CN110528134A - A kind of titanium germanium conductive yarn and preparation method thereof - Google Patents

A kind of titanium germanium conductive yarn and preparation method thereof Download PDF

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Publication number
CN110528134A
CN110528134A CN201910777767.8A CN201910777767A CN110528134A CN 110528134 A CN110528134 A CN 110528134A CN 201910777767 A CN201910777767 A CN 201910777767A CN 110528134 A CN110528134 A CN 110528134A
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China
Prior art keywords
yarn
titanium germanium
germanium conductive
core wire
conductive yarn
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CN201910777767.8A
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Chinese (zh)
Inventor
卢益新
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ZHANGJIAGANG CITY HUAYI TEXTILE Co Ltd
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ZHANGJIAGANG CITY HUAYI TEXTILE Co Ltd
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Priority to CN201910777767.8A priority Critical patent/CN110528134A/en
Publication of CN110528134A publication Critical patent/CN110528134A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates
    • C23C14/205Metallic material, boron or silicon on organic substrates by cathodic sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/32Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic
    • D02G3/328Elastic yarns or threads ; Production of plied or cored yarns, one of which is elastic containing elastane
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441Yarns or threads with antistatic, conductive or radiation-shielding properties
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/063Load-responsive characteristics high strength
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/16Physical properties antistatic; conductive

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The present invention provides a kind of titanium germanium conductive yarn and preparation method thereof.The titanium germanium conductive yarn, it include: elastic core wire, yarn and aramid fiber, the yarn and the mutual doubling of the aramid fiber and the surface for being wrapped in the elastic core wire, the outer surface sputter of the yarn and the aramid fiber has titanium germanium conductive layer, the following steps are included: step 1: doubling takes yarn and is wound in yarn spool by bobbin-winding machine.The setting that titanium germanium conductive yarn provided by the invention and preparation method thereof passes through elastic core wire, the ductility of titanium germanium conductive yarn is effectively guaranteed, more extend the scope of application of titanium germanium conductive yarn, it avoids during use, the case where titanium germanium conductive yarn discovery fracture, and pass through the doubling of aramid fiber and yarn, the endurance quality of titanium germanium conductive yarn is effectively raised, so that excellent performances such as titanium germanium conductive yarn have superhigh intensity, high-modulus and high temperature resistant, acid-fast alkali-proof, light-weight, anti-aging, life cycle is long.

Description

A kind of titanium germanium conductive yarn and preparation method thereof
Technical field
The present invention relates to titanium germanium conductive yarn fields more particularly to a kind of titanium germanium conductive yarn and preparation method thereof.
Background technique
Yarn is a kind of textile, and the product of certain fineness is processed into various textile fabrics, is used for woven fabric, rope making, system Line, knitting and embroidery etc. are divided into staple yarn, continuous filaments etc..There are many representation methods, such as number, public affairs for the fineness of yarn (see numbers) such as number processed, English count, daniers.The twist of yarn is with every meter or the number of twists of per inch indicates.Sputter leads to It often refers to magnetic control sputtering plating, belongs to high-speed low temperature sputtering method, which requires vacuum degree in 1 × 10-3Torr or so, i.e., 1.3 × The vacuum state of 10-3Pa is filled with inert gas argon gas (Ar), and is added between plastic rubber substrate (anode) and metal targets (cathode) Upper high voltage direct current generates plasma due to the electron excitation inert gas that glow discharge (glow discharge) is generated, Plasma drives the atom of metal targets out of, is deposited on plastic rubber substrate with the charged of tens electron-volts or more kinetic energy Particle bombardment material surface sputters it into gas phase, can be used to etch and plated film.The original that an incident ion is sputtered Sub- number is known as that the higher sputtering rate of sputtering yield (Yield) yield is faster, and with Cu, the highests such as Au, Ag, Ti, Mo, Ta, W etc. are most It is low.Generally in 0.1-10 atom/ion.Ion can be generated with direct current glow discharge (glow discharge), in 10-1-10 Pa vacuum degree adds high pressure in two interpolars and generates electric discharge, and cation can bombard the target of negative electricity and sputter also target, and be plating to plated On object.
The case where existing titanium germanium conductive yarn has a single function, and does not have good ductility, is easy to happen fracture, and Existing titanium germanium conductive yarn durability is poor, can not prolonged use.
Therefore, it is necessary to which providing a kind of titanium germanium conductive yarn and preparation method thereof solves above-mentioned technical problem.
Summary of the invention
The present invention provides a kind of titanium germanium conductive yarn and preparation method thereof, solves existing titanium germanium conductive yarn function list One, the case where not having good ductility, be easy to happen fracture, and existing titanium germanium conductive yarn durability is poor, nothing The problem of method prolonged use.
In order to solve the above technical problems, titanium germanium conductive yarn provided by the invention, comprising: elastic core wire, yarn and aramid fiber, Outside the yarn and the mutual doubling of the aramid fiber and the surface for being wrapped in the elastic core wire, the yarn and the aramid fiber Surface sputter has titanium germanium conductive layer.
A kind of production method of titanium germanium conductive yarn, comprising the following steps:
Step 1: doubling takes yarn and is wound in yarn spool by bobbin-winding machine, separately takes aramid line and is wound in by bobbin-winding machine Then yarn spool and aramid line spool are placed into doubling frame by aramid line spool, mutual doubling is at a strand, then again Yarn is wound in by bobbin-winding machine and aramid line combines spool;
Step 2: elastic core wire is taken, and elastic core wire is placed into glue spreader and carries out gluing;
Step 3: the elastic core wire for being painted with glue is placed into coil winding machine as core wire, and combines yarn and aramid line Spool be placed into coil winding machine it is more outer wind line, then by coil winding machine by yarn and aramid line group zygonema around to elastic core wire On, form elastomeric yarn;
Step 4: elastomeric yarn being sent in dryer and is dried, and the elastomeric yarn that drying is completed utilizes winder Machine is wound in elastomeric yarn spool;
Step 5: elastomeric yarn is placed into plating glue machine, plating glue processing is carried out to the surface of elastomeric yarn, and then carried out It is dry;
Step 6: the dry elastomeric yarn completed is placed into vacuum splashing and plating machine, titanium germanium metal ion is sputtered to elasticity The surface of yarn, which is formed, has titanium germanium conductive yarn, and titanium germanium conductive yarn is wound in titanium germanium conductive yarn by bobbin-winding machine Spool.
Preferably, the elastic core wire is made of rubber material.
Preferably, the drying duration of the step 4 and step 5 is required in 10min-15min.
Preferably, need to reach 10E-4mbar vacuum degree in the vacuum splashing and plating machine.
Preferably, need to be passed through the argon gas that pressure is 10E-3 bar in the vacuum splashing and plating machine.
Compared with the relevant technologies, titanium germanium conductive yarn provided by the invention and preparation method thereof has following beneficial to effect Fruit:
The present invention provides a kind of titanium germanium conductive yarn and preparation method thereof, and by the setting of elastic core wire, titanium is effectively guaranteed The ductility of germanium conductive yarn more extends the scope of application of titanium germanium conductive yarn, avoids during use, and titanium germanium is led The case where electric yarn discovery fracture, and pass through the doubling of aramid fiber and yarn, effectively raise the durable of titanium germanium conductive yarn Performance, so that titanium germanium conductive yarn has superhigh intensity, high-modulus and high temperature resistant, acid-fast alkali-proof, light-weight, anti-aging, life The excellent performances such as period length.
Specific embodiment
Below with reference to embodiment, the invention will be further described.
A kind of titanium germanium conductive yarn, comprising: elastic core wire, yarn and aramid fiber, the yarn and the mutual doubling of the aramid fiber And it is wrapped in the surface of the elastic core wire, the outer surface sputter of the yarn and the aramid fiber has titanium germanium conductive layer.
A kind of production method of titanium germanium conductive yarn, comprising the following steps:
Step 1: doubling takes yarn and is wound in yarn spool by bobbin-winding machine, separately takes aramid line and is wound in by bobbin-winding machine Then yarn spool and aramid line spool are placed into doubling frame by aramid line spool, mutual doubling is at a strand, then again Yarn is wound in by bobbin-winding machine and aramid line combines spool;
Step 2: elastic core wire is taken, and elastic core wire is placed into glue spreader and carries out gluing;
Step 3: the elastic core wire for being painted with glue is placed into coil winding machine as core wire, and combines yarn and aramid line Spool be placed into coil winding machine it is more outer wind line, then by coil winding machine by yarn and aramid line group zygonema around to elastic core wire On, form elastomeric yarn;
Step 4: elastomeric yarn being sent in dryer and is dried, and the elastomeric yarn that drying is completed utilizes winder Machine is wound in elastomeric yarn spool;
Step 5: elastomeric yarn is placed into plating glue machine, plating glue processing is carried out to the surface of elastomeric yarn, and then carried out It is dry;
Step 6: the dry elastomeric yarn completed is placed into vacuum splashing and plating machine, titanium germanium metal ion is sputtered to elasticity The surface of yarn, which is formed, has titanium germanium conductive yarn, and titanium germanium conductive yarn is wound in titanium germanium conductive yarn by bobbin-winding machine Spool.
The elastic core wire is made of rubber material.
The drying duration of the step 4 and step 5 is required in 10min-15min.
Need to reach 10E-4mbar vacuum degree in the vacuum splashing and plating machine.
Need to be passed through the argon gas that pressure is 10E-3 bar in the vacuum splashing and plating machine.
Compared with the relevant technologies, titanium germanium conductive yarn provided by the invention and preparation method thereof has following beneficial to effect Fruit:
By the setting of elastic core wire, the ductility of titanium germanium conductive yarn is effectively guaranteed, more extends titanium germanium conductive yam The case where scope of application of line avoids during use, the discovery fracture of titanium germanium conductive yarn, and pass through aramid fiber and yarn Doubling, effectively raise the endurance quality of titanium germanium conductive yarn so that titanium germanium conductive yarn have superhigh intensity, high-modulus With the excellent performances such as high temperature resistant, acid-fast alkali-proof, light-weight, anti-aging, life cycle length.
The above description is only an embodiment of the present invention, is not intended to limit the scope of the invention, all to utilize this hair Equivalent structure or equivalent flow shift made by bright specification is applied directly or indirectly in other relevant technical fields, Similarly it is included within the scope of the present invention.

Claims (6)

1. a kind of titanium germanium conductive yarn characterized by comprising elastic core wire, yarn and aramid fiber, the yarn and the aramid fiber The outer surface sputter of mutual doubling and the surface for being wrapped in the elastic core wire, the yarn and the aramid fiber has titanium germanium conductive Layer.
2. a kind of production method of titanium germanium conductive yarn, which comprises the following steps:
Step 1: doubling takes yarn and is wound in yarn spool by bobbin-winding machine, separately takes aramid line and is wound in by bobbin-winding machine Then yarn spool and aramid line spool are placed into doubling frame by aramid line spool, mutual doubling is at a strand, then again Yarn is wound in by bobbin-winding machine and aramid line combines spool;
Step 2: elastic core wire is taken, and elastic core wire is placed into glue spreader and carries out gluing;
Step 3: the elastic core wire for being painted with glue is placed into coil winding machine as core wire, and combines yarn and aramid line Spool be placed into coil winding machine it is more outer wind line, then by coil winding machine by yarn and aramid line group zygonema around to elastic core wire On, form elastomeric yarn;
Step 4: elastomeric yarn being sent in dryer and is dried, and the elastomeric yarn that drying is completed utilizes winder Machine is wound in elastomeric yarn spool;
Step 5: elastomeric yarn is placed into plating glue machine, plating glue processing is carried out to the surface of elastomeric yarn, and then carried out It is dry;
Step 6: the dry elastomeric yarn completed is placed into vacuum splashing and plating machine, titanium germanium metal ion is sputtered to elasticity The surface of yarn, which is formed, has titanium germanium conductive yarn, and titanium germanium conductive yarn is wound in titanium germanium conductive yarn by bobbin-winding machine Spool.
3. titanium germanium conductive yarn according to claim 2, which is characterized in that the elastic core wire uses rubber material system At.
4. titanium germanium conductive yarn according to claim 2 and preparation method thereof, which is characterized in that the step 4 and step Five drying duration is required in 10min-15min.
5. titanium germanium conductive yarn according to claim 2 and preparation method thereof, which is characterized in that in the vacuum splashing and plating machine Need to reach 10E-4mbar vacuum degree.
6. titanium germanium conductive yarn according to claim 2 and preparation method thereof, which is characterized in that in the vacuum splashing and plating machine Need to be passed through the argon gas that pressure is 10E-3 bar.
CN201910777767.8A 2019-08-22 2019-08-22 A kind of titanium germanium conductive yarn and preparation method thereof Pending CN110528134A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111544159A (en) * 2020-06-12 2020-08-18 江苏邦士医疗科技有限公司 Weaving method of closed jointless O-shaped weaving loop ring

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CN107090640A (en) * 2017-05-11 2017-08-25 广州市爱因电子有限公司 The underwear that a kind of use conductive yarn makes
CN207483956U (en) * 2017-10-19 2018-06-12 江苏新芳科技集团股份有限公司 A kind of novel combined covering yarn
CN207512352U (en) * 2017-08-25 2018-06-19 苏州耐德新材料科技有限公司 A kind of composite material sewing thread of silk, yarn clad structure
CN207632947U (en) * 2016-12-08 2018-07-20 王武英 Fabric complex yarn
US20190169770A1 (en) * 2016-08-25 2019-06-06 Japan Matex Co., LTD Twisted yarn, opened yarn, carbon fiber-covered twisted yarn, and method for manufacturing these

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CN1924131A (en) * 2005-08-31 2007-03-07 库夫纳制衣有限公司 Electrically conductive, elastically stretchable hybrid yarn, method for manufacture thereof and textile product with a hybrid yarn of this kind
CN1818168A (en) * 2006-03-27 2006-08-16 陈成泗 High-strength yarn with polyvinyl coating and warp knitting cloth
CN201915191U (en) * 2010-12-23 2011-08-03 陈国平 Novel high-strength cutting-resistant coated yarn
CN202509192U (en) * 2012-01-13 2012-10-31 杭州翔盛高强纤维材料股份有限公司 Plied pre-twist type high strength anti-cutting wrapped yarn
CN202530225U (en) * 2012-03-22 2012-11-14 浙江国远纱线有限公司 Conductive fiber wrap yarn
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CN106757508A (en) * 2016-11-23 2017-05-31 浙江华峰氨纶股份有限公司 A kind of aramid fiber spandex core-skin composite fiber and preparation method thereof
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111544159A (en) * 2020-06-12 2020-08-18 江苏邦士医疗科技有限公司 Weaving method of closed jointless O-shaped weaving loop ring
CN111544159B (en) * 2020-06-12 2021-02-02 江苏邦士医疗科技有限公司 Weaving method of closed jointless O-shaped weaving loop ring

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Application publication date: 20191203