CN109594347A - A kind of aluminium system waterproof glossy canvas and preparation method thereof - Google Patents
A kind of aluminium system waterproof glossy canvas and preparation method thereof Download PDFInfo
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- CN109594347A CN109594347A CN201811523669.3A CN201811523669A CN109594347A CN 109594347 A CN109594347 A CN 109594347A CN 201811523669 A CN201811523669 A CN 201811523669A CN 109594347 A CN109594347 A CN 109594347A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0065—Organic pigments, e.g. dyes, brighteners
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/10—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with styrene-butadiene copolymerisation products or other synthetic rubbers or elastomers except polyurethanes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
- D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
- D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/08—Properties of the materials having optical properties
- D06N2209/0838—Bright, glossy, shiny surface
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/142—Hydrophobic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/148—Superabsorbing
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aluminium system waterproof glossy canvases and preparation method thereof, by oil painting cloth base material as base cloth layer；Back cover coating is coated on oil painting cloth base material；And carry out press polish processing；Then one layer of water-base resin prime coat layer is coated on back cover coating；One layer of aluminium system waterproof glossy ink-absorbed coated layer is finally further coated on prime coat layer.The aluminium system waterproof glossy ink-absorbed coated layer includes: nano aluminium oxide, adhesive, pH adjusting agent, silane coupling agent, defoaming agent, levelling agent, coalescing agent and crosslinking agent.The present invention is by adjusting the ratio of nano aluminium oxide and adhesive, addition coalescing agent, change crosslinking agent type and adjustment coating layer thickness etc. in aluminium system waterproof glossy ink-absorbed coated layer, aluminum current system waterproof glossy ink-absorbed coated layer is solved when being coated with application on canvas, it is easy to appear ink-absorbed coated layer fracture, prints the problems such as air brushing is ineffective, and chance water coating is destroyed.
Description
Technical field:
The invention belongs to color spray print media fields more particularly to a kind of aluminium system waterproof glossy canvas and preparation method thereof.
Technical background:
Canvas refers to that the infiltrations such as ink, solvent and water can be prevented by being coated with one or more layers on certain specific dry goods substrates
Back cover coating primer, for Freehandhand-drawing or as the dry goods of color spray print media.Using after numerial code spray drawing be used for advertisement and interior
The canvas of decoration is known as color spray inkjet printing canvas.With the development in world information epoch, inkjet printing technology is gradually big
Type, output are rapid, and color spray inkjet printing canvas has been largely used to Freehandhand-drawing picture, decoration painting, mountain ink and wash, oil painting product
It is imitated etc..Especially mountain ink and wash and oil painting product are copied, compared with the traditional oil painting art work, color spray ink-jet is beaten
The advantages of stamp-pad ink painting canvas is cheap, facilitates maintenance promotes market to the demand and development of the art work, domestic cultural product, right
The demand of color spray inkjet printing canvas obviously increases, for the printing effect and appearance glossiness of ink-jet canvas print media
Requirement it is also higher and higher.
Swelling type and pore type can be divided into suitable for the canvas of inkjet printing currently on the market.Swelling type ink-jet printing ink
Painting canvas, appearance glossiness is higher, mainly carries out blotting by the swelling principle of polyvinyl alcohol, is swollen speed by polyvinyl alcohol itself
It is slower that rate influences blotting speed.And polyvinyl alcohol meet the instant characteristic of water cause such bloom canvas product waterproof property compared with
Difference, in the case where current aqueous printer is widely applied, product limitation is obvious.And pore type inkjet printing canvas is main
It is to have rate of drying fast, the good feature of waterproof performance by coated filler gap blotting；Pore type inkjet printing canvas is again
Aluminium system and two kinds of silicon systems can be divided into, wherein silicon systems pore type inkjet printing canvas, matt appearance, need to add work in the later period
Sequence improves appearance glossiness, in the use of most of consumer brings inconvenience.And aluminium system pore type ink-jet printing ink
Painting canvas, appearance glossiness is high, does not need to add process in the later period to achieve the effect that bloom, waterproof, cost is relatively low, production process
Simply.But since oil painting cloth base material woven design sense itself is strongly clear, it is uneven between textile yarn and aluminium system waterproof glossy
The easy cracking behavior of coating itself causes aluminium system waterproof glossy coating to be coated with application on canvas, produces a kind of aluminium system waterproof
When bloom canvas, it is easy to appear ink-absorbed coated layer fracture, prints the problems such as air brushing effect is uneven.
Summary of the invention:
It is an object of that present invention to provide a kind of aluminium system waterproof glossy canvases and preparation method thereof, by adjusting aluminium system waterproof glossy
The ratio of nano aluminium oxide and adhesive, addition coalescing agent, change crosslinking agent type and adjustment blotting apply in ink-absorbed coated layer
The aspect of thickness degree solves aluminum current system waterproof glossy canvas and is easy to appear ink-absorbed coated layer fracture, and printing color is uneven, prevents
The deficiency of the technologies such as aqueous energy difference.
To achieve the above object and the technical solution adopted is as follows:
A kind of aluminium system waterproof glossy canvas, it is characterised in that use oil painting cloth base material as base cloth layer, in oil painting cloth base material
One layer of back cover coating of upper coating, and carry out press polish processing；Then one layer of water-base resin prime coat layer is coated on back cover coating；Most
One layer of aluminium system waterproof glossy ink-absorbed coated layer is further coated on prime coat layer afterwards.
The substrate layer be the blended base fabric of polyester-cotton blend (containing the amount of washing≤60%), cotton base fabric, chemical fabric, chemical fibre imitate cotton cloth,
The substrates such as flax, chemical fibre black-out cloth.
A kind of aluminium system waterproof glossy canvas, it is characterised in that the back cover coating is water-borne acrylic coatings
Coating or aqueous polyurethane coating coating, formula score by weight are calculated as: 80-100 parts of filler, 40-70 parts of adhesive, dispersing agent
0.5-1 parts, 1-2 parts of other auxiliary agents；The filler is talcum powder, lithopone, nano-titanium dioxide, precipitated calcium carbonate and kaolin
One or more, wherein nano-titanium dioxide average grain diameter 0.1-1 microns, 1-5 microns of precipitated calcium carbonate average grain diameter；It is described viscous
Mixture is the one or more of polyvinyl alcohol, acrylic resin, pure-acrylic emulsion and polyurethane resin；Other described auxiliary agents are defoaming
Agent, levelling agent etc..
The prime coat layer is water-borne Self-Crosslinked Acrylic resin or waterborne polyurethane resin.
A kind of aluminium system waterproof glossy canvas, it is characterised in that the aluminium system waterproof glossy ink-absorbed coated layer coating
Formula number is calculated as: 100 parts of nano aluminium oxide；15-25 parts of adhesive；0.5-1.0 parts of pH adjusting agent；Silane coupling agent
0.5-1.0 parts；10-20 parts of cosolvent；0.2-0.5 parts of levelling agent；5-15 parts of coalescing agent；0.5-1 parts of crosslinking agent；
The nano aluminium oxide, is boehmite type nano aluminium oxide, and chemical composition is AIOOH xH2O, partial size are received for 10-20
Rice；
The adhesive is the one or more of polyvinyl alcohol, styrene-butadiene latex, polyurethane and pure C latex；
The pH adjusting agent is the one or more of nitric acid, acetic acid and hydrochloric acid；
The cosolvent is isopropanol, n-butanol, dimethylformamide, propylene glycol monomethyl ether, dipropylene glycol methyl ether；
The levelling agent is the acrylic copolymer of fluorine richness；
The coalescing agent is polyethylene glycol (molecular weight 200-600), alcohol ester 12, hexylene glycol monobutyl ether acetate, 3- second
Oxygroup ethyl propionate is one or more of；
The crosslinking agent is the one or more of boric acid, borax, glyoxal, glutaraldehyde, epoxy resin and Lauxite.
A kind of preparation method of the aluminium system waterproof glossy canvas, comprising the following steps:
(1) preparation of back cover coating
The preparation of dispersion liquid: in the case of stirring, 80-100 parts of filler, 0.5-1 parts of dispersing agent being add to deionized water,
Mixing speed is slowly increased to 2300r/min or more, high speed shear disperses 60-90min, and the dispersion that solid content is 30-50% is made
Liquid, for use.
Prepared at material: under conditions of low whipping speed is 300-500r/min, slowly by 40-70 parts of adhesive, other help
1-2 parts of agent are added in above-mentioned dispersion liquid, stir 20-30min, and the filtering of 160 mesh defoams, for use.
(2) preparation of aluminium system waterproof glossy blotting coating
The preparation of dispersion liquid: in the case of stirring, 100 parts of nano aluminium oxide, 0.5-1.0 parts of pH adjusting agent and silane is even
Agent 0.5-1.0 parts of connection is add to deionized water, and is slowly increased mixing speed to 2300r/min or more, high speed dispersion 90min,
It is 20-30% that solid content, which is made, and pH is the dispersion liquid of 3-5, for use；
The curing of dispersion liquid: above-mentioned dispersion liquid being placed in 65 ± 5 DEG C of water bath, cures 12h, and holding dispersion liquid pH is 3-
Between 5, guarantee that silane coupling agent is fully hydrolyzed, for use；
It is prepared at material: under conditions of 50 ± 5 DEG C, the mixing speed of 300-500r/min, by 15-25 parts of adhesives, 10-20 parts
Cosolvent, 0.5-1.0 levelling agent, 5-15 parts of coalescing agents and 0.5-1 parts of crosslinking agent are slowly added to the dispersion liquid to curing
In, 20-30min is stirred, the filtering of 300 mesh defoams, for use.
(3) aluminium system waterproof glossy canvas applies etamine making process:
It is coated with back cover coating with needle plate scraper plate coating method, is dried through 120-150 DEG C of hot-air oven, is coated with 1-3 times, obtains 60-
180 grams per square meters of back cover coatings；
By calender, press polish is carried out with the pressure of 0.4MPa；
On back cover coating, one layer of water-borne Self-Crosslinked Acrylic resin or polyurethane resin bottoming are coated with using scraper coating method
Coating dries through 90-120 DEG C of hot-air oven, obtains 10-15 grams per square meters of prime coat layer；
On prime coat layer, it is coated with one layer of aluminium system waterproof glossy ink-absorbed coated layer using slope flow coating mode, through 90-105 DEG C of hot wind
Baking oven drying, obtains 30-40 grams per square meters of aluminium system waterproof glossy ink-absorbed coated layer, finally obtains a kind of aluminium system waterproof glossy canvas.
The present invention is by adjusting the ratio of nano aluminium oxide and adhesive, addition film forming in aluminium system waterproof glossy ink-absorbed coated layer
Auxiliary agent changes crosslinking agent type and adjustment coating layer thickness etc., solves aluminum current system waterproof glossy coating on canvas
Coating is in application, being easy cracking, printing the problems such as air brushing is ineffective, and chance water coating is destroyed.
Specific embodiment
The present invention is described in more detail combined with specific embodiments below
Specific embodiment 1
A kind of aluminium system waterproof glossy canvas, it is characterised in that use oil painting cloth base material as base cloth layer, in oil painting cloth base material
One layer of back cover coating of upper coating, and carry out press polish processing；Then one layer of water-base resin prime coat layer is coated on back cover coating；Most
One layer of aluminium system waterproof glossy ink-absorbed coated layer is further coated on prime coat layer afterwards.
The substrate layer is preferably the blended base fabric of polyester-cotton blend (containing the amount of washing≤60%), and yarn knits coefficient: 16+16 × 10, grammes per square metre
200g。
The back cover coating is water-borne acrylic coatings coating or aqueous polyurethane coating coating, formula score by weight
It is calculated as: 80 parts of filler, 55 parts of adhesive, 0.5 part of dispersing agent, 2 parts of other auxiliary agents；The filler is talcum powder, lithopone, nanometer
Titanium dioxide, precipitated calcium carbonate and kaolin are one or more of, and wherein nano-titanium dioxide average grain diameter 0.1-1 microns, lightweight
1-5 microns of calcium carbonate average grain diameter；Described adhesive is polyvinyl alcohol, acrylic resin, pure-acrylic emulsion and polyurethane resin
It is one or more of；Other described auxiliary agents are defoaming agent, levelling agent etc..
The prime coat layer is water-borne Self-Crosslinked Acrylic resin glue or waterborne polyurethane resin glue.
The aluminium system waterproof glossy ink-absorbed coated layer formulation for coating material is calculated by weight as: 100 parts of nano aluminium oxide；Adhesive
15 parts；0.5 part of pH adjusting agent；0.5 part of silane coupling agent；15 parts of cosolvent；0.2 part of levelling agent；5 parts of coalescing agent；Crosslinking agent
0.5 part；
The nano aluminium oxide, is boehmite type nano aluminium oxide, and chemical composition is AIOOH xH2O, partial size are received for 10-20
Rice；
The adhesive is preferably polyvinyl alcohol, the degree of polymerization >=2500, alcoholysis degree 88%；
The pH adjusting agent is preferably the aqueous solution of nitric acid that effective content is 10%；
The cosolvent is preferably isopropanol, dimethylformamide；
The levelling agent is preferably the acrylic copolymer of fluorine richness；
The plasticizer is preferably alcohol ester 12；
The crosslinking agent is preferably boric acid, borax.
A kind of preparation method of aluminium system waterproof glossy canvas as mentioned, comprising the following steps:
(1) preparation of back cover coating
The preparation of dispersion liquid: in the case of stirring, 80 parts of filler, 0.5 part of dispersing agent being add to deionized water, and slowly increased
Add mixing speed to 2300r/min or more, high speed shear disperses 60-90min, the dispersion liquid that solid content is 30-50% is made, to
With；
It prepares at material: under conditions of low whipping speed is 300-500r/min, slowly adding 55 parts of adhesive, 2 parts of other auxiliary agents
Enter into above-mentioned dispersion liquid, stir 20-30min, the filtering of 160 mesh defoams, for use.
(2) preparation of aluminium system waterproof glossy blotting coating
The preparation of dispersion liquid: in the case of stirring, by 0.5 part and 0.5 part 100 parts of nano aluminium oxide, pH adjusting agent silane
Coupling agent KH-560 is add to deionized water, and is slowly increased mixing speed to 2300r/min or more, high speed dispersion 90min, system
It is 20-30% at solid content, pH is the dispersion liquid of 3-5, for use；
The curing of dispersion liquid: above-mentioned dispersion liquid being placed in 65 ± 5 DEG C of water bath, cures 12h, and holding dispersion liquid pH is 3-
Between 5, guarantee that silane coupling agent KH-560 is fully hydrolyzed, for use；
It is prepared at material: under conditions of 50 ± 5 DEG C, the mixing speed of 300-500r/min, by 15 parts of adhesives, 15 parts of hydrotropies
Agent, 0.2 part of levelling agent, 5 parts of coalescing agent alcohol esters 12 and 0.5 part crosslinking agent borax, boric acid mixed aqueous solution be slowly added to
In dispersion liquid after to curing, 20-30min is stirred, the filtering of 300 mesh defoams, for use.
(3) aluminium system waterproof glossy canvas applies etamine making process:
In base fabric, it is coated with back cover coating with needle plate scraper plate coating method, is dried through 120-150 DEG C of hot-air oven, is coated with 3 times,
Obtain 180 grams per square meters of back cover coatings；
On back cover coating, one layer of water-borne Self-Crosslinked Acrylic resin or polyurethane resin bottoming are coated with using scraper coating method
Coating dries through 90-120 DEG C of hot-air oven, obtains 10 grams per square meters of prime coat layers；
On prime coat layer, it is coated with one layer of aluminium system aqueous ink sorptive coating using slope flow coating mode, through 90-105 DEG C of hot-air oven
Drying, obtains 30 grams per square meters of aluminium system waterproof glossy ink-absorbed coated layers, finally obtains a kind of aluminium system waterproof glossy canvas.
1 comparative example 1 of embodiment
This comparative example with embodiment 1, institute the difference is that: by aluminium system waterproof glossy ink-absorbed coated layer formulation for coating material, adhesive
Number is improved to 25 parts.
1 comparative example 2 of embodiment
This comparative example with embodiment 1, institute the difference is that: by aluminium system waterproof glossy ink-absorbed coated layer formulation for coating material, film forming is helped
Agent is improved to 15 parts.
1 comparative example 3 of embodiment
This comparative example with embodiment 1, institute the difference is that: by aluminium system waterproof glossy ink-absorbed coated layer formulation for coating material, crosslinking agent
It improves to 1 part.
Specific embodiment 2
The substrate layer is preferably chemical fabric base fabric.
The back cover coating is the same as embodiment 1.
The prime coat layer is the same as embodiment 1.
The aluminium system waterproof glossy ink-absorbed coated layer formulation for coating material is calculated by weight as: 100 parts of nano aluminium oxide；Adhesive
20 parts；0.5 part of pH adjusting agent；0.5 part of silane coupling agent；15 parts of cosolvent；0.5 part of levelling agent；5 parts of coalescing agent；Crosslinking agent
0.7 part；
The coalescing agent is preferably hexylene glycol monobutyl ether acetate；
The crosslinking agent is preferably epoxy resin.
A kind of preparation method of aluminium system waterproof glossy canvas, comprising the following steps:
(1) preparation of back cover coating is the same as 1 step of embodiment (1)
(2) preparation of aluminium system waterproof glossy blotting coating
The preparation of dispersion liquid is the same as embodiment 1
The curing of dispersion liquid is the same as embodiment 1
It is prepared at material: under conditions of 50 ± 5 DEG C, the mixing speed of 300-500r/min, by 20 parts of adhesives, 15 parts of hydrotropies
Agent, 0.5 part of levelling agent, 5 parts of coalescing agent hexylene glycol monobutyl ether acetates and 0.7 part of crosslinking agent epoxy resin are slowly added to ripe
In dispersion liquid after change, 20-30min is stirred, the filtering of 300 mesh defoams, for use；
(3) aluminium system waterproof glossy canvas apply etamine making process and 1 step of embodiment (3) the difference is that: wherein back cover applies
Layer is dried through 120-150 DEG C of hot-air oven, is coated with 2 times, is obtained 120 grams of back cover coating/square meters.
2 comparative example 1 of embodiment
This comparative example with embodiment 2, institute the difference is that: by aluminium system waterproof glossy ink-absorbed coated layer coating weight control be 35 grams/
Square meter.
2 comparative example 2 of embodiment
This comparative example with embodiment 2, institute the difference is that: by aluminium system waterproof glossy ink-absorbed coated layer coating weight control be 40 grams/
Square meter.
Performance parameter test:
| Coating grammes per square metre g/m2 | Ink-absorbed coated layer crack conditions | Print drying time | |
| Conventional aluminium system bloom canvas | 30 | It is easy to appear fracture | 10-15s |
| Conventional aluminium system bloom canvas | 40 | It is easy to appear fracture | 8-10s |
| Embodiment 1 | 30 | It is not broken | 3-4s |
| 1 comparative example 1 of embodiment | 30 | It is not broken | 5-6s |
| 1 comparative example 2 of embodiment | 30 | It is not broken | 5-6s |
| 1 comparative example 3 of embodiment | 30 | It is not broken | 3-4s |
| Embodiment 2 | 30 | It is not broken | 5-6s |
| 2 comparative example 1 of embodiment | 35 | It is not broken | 3-4s |
| 2 comparative example 2 of embodiment | 40 | It is not broken | 1-2s |
Claims (6)
1. a kind of aluminium system waterproof glossy canvas, it is characterised in that use oil painting cloth base material as base cloth layer, in canvas base
It is coated with back cover coating on material, and carries out press polish processing；Then one layer of water-base resin prime coat layer is coated on back cover coating；Finally
One layer of aluminium system waterproof glossy ink-absorbed coated layer is further coated on prime coat layer.
2. a kind of aluminium system waterproof glossy canvas according to claim 1, it is characterised in that the base cloth layer is polyester-cotton blend
Blended base fabric (containing the amount of washing≤60%), cotton base fabric, chemical fabric, chemical fibre imitate the substrates such as cotton cloth, flax, chemical fibre black-out cloth.
3. a kind of aluminium system waterproof glossy canvas according to claim 1, it is characterised in that the back cover coating is water
Property acrylic coating coating or aqueous polyurethane coating coating, formula score by weight is calculated as: 80-100 parts of filler, adhesive
40-70 parts, 0.5-1 parts of dispersing agent, 1-2 parts of other auxiliary agents；The filler is talcum powder, lithopone, nano-titanium dioxide, lightweight
Calcium carbonate and kaolin are one or more of, and wherein nano-titanium dioxide average grain diameter 0.1-1 microns, precipitated calcium carbonate average grain diameter
1-5 microns；Described adhesive is the one or more of polyvinyl alcohol, acrylic resin, pure-acrylic emulsion and polyurethane resin；It is described
Other auxiliary agents are defoaming agent, levelling agent etc..
4. a kind of aluminium system waterproof glossy canvas according to claim 1, it is characterised in that the aluminium system waterproof glossy
Ink-absorbed coated layer formulation for coating material is calculated by weight as: 100 parts of nano aluminium oxide；15-25 parts of adhesive；PH adjusting agent 0.5-1.0
Part；0.5-1.0 parts of silane coupling agent；10-20 parts of cosolvent；0.2-0.5 parts of levelling agent；5-15 parts of coalescing agent；Crosslinking agent
0.5-1 parts；
The nano aluminium oxide, is boehmite type nano aluminium oxide, and chemical composition is AIOOH xH2O, partial size are received for 10-20
Rice；
The adhesive is the one or more of polyvinyl alcohol, styrene-butadiene latex, polyurethane and pure C latex；
The pH adjusting agent is the one or more of nitric acid, acetic acid and hydrochloric acid；
The cosolvent is isopropanol, n-butanol, dimethylformamide, propylene glycol monomethyl ether, dipropylene glycol methyl ether；
The levelling agent is the acrylic copolymer of fluorine richness；
The coalescing agent is polyethylene glycol (molecular weight 200-600), alcohol ester 12, hexylene glycol monobutyl ether acetate, 3- second
Oxygroup ethyl propionate is one or more of；
The crosslinking agent is the one or more of boric acid, borax, glyoxal, glutaraldehyde, epoxy resin and Lauxite.
5. a kind of aluminium system waterproof glossy canvas according to claim 1, it is characterised in that the aluminium system waterproof glossy
The pH value of blotting coating is 4-5, solid content 15-20%.
6. the preparation method of aluminium system waterproof glossy canvas described in -6 any one according to claim 1, it is characterised in that: packet
Include following steps:
(1) preparation of back cover coating
The preparation of dispersion liquid: in the case of stirring, 80-100 parts of filler, 0.5-1 parts of dispersing agent being add to deionized water,
Mixing speed is slowly increased to 2300r/min or more, high speed shear disperses 60-90min, and the dispersion that solid content is 30-50% is made
Liquid, for use；
It is prepared at material: under conditions of low whipping speed is 300-500r/min, slowly by 40-70 parts of adhesive, other auxiliary agents 1-2
Part is added in above-mentioned dispersion liquid, stirs 20-30min, and the filtering of 160 mesh defoams, for use；
(2) preparation of aluminium system waterproof glossy blotting coating
The preparation of dispersion liquid: in the case of stirring, 100 parts of nano aluminium oxide, 0.5-1.0 parts of pH adjusting agent and silane is even
Agent 0.5-1.0 parts of connection is add to deionized water, and is slowly increased mixing speed and is made to 2300r/min, high speed dispersion 90min
Solid content is 20-30%, and pH is the dispersion liquid of 3-5, for use；
The curing of dispersion liquid: above-mentioned dispersion liquid being placed in 65 ± 5 DEG C of water bath, cures 12h, and holding dispersion liquid pH is 3-
Between 5, guarantee that silane coupling agent is fully hydrolyzed, for use；
It is prepared at material: under conditions of 50 ± 5 DEG C, the mixing speed of 300-500r/min, by 15-25 parts of adhesives, 10-20 parts
Cosolvent, 0.5-1.0 levelling agent, 5-15 parts of coalescing agents and 0.5-1 parts of crosslinking agent are slowly added in the dispersion liquid after curing,
20-30min is stirred, the filtering of 300 mesh defoams, for use；
(3) aluminium system waterproof glossy canvas applies etamine making process:
In base fabric, it is coated with back cover coating with needle plate scraper plate coating method, is dried through 120-150 DEG C of hot-air oven, 1-3 is coated with
It is secondary, obtain 60-180 grams per square meters of back cover coating；
By calender, press polish is carried out with the pressure of 0.4MPa；
On back cover coating, one layer of water-borne Self-Crosslinked Acrylic resin or polyurethane resin bottoming are coated with using scraper coating method
Coating dries through 90-120 DEG C of hot-air oven, obtains 10-15 grams per square meters of prime coat layer；
On prime coat layer, it is coated with one layer of aluminium system waterproof glossy ink-absorbed coated layer using slope flow coating mode, through 90-105 DEG C of hot wind
Baking oven drying, obtains 30-40 grams per square meters of aluminium system waterproof glossy ink-absorbed coated layer.
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| CN111041891A (en) * | 2019-12-30 | 2020-04-21 | 广东高璐美数码科技有限公司 | Waterproof highlight color-spray coating and preparation method thereof |
| CN113265884A (en) * | 2021-05-19 | 2021-08-17 | 江苏浙创纺织科技有限公司 | High-gloss waterproof chemical fiber photo spray painting canvas |
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