may further comprise the steps: (i) preparation sent out bunch of hair; (ii) silicone deposition is measured.
(i) preparation sent out bunch of hair
For the measurement of silicone deposition, use 2 grams to send out bunch.Prepare to send out bunch by following steps:
(a) provide five shampoos of taking turns/conditioning to handle to this bunch, each is taken turns shampoo/conditioning processing and may further comprise the steps:
(a-1) use shampoo with the amount of 0.2cc and make a bunch foaming; Clean to send out then bunch;
(a-2) use shampoo once more with the amount of 0.2cc and make a bunch foaming; Clean to send out then bunch; With
(a-3) bunch nurse one's health processing to sending out then, this conditioning is handled and is comprised with the amount of 0.2cc and use conditioner and handle bunch; Clean to send out then bunch; With
(b) dry then bunch.
This bunch preparation is used to measure its silicone deposition amount.
(ii) silicone deposition is measured
Be extracted in a bunch last sedimentary siloxanes with appropriate solvent.Then this extracting solution is imported Atomic Absorption/emission detector device and under suitable wavelengths, measure.Then, by external calibration curve, the absorption/emission value that instrument can be reported changes on the hair actual concentrations (ppm) of deposition siloxanes, and this external calibration curve is from the silicone compounds of studying (the standardization preferably) acquisition of known weight.
Aqueous carrier
Compositions of the present invention comprises aqueous carrier.According to selecting the content and the kind of described carrier with required other characteristic of the compatibility of other component and product.
Be used for the aqueous solution that carrier of the present invention comprises water and lower alkyl alcohol.Being used for lower alkyl alcohol of the present invention is the monohydric alcohol with 1 to 6 carbon atom, more preferably ethanol and isopropyl alcohol.
Preferred aqueous carrier is water basically.The preferred deionized water that uses.The characteristic required according to product also can be used the water of the natural origin that comprises mineral cation.Usually, compositions of the present invention comprises about 20% to about 99%, and preferred about 40% to about 98%, more preferably from about 50% to about 98% water.
The pH value of the present composition is preferably about 2 to about 8, more preferably about 3 to about 7, and also more preferably 4 to 6.Can add buffer agent and other pH regulator agent to obtain required pH value.
Annexing ingredient
The compounds of this invention can comprise annexing ingredient, these annexing ingredients can be selected according to the characteristic of required final products by the technical staff, and these annexing ingredients be suitable for making said composition beauty treatment or aesthetic easilier be accepted or make it to have additional use beneficial effect.
Cationic conditioning polymer
Care composition of the present invention also can comprise cationic conditioning polymer.The common weight average molecular weight that has of cationic polymer herein is at least about 5,000, and the typical case is at least about 10,000, and less than about 1,000 ten thousand, preferably its molecular weight is about 100,000 to about 200 ten thousand.
Described cationic conditioning polymer is included in content in the described compositions and is preferably about 0.01% by weight to about 10%, and more preferably from about 0.05% to about 5%.
Suitable cationic conditioning polymer comprises, for example: l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (as, chloride salt) copolymer is (industrial by Cosmetic, Toiletry, and Fragrance Association, " CTFA " is called polyquaternary ammonium salt-16), as with trade name LUVIQUAT (as LUVIQUAT FC 370) available from BASF Wyandotte Corp. (Parsippany, NJ, USA) those; The copolymer of l-vinyl-2-pyrrolidone and dimethylamino methyl ethyl acrylate (being called polyquaternary ammonium salt-11 by CTFA) industrial, as with trade name GAFQUAT (as GAFQUAT 755N) available from Gaf Corporation (Wayne, NJ, USA) those; The polymer of cation diallyl quaternary ammonium ion comprises the copolymer of dimethyl diallyl ammonium chloride homopolymer for example and acrylamide and dimethyl diallyl ammonium chloride, be called polyquaternary ammonium salt 6 and polyquaternary ammonium salt 7 at industrial (CTFA), polyquaternary ammonium salt-7 comprises with trade name Merquat 550 available from those of Ondeo Nalco; Polyisobutylene acyl group amido propyl trimethyl ammonia chloride, as with trade name Polycare 133 available from those of Rhone-Poulenc; And with trade name Synthalen CR, Synthalen CU and Synthalen CN polyquaternary ammonium salt-37 available from 3V Sigma.
The cationic conditioning polymer that this paper is suitable also comprises cationic cellulose derivative.Can be used for cationic cellulose derivative of the present invention and comprise the epoxide reaction that for example hydroxyethyl-cellulose and trimethyl ammonium replace and the salt that generates, it is called polyquaternary ammonium salt 10 in this area (CTFA), with their Polymer JR
And LR
Series available from Amerchol Corp. (Edison, NJ, USA), also with trade name Celquat SC-230M available from National Starch ﹠amp; Chemical; With with trade name CelquatH-100 available from National Starch ﹠amp; The polyquaternary ammonium salt of Chemical-4.
Other suitable cationic conditioning polymer comprises the cationic guar gum derivant, as with their Jaguar series available from the Rhaball Gum CG-M 8M of Rhodia.
Wetting agent and/or cosolvent
Compositions of the present invention can comprise wetting agent and/or cosolvent, is dissolvable in water described compositions substantially to help described surfactant system and/or silicone compounds.The wetting agent of this paper and/or cosolvent are selected from polyhydric alcohol, water soluble alkoxylated non-ionic polymers, and their mixture.By described composition weight meter, the wetting agent of this paper and/or cosolvent be preferably with about 0.1% to about 20%, more preferably uses with about 0.5% to about 5% content.
Can be used for polyhydric alcohol of the present invention and comprise glycerol, sorbitol, propylene glycol, butanediol, hexanediol, ethoxylated glucose, 1,2-hexanediol, hexanetriol, dipropylene glycol, erithritol, trehalose, diglycerol, xylitol, maltose alcohol, maltose, glucose, fructose, sodium chondroitin sulfate, hyaluronate sodium, adenylic acid sodium, sodium lactate, ketopyrrolidine carbonate, glycosamine, cyclodextrin, and their mixture.In these polyhydric alcohol, preferred cosolvent is 1,2-hexanediol, hexanediol, butanediol, glycerol, and their mixture.
The water soluble alkoxylated non-ionic polymers that can be used for this paper comprises molecular weight about 10,000 Polyethylene Glycol and polypropylene glycol at most, for example those of CTFA called after PEG-4, PEG-8, PEG-12, PEG-20, PEG-150, and their mixture.
Other annexing ingredient
The present composition also can comprise other annexing ingredient.The independent consumption of other annexing ingredient is generally about 0.001% to about 10%, preferred maximum about 5% by the weight of described compositions.
Various other annexing ingredients can be formulated in the compositions of the present invention.These components comprise: other conditioner, as hydrolytic collagen (with trade name Peptein 2000 available from Hormel), vitamin E (with trade name Emix-d available from Eisai), pantothenylol (available from Roche), general benzyl ethyl ether (available from Roche); Non-ionic surface active agent is as tristerin (available from StepanChemicals), hydrolysis of keratin, protein, plant extract and nutrient substance; Emollient is as PPG-3 myristyl ether (with trade name Varonic APM available from Goldschmidt), trimethyl amylalcohol hydroxyethyl ether, PPG-11 stearyl ether (with trade name Varonic APS available from Goldschmidt), stearyl heptanoate (with trade name Tegosoft SH available from Goldschmidt), Lactil (sodium lactate, PCA sodium, glycine, fructose, urea, nicotiamide, inositol, the mixture of sodium benzoate and lactic acid) (available from Goldschmidt), the ethylhexyl cetylate (with trade name Saracos available from NishinSeiyu and with trade name Tegosoft OP available from Goldschmidt); The hair fixed polymer is as both sexes fixed polymer, stationary cation polymer, anion fixed polymer, nonionic fixed polymer and silicone grafted copolymer; Antiseptic is as benzyl alcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; The pH regulator agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is usually as potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as thioglycolate salt; Spice; And sequestering agent, as disodiumedetate; Ultraviolet and infrared shield agent and absorbent are as ethylhexyl salicylate; The dandruff agent is as Zinc Pyrithione and salicylic acid; Visible particle (with trade name Unisphere and Unicerin available from InduchemAG (Switzerland)); And defoamer, as with trade name XS63-B8929 available from those of GE-ToshibaSilicone.
Product form
Care composition of the present invention can be rinse-off products or leave product form, can be transparent, translucent or opaque, and can be mixed with various product forms, includes but not limited to cream, gel, emulsion, mousse and spray.
Care composition of the present invention can be nursed one's health multiple substrate by described compositions is applied on substrate such as hair, skin and the fabric, as hair, skin and fabric.Care composition of the present invention is particularly useful for hair care product (as hair conditioner), skin nursing products (as skin conditioning agent) and fabric care product (as fabric softener).
Care composition of the present invention is particularly useful for the hair conditioner of washing-off type purposes.Above-mentioned composition preferably follows these steps to use:
(i) after the hair washing, the care composition of coating effective dose is with conditioning hair on hair; With
(ii) clean hair then.
Embodiment
The following example further describes and the interior embodiment of for example clear scope of the invention.These embodiment that given only are illustrative, and are unintelligible for being limitation of the present invention, because can carry out many changes in the case of without departing from the spirit and scope of protection of the present invention.Unless limit in addition below, composition is all with chemical name or CTFA name identification.
Form (wt%)
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | |
| The crosslinked cationic thickening polymers of hydrophobically modified-1 *1 | 2.0 | 4.0 | 2.0 | 2.0 | 1.8 | 2.5 | 2.0 | 2.2 | 2.0 | 2.5 | 1.0 |
| Ceteth-10 *3 | - | - | - | 3.0 | - | - | - | - | - | - | - |
| PPG-5-ceteth-20 *5 | - | - | - | - | 2.0 | 2.0 | - | - | - | - | - |
| Laureth-25 *6 | - | - | - | - | - | - | 3.0 | - | - | - | - |
| Polysorbate-20 *7 | - | - | - | - | - | - | - | 4.0 | 1.0 | 1.0 | - |
| The cetyl trimethyl ammonium chloride *8 | 0.8 | 0.5 | - | - | 0.4 | - | - | - | 0.5 | - | 1.0 |
| The stearyl trimethyl ammonium chloride *9 | - | - | 1.0 | - | - | - | - | - | - | - | - |
| Amino-terminated dimethicone copolyol *10 | - | - | 2.0 | - | - | - | - | 1.0 | - | - | - |
| Quaternized siloxanes nanoemulsions *11 | - | 1.0 | - | - | - | - | - | - | - | 1.0 | 0.6 |
| The amino methyl silicone copolyol of hydrophobically modified *12 | 4.0 | 1.0 | 2.0 | 4.0 | 4.0 | 2.0 | 3.0 | 2.0 | - | - | - |
| Dimethicone copolyol *13 | - | - | - | - | - | - | - | - | 2.0 | - | - |
| 1, the 2-hexanediol | - | - | - | - | - | - | 1.0 | - | - | - | - |
| PEG-12 *14 | - | - | - | - | - | - | - | 1.0 | 1.0 | - | - |
| PEG-200 *15 | - | - | - | - | - | 1.0 | - | - | - | 1.0 | - |
| Kathon CG *16 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 |
| Lactic acid | 0.43 | 0.86 | 0.43 | 0.43 | - | 0.54 | - | - | - | 0.54 | - |
| Glycolic | - | - | - | - | 0.35 | - | 0.36 | 0.38 | 0.36 | - | 0.18 |
| Disodiumedetate | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 |
| The m-p-Hydroxybenzoate | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Spice | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
| Deionized water | -----in right amount is to 100%----- | ||||||||||
Form (wt%)
| 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 | 21 | |
| The crosslinked cationic thickening polymers of hydrophobically modified-1 *1 | - | - | 2.0 | 2.0 | 2.0 | - | 3.5 | 3.0 | 1.5 | 2.5 |
| The crosslinked cationic thickening polymers of hydrophobically modified-2 *2 | 2.5 | 3.0 | - | - | - | 2.0 | - | - | - | - |
| Ceteth-10 *3 | - | - | - | - | - | 3.0 | - | - | - | - |
| Ceteth-20 *4 | - | - | - | 0.5 | - | - | 2.0 | - | 3.0 | - |
| PPG-5-ceteth-20 *5 | - | - | 1.0 | - | - | - | - | 4.0 | - | - |
| Laureth-25 *6 | - | 1.0 | - | - | - | - | - | - | - | - |
| Polysorbate-20 *7 | 0.8 | 0.8 | - | - | 0.5 | 2.0 | - | - | - | - |
| The cetyl trimethyl ammonium chloride *8 | - | - | 0.8 | 0.5 | 1.0 | - | - | - | - | 0.65 |
| The stearyl trimethyl ammonium chloride *9 | - | 2.0 | - | - | 1.0 | - | - | 0.5 | - | - |
| Amino-terminated poly dimethyl silicon | - | - | - | - | - | - | - | 2.0 | - | - |
| Oxygen alkane polyol *10 | - | - | - | - | - | - | - | - | - | - |
| Quaternized siloxanes nanoemulsions *11 | 3.0 | 4.0 | - | - | - | - | - | - | - | - |
| The amino methyl silicone copolyol of hydrophobically modified *12 | - | - | 5.0 | 3.0 | 1.0 | 4.0 | 1.5 | - | 2.0 | - |
| Dimethicone copolyol *13 | 1.0 | - | - | - | - | - | - | - | - | 3.0 |
| 1, the 2-hexanediol | - | 2.0 | - | - | - | - | 1.0 | - | - | 1.0 |
| Butanediol | - | - | - | - | - | - | - | - | 2.0 | - |
| PEG-12 *14 | - | - | - | 1.0 | - | - | - | - | - | 1.0 |
| PEG-200 *15 | 0.5 | 1.0 | - | - | 1.5 | - | - | 1.0 | - | - |
| Kathon CG *16 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 | 0.033 |
| Lactic acid | 0.54 | 0.65 | 0.43 | - | - | 0.43 | 0.75 | 0.65 | 0.33 | 0.54 |
| Glycolic | - | - | - | 0.36 | 0.36 | - | - | - | - | - |
| Disodiumedetate | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 | 0.127 |
| The m-p-Hydroxybenzoate | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
| Spice | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 | 0.3 |
| Deionized water | -----in right amount is to 100%----- | |||||||||
The component definition
*The crosslinked cationic thickening polymers of 1 hydrophobically modified-1: acrylate/amino acrylates/vinyl alcoxyl acid esters/C10-30 alkyl PEG-25 methacrylate: EX-832, available from Noveon
*The crosslinked cationic thickening polymers of 2 hydrophobically modifieds-2: acrylate/amino acrylates/vinyl alcoxyl acid esters/C10-30 alkylmethacrylate/PEG-15 methacrylate
*3 ceteths-10:BC-10TX are available from Nikko Chemicals
*4 ceteths-20:BC-20TX are available from Nikko Chemicals
*5PPG-5-ceteth-20:Procetvl AWS is available from Croda
*6 laureth-25:BL-21 are available from Nikko Chemicals
*7 polysorbates-20:Glycosperse L-20K are available from Lonza
*8 cetyl trimethyl ammonium chlorides: CTAC 30KC, available from KCI
*9 stearyl trimethyl ammonium chlorides: Genamine STACP, available from Clariant
*10 amino-terminated dimethicone copolyol: DC2-8500 are available from Dow Corning
*11 quaternized siloxanes nanoemulsions: DC5-7133 are available from Dow Corning
*The amino methyl silicone copolyol of 12 hydrophobically modifieds: BY16-906 is available from Dow Corning
*13 dimethicone copolyols: DC-5330 is available from Dow Corning
*14PEG-12: available from Dow Chemical
*15PEG-200:Emkapol is available from ICI
*16 methylchloroisothiazandnone/Methylisothiazolinone: Kathon CG, available from Rohm﹠amp; Haas
Preparation method
As mentioned above, the care composition of " embodiment 1 " to " embodiment 21 " can be by any conventional method preparation well known in the art.They can followingly suitably prepare:
Polymeric material at room temperature is scattered in the water, and vigorous stirring is mixed.Additionally, silicone compounds, surfactant system and other oily components (if comprising) are mixed under room temperature as spice.Stirring the mixture that will comprise silicone compounds and surfactant system down adds in the described polymeric dispersions.Then, stir down remaining component is added as antiseptic, defoamer and pH regulator agent as described in the mixture.
Embodiment 1 to 21 is the care compositions of the present invention that are particularly useful for the hair conditioner of washing-off type purposes.These embodiment have many advantages.For example, when being used for hair care product such as hair-conditioning product, the compositions of " embodiment 1 " to " embodiment 21 " has the rheological behavior that is suitable for care composition and the conditioning beneficial effect is provided, and the especially wet flexibility of sending out is twined with reducing.The compositions of " embodiment 1 " to " embodiment 4 " has transparent or translucent outward appearance.When being used for hair care product, the compositions of " embodiment 1 " to " embodiment 21 " can provide above-mentioned rheological behavior and conditioning beneficial effect, does not force down hair simultaneously.When using with the rinse-off products form, " embodiment 1 " to the compositions of " embodiment 21 " can provide the sensation that is easy to rinsing, and above-mentioned rheology beneficial effect and conditioning beneficial effect are provided simultaneously.
The relevant portion of all documents of quoting in detailed Description Of The Invention is incorporated herein by reference; It is to its approval as prior art of the present invention that the quoting of any document not can be regarded as.Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that many other variations and modifications may be made in the case of without departing from the spirit and scope of protection of the present invention.Therefore, in additional claims, comprise all such changes and modifications in the scope of the invention consciously.
Claims (36)
1. care composition, described care composition comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% the surfactant system that comprises cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds; With
(d) aqueous carrier.
2. care composition, described care composition comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% surfactant system, described system comprise the HLB value and are about 11 to about 20 non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds; With
(d) aqueous carrier.
3. care composition, described care composition comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.01% to about 6.0% hydrophobically modified;
(b) about 0.1% to about 8.0% surfactant system, described surfactant system is selected from cationic surfactant, non-ionic surface active agent, and their mixture;
(c) about 0.1% to about 10% silicone compounds, wherein said silicone compounds is selected from mean diameter in the described compositions and is 300nm or littler those, is dissolvable in water those of described compositions substantially, and their mixture, and wherein said soluble substantially silicone compounds is selected from the amino silicone polyol of amino silicone, amino silicone polyol, hydrophobically modified, the amido silicone copolyol of hydrophobically modified, and their mixture; With
(d) aqueous carrier.
4. as each described care composition in the claim 1 to 3, wherein said compositions is substantially free of water-insoluble oiliness compound, and described oiliness compound is selected from hydrocarbon, aliphatic compound, and their mixture.
5. as each described care composition in the claim 1 to 3, wherein said compositions is transparent or translucent.
6. care composition as claimed in claim 5, wherein said compositions is transparent.
7. care composition as claimed in claim 6, wherein said compositions have 50% or higher transmittance.
8. care composition as claimed in claim 7, wherein said compositions have 65% or higher transmittance.
9. care composition as claimed in claim 8, wherein said compositions have 80% or higher transmittance.
10. as each described care composition in the claim 1 to 3, wherein said compositions has about 100cps to about 100, the viscosity of 000cps and 30 or higher shear thinning index.
11. it is about 1 that care composition as claimed in claim 10, wherein said compositions have, 000cps is to about 50, the viscosity of 000cps and 50 or higher shear thinning index.
12. it is about 2 that care composition as claimed in claim 11, wherein said compositions have, 000cps is to about 50, the viscosity of 000cps and 70 or higher shear thinning index.
13. it is about 5 that care composition as claimed in claim 12, wherein said compositions have, 000cps is to about 20, the viscosity of 000cps and 90 or higher shear thinning index.
14. as each described care composition in the claim 1 to 3, the crosslinked cationic thickening polymers of wherein said hydrophobically modified is the cross-linked cationic acrylate thickening polymer of hydrophobically modified.
15. as each described care composition in the claim 1 to 3, the crosslinked cationic thickening polymers of wherein said hydrophobically modified contains hydrophilic group.
16. care composition as claimed in claim 15, wherein said hydrophilic group are polyoxyalkylenes.
17. care composition as claimed in claim 16, wherein said alkylene oxide is selected from oxirane, expoxy propane, and their mixture.
18. as each described care composition in the claim 1 to 3, wherein said surfactant system is dissolvable in water described compositions substantially.
19. as claim 1 or 3 described care compositions, wherein said non-ionic surface active agent has about 8 to about 22 HLB value.
20. as claim 1 or 3 described care compositions, wherein said non-ionic surface active agent is selected from Arlasolve 200, PPG-5-ceteth-20, PEG-40 castor oil hydrogenated, polysorbate-20, laureth-20, ceteth-10, ceteth-20, and their mixture.
21. as claim 1 or 3 described care compositions, wherein said cationic surfactant is selected from two long alkyl quaternary ammonium salt, a long alkyl chain amine, the dialkyl group streptamine of a long alkyl quaternary ammonium salts, two long alkyl quaternary ammonium salt, a long alkyl quaternary ammonium salts of hydrophilic replacement, hydrophilic replacement, and their mixture.
22. care composition as claimed in claim 21, wherein said cationic surfactant are selected from cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, Varisoft 432PPG, and their mixture.
Be 300nm or littler those, be dissolvable in water those of described compositions and their mixture substantially 23. care composition as claimed in claim 1 or 2, wherein said silicone compounds are selected from described compositions mean diameter.
24. care composition as claimed in claim 23, wherein said soluble substantially silicone compounds is selected from the amino silicone polyol of amino silicone, amino silicone polyol, hydrophobically modified, the amido silicone copolyol of hydrophobically modified, and their mixture.
25. care composition as claimed in claim 24, wherein said silicone compounds are the amido silicone copolyols of hydrophobically modified.
26. as each described care composition in the claim 1 to 3, described care composition also comprises cosolvent.
27. care composition as claimed in claim 26, wherein said cosolvent is selected from 1,2-hexanediol, hexanediol, butanediol, glycerol, and their mixture.
28. as each described care composition in the claim 1 to 3, described care composition comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.1% to about 5.0% hydrophobically modified;
(b) about 0.2% to about 5.0% surfactant system;
(c) about 0.5% to about 8.0% silicone compounds; With
(d) aqueous carrier.
29. care composition as claimed in claim 26, described care composition comprises by weight:
(a) crosslinked cationic thickening polymers of about 0.3% to about 4.0% hydrophobically modified;
(b) about 0.4% to about 4.0% surfactant system;
(c) about 1.0% to about 6.0% silicone compounds; With
(d) aqueous carrier.
30. as each described care composition in the claim 1 to 3, described care composition is a hair care composition.
31. as each described care composition in the claim 1 to 3, described care composition is used for the washing-off type purposes.
32. as each described care composition in the claim 1 to 3, described care composition provides about 50ppm or more silicone deposition behind flush away from described hair.
33. care composition as claimed in claim 32, described care composition provide about 100ppm or more silicone deposition behind flush away from described hair.
34. care composition as claimed in claim 33, described care composition provide about 200ppm or more silicone deposition behind flush away from described hair.
35. care composition as claimed in claim 34, described care composition provide about 400ppm or more silicone deposition behind flush away from described hair.
36. the method for a conditioning hair said method comprising the steps of:
(i) after shampoo is sent out, with being administered on the hair with hair as described in nursing one's health of effective dose as each described care composition in the claim 1 to 3; With
The (ii) described hair of rinsing then.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US54339704P | 2004-02-10 | 2004-02-10 | |
| US60/543,397 | 2004-02-10 | ||
| US60/580,525 | 2004-06-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1917853A true CN1917853A (en) | 2007-02-21 |
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ID=37738609
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200580004559 Pending CN1917853A (en) | 2004-02-10 | 2005-02-09 | Conditioning compositions comprising hydrophobically modified crosslinked cationic thickening polymers |
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| CN (1) | CN1917853A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102448549A (en) * | 2008-12-12 | 2012-05-09 | 宝洁公司 | Hair conditioning composition comprising a cationic surfactant system and a direct dye |
| CN104837529A (en) * | 2012-12-20 | 2015-08-12 | 可泰克斯公司 | Agent for obtaining a stable aqueous composition comprising suspended particles |
| CN110536720A (en) * | 2017-04-26 | 2019-12-03 | 宝洁公司 | Composition with thickening polymer |
| US11291616B2 (en) | 2015-04-23 | 2022-04-05 | The Procter And Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
| US11446217B2 (en) | 2016-03-03 | 2022-09-20 | The Procter & Gamble Company | Aerosol antidandruff composition |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
-
2005
- 2005-02-09 CN CN 200580004559 patent/CN1917853A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102448549A (en) * | 2008-12-12 | 2012-05-09 | 宝洁公司 | Hair conditioning composition comprising a cationic surfactant system and a direct dye |
| CN102448549B (en) * | 2008-12-12 | 2014-11-12 | 宝洁公司 | Hair conditioning composition comprising cationic surfactant system and direct dye |
| CN104837529A (en) * | 2012-12-20 | 2015-08-12 | 可泰克斯公司 | Agent for obtaining a stable aqueous composition comprising suspended particles |
| US11291616B2 (en) | 2015-04-23 | 2022-04-05 | The Procter And Gamble Company | Delivery of surfactant soluble anti-dandruff agent |
| US11446217B2 (en) | 2016-03-03 | 2022-09-20 | The Procter & Gamble Company | Aerosol antidandruff composition |
| CN110536720A (en) * | 2017-04-26 | 2019-12-03 | 宝洁公司 | Composition with thickening polymer |
| US11679073B2 (en) | 2017-06-06 | 2023-06-20 | The Procter & Gamble Company | Hair compositions providing improved in-use wet feel |
| US11318073B2 (en) | 2018-06-29 | 2022-05-03 | The Procter And Gamble Company | Low surfactant aerosol antidandruff composition |
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