CN106608775B - A kind of cleaning heat production gas generating agent - Google Patents
A kind of cleaning heat production gas generating agent Download PDFInfo
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- CN106608775B CN106608775B CN201510682388.2A CN201510682388A CN106608775B CN 106608775 B CN106608775 B CN 106608775B CN 201510682388 A CN201510682388 A CN 201510682388A CN 106608775 B CN106608775 B CN 106608775B
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- heat production
- generating agent
- gas generating
- production gas
- cleaning heat
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- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/28—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
A kind of cleaning heat production gas generating agent, including fuel: 30% ~ 50%, oxidant: 50% ~ 70%, catalyst: 0 ~ 2%, process auxiliaries: 0 ~ 2%.Wherein fuel is guanidine nitrate, and oxidant is ammonium nitrate or modified ammonium nitrate, and catalyst is one kind or combination of copper oxide or copper chromite or potassium hyperchlorate, and process auxiliaries are one kind or combination of kaolin or clay or silicon nitride.The present invention has high safety, and extremely difficult generation chemically reacts under normal pressure, can be caused by electric signal under high pressure, has many advantages, such as that safety and stability, heat production are high, factor of created gase is high, gas ingredients cleaning, residue is few and nontoxic, cost performance is high.
Description
Technical field
The present invention relates to fever and gas exhausted material fields, in particular it relates to which a kind of carbon dioxide that is suitable for is exploited
The clean and effective heat production gas generating agent and its manufacturing method of device heater.
Background technique
Carbon dioxide exploitation device is metal tube, the heater that can repeat to fill liquid carbon dioxide by a high intensity
The composition such as (heat generating device), filling body and level pressure Guo Neng mechanism.Exploitation device is placed in coal body drilling, is started using exploder
Heater heats pressurization for internal liquid CO 2, and pressure persistently increases compressing level pressure Guo Neng mechanism in pipeline, makes wherein
Level pressure let out can piece rupture, release volume expand 600 times, pressure be more than hundred megapascal carbon dioxide gas, progress explosion fall
Coal.The blasting method effectively prevents causing gas combustion or explosion accident due to generating open fire because blowing out, and is particularly suitable for high watt
The mine coal blasting of this and coal and gas prominent, is conducive to Safety of Coal Mine Production.
The proof test of Huaibei Coal Mines in 2007 and cardox company cooperation development carbon dioxide exploitation device, exploits device table
Good Security and demolition effect are revealed.But it is disposable production that carbon dioxide, which exploits heater (heat generating device) in device,
Product, rely primarily on import, and higher cost limits it and popularizes in an all-round way and apply in coal mine.The domestic heat generating device of developing low-cost,
Reducing use cost seems especially urgent.
Summary of the invention
Technology of the invention solves the problems, such as it is to overcome the deficiencies of the prior art and provide that a kind of safety and stability, heat production is high, produces
Gas rate is high, gas ingredients clean, the cleaning heat production gas generating agent that residue is few and nontoxic, cost performance is high, is suitable for carbon dioxide
It exploits device heater (heat generating device).
The present invention also provides the manufacturing methods of above-mentioned cleaning heat production gas generating agent.
The present invention also provides the application methods of above-mentioned cleaning heat production gas generating agent.
The technical solution of the invention is as follows: a kind of clean and effective heat production gas generating agent, it is characterised in that including following quality
Percentage component:
Fuel: 30% ~ 50%,
Oxidant: 50% ~ 70%,
Catalyst: 0 ~ 2%,
Process auxiliaries: 0 ~ 2%.
Optimization formula of the invention are as follows:
Fuel: 30% ~ 45%,
Oxidant: 55% ~ 70%,
Catalyst: 0 ~ 2%,
Process auxiliaries: 0 ~ 1.5%.
The fuel is guanidine nitrate.
The oxidant is ammonium nitrate or modified ammonium nitrate.
The catalyst is one kind or combination of copper oxide or copper chromite or potassium hyperchlorate.
The process auxiliaries are one kind or combination of kaolin or clay or silicon nitride.
Invention also provides the manufacturing methods of above-mentioned cleaning heat production gas generating agent, including the following steps:
(1) material after sieving, drying is added to the mixer after weighing proportionally, such as V-Mixer, multidirectional fortune
Dynamic mixing machine, stereo mixing machines etc..
(2) 20 mesh ~ 80 mesh standard sieves will be crossed by mixed powder, according to the requirement to the medicament difference starting time, medicine
Powder uses after directly loading the tablet for using or being pressed into different-thickness and diameter.
A kind of application method of cleaning heat production gas generating agent of the invention is that directly pulverulent mixture is pressed into paper tube to make
With or be fitted into paper tube and use after being granulated.
The advantages of the present invention over the prior art are that:
(1) of the invention compared with now commonly using alkali type nantokite and perchlorate etc., have factor of created gase is higher, aerogenic composition more
The advantages that after clean, burning without residue, it is more suitable for the semiclosed environment of person works.
(2) metallic compound that there is catalytic action to ammonium nitrate is added in the present invention, adjustable heat production gas generating agent
Ignition performance and burn rate.In liquid CO 2 High Voltage atmosphere, the addition of a small amount of catalyst can regulate and control in very wide range
The reaction speed of heat production gas generating agent.Compared with existing general invention, metallic compound dosage is minimized.
(3) copper oxide and copper chromite being added in the present invention are not involved in reaction, and burning front and back does not change, do not influence
Gas component；Potassium hyperchlorate also acts as the effect of oxidant in addition to as catalyst, is changed into after burning corrosion-free, easy cleaning
KCl has no adverse effect to aerogenic composition.
(4) kaolin for being not involved in reaction or clay or silicon nitride being added in the present invention, can increase the self-adhesion of medicinal powder
Property, so that medicament is easy to compression molding.Especially the use of silicon nitride can make coat tablets bright and clean, prevent tablet from clinging tablet press machine mould
Tool improves demolding performace.
(5) heat production gas generating agent of the present invention, according to the requirement of use environment and starting speed, uniformly mixed medicinal powder and compacting
Molding tablet may be used to heat-producing unit, adaptable, application form multiplicity.
In short, providing the cleaning heat production gas generating agent and manufacturing process for carbon dioxide exploitation device heat-producing unit, manufacture
Clean and effective heat production gas generating agent out has high safety, and extremely difficult generation chemically reacts under normal pressure, can pass through electricity under high pressure
Signal causes；Safety and stability, heat production is high, factor of created gase is high, gas ingredients cleaning, that residue is few and nontoxic, cost performance is high etc. is excellent
Point.For the present invention using guanidine nitrate as fuel, ammonium nitrate ensures combustion gas, the high production for producing gas heat production agent cleaning as oxidant
Heat and factor of created gase, high thermal stability and safety, medicament is difficult to light under normal pressure, but again can vigorous combustion under high pressure.Metal
The addition of compound improves ignition performance, shortens ignition delay time, thus, guarantee the effective work for producing gas heat production agent.
The security performance height of gas heat production agent and easy to form is produced based on the present invention, it can be loaded with powder-form and be used, may be made as
Sizes tablet, medicine ball carry out filling use, have widened the use scope of medicament.
Specific embodiment
Following embodiments are the implementation results being formulated in order to better illustrate the present invention with technique, but the present invention is not limited only to
Embodiment.Proportion is mass percent below.
Embodiment 1
42.6% guanidine nitrate, 1% silicon nitride and 56.4% ammonium nitrate are added sequentially in Mixers with Multi-direction Movement,
Mixing 0.5 hour crosses and sifts out material, obtains the consistent medicinal powder that is uniformly dispersed.Medicinal powder directly or on tablet press machine is packed into after tabletting
Internal diameter is in the paper tube of Ф 12mm ~ Ф 20mm, and installing igniter, plug and copper packing etc. additional can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 39.3%；H2O, 44.2%；CO2, 15.4%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
Yu Shiwan/bis-.
Embodiment 2
By 42.1% guanidine nitrate, 1% clay, 55.9% ammonium nitrate and 1% copper oxide, be added sequentially to Multidirectional motion
It in mixing machine, mixes 0.5 hour, crosses and sift out material, obtain the consistent medicinal powder that is uniformly dispersed.Medicinal powder directly or on tablet press machine is pressed
It is in Ф 12mm ~ Ф 20mm paper tube that internal diameter is fitted into after piece, and installing igniter, plug and copper packing etc. additional can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 38.9%；H2O, 43.8%；CO2, 15.2%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
In ten a ten thousandths.
Embodiment 3
By 43.1% guanidine nitrate, 1% kaolin, 54.9% ammonium nitrate and 1% potassium hyperchlorate, be added sequentially to multidirectional
It in movement mixer, mixes 0.5 hour, crosses and sift out material, obtain the consistent medicinal powder that is uniformly dispersed.By medicinal powder directly or tablet press machine
It is in Ф 12mm ~ Ф 20mm paper tube that internal diameter is fitted into after upper tabletting, and installing igniter, plug and copper packing etc. additional can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 39.0%；H2O, 43.8%；CO2, 15.5%；No pernicious gas CO is generated, and HCl and nitrogen oxides contain
Amount is total to be lower than 4/100000ths.
Embodiment 4
By 41.3% guanidine nitrate, 1% clay and 57.7% modified ammonium nitrate (5%Ni2O3It is modified), it is added sequentially to more
It into movement mixer, mixes 0.5 hour, crosses and sift out material, obtain the consistent medicinal powder that is uniformly dispersed.By medicinal powder directly or tabletting
Being fitted into internal diameter on machine after tabletting is in Ф 12mm ~ Ф 20mm paper tube, and installing igniter, plug and copper packing etc. additional can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 38.1%；H2O, 43.0%；CO2, 14.9%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
In ten a ten thousandths.
Embodiment 5
By 40.9% guanidine nitrate, 0.5% clay, 0.5% silicon nitride, 57.1% modified ammonium nitrate (5% Ni2O3Change
Property) and 1% copper chromite, be added sequentially in Mixers with Multi-direction Movement, mix 0.5 hour, cross sift out material, dispersed
Uniform medicinal powder.Medicinal powder is fitted into internal diameter in Ф 12mm ~ Ф 20mm paper tube directly or on tablet press machine after tabletting, attachment point
Firearm, plug and copper packing etc. can be applied.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 37.8%；H2O, 42.5%；CO2, 14.7%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
In ten a ten thousandths.
Embodiment 6
By 40% guanidine nitrate, 0.5% kaolin, 0.5% silicon nitride and 59% modified ammonium nitrate (10% Ni2O3Change
Property), it is added sequentially in Mixers with Multi-direction Movement, mixes 0.5 hour, cross and sift out material, obtain the consistent medicinal powder that is uniformly dispersed.
Medicinal powder directly or on tablet press machine is fitted into internal diameter after tabletting to install igniter, plug and copper packing additional in Ф 12mm ~ Ф 20mm paper tube
Etc. can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 37.0%；H2O, 41.6%；CO2, 14.4%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
In ten a ten thousandths.
Embodiment 7
By 39.6% guanidine nitrate, 1% silicon nitride, 58.4% modified ammonium nitrate (10%Ni2O3It is modified) and 1% oxidation
Copper is added sequentially in Mixers with Multi-direction Movement, is mixed 0.5 hour, is crossed and is sifted out material, and the consistent medicinal powder that is uniformly dispersed is obtained.
Medicinal powder directly or on tablet press machine is fitted into internal diameter after tabletting to install igniter, plug and copper packing additional in Ф 12mm ~ Ф 20mm paper tube
Etc. can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 36.6%；H2O, 41.2%；CO2, 14.3%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
In ten a ten thousandths.
Embodiment 8
It is added sequentially to 43% guanidine nitrate and 57% ammonium nitrate in Mixers with Multi-direction Movement, mixes 0.5 hour, mistake
Material is sifted out, the consistent medicinal powder that is uniformly dispersed is obtained.Medicinal powder directly or on tablet press machine is packed into internal diameter after tabletting as Ф 12mm ~ Ф
In the paper tube of 20mm, installing igniter, plug and copper packing etc. additional can be applied.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 39.7%；H2O, 44.6%；CO2, 15.2%；No pernicious gas CO is generated, and amount of nitrogen oxides is low
Yu Shiwan/bis-.
Embodiment 9
By 40% guanidine nitrate, 59% modified ammonium nitrate (10%Ni2O3It is modified) and 1% copper oxide, be added sequentially to multidirectional
It in movement mixer, mixes 0.5 hour, crosses and sift out material, obtain the consistent medicinal powder that is uniformly dispersed.By medicinal powder directly or tablet press machine
It is in Ф 12mm ~ Ф 20mm paper tube that internal diameter is fitted into after upper tabletting, and installing igniter, plug and copper packing etc. additional can apply.
Initial pressure set is 10MPa, and burst pressure is set as 270MPa, and generation predominant gas is after calculating medicament reaction
(compared to former pharmacy quality): N2, 37%；H2O, 41.6%；CO2, 14.4%；No pernicious gas CO is generated, and amount of nitrogen oxides is lower than
Ten a ten thousandths.
The present invention can be used for but be used not only for carbon dioxide exploitation device heat-producing unit, and unspecified part belongs to this field
Technical staff's common knowledge.
Claims (6)
1. a kind of cleaning heat production gas generating agent for carbon dioxide exploitation device heater, it is characterised in that including following quality percentage
Than component:
Fuel: 30% ~ 50%；
Oxidant: 50% ~ 70%；
Catalyst: 0 ~ 2%, endpoint value is not zero；
Process auxiliaries: 0 ~ 2%, endpoint value is not zero；
The fuel is guanidine nitrate；
The oxidant is ammonium nitrate or modified ammonium nitrate；
The catalyst is one of copper chromite, potassium hyperchlorate or combination.
2. cleaning heat production gas generating agent according to claim 1, it is characterised in that: component of the invention are as follows:
Fuel: 30% ~ 45%；
Oxidant: 55% ~ 70%；
Catalyst: 0 ~ 2%, endpoint value is not zero；
Process auxiliaries: 0 ~ 1.5%, endpoint value is not zero.
3. cleaning heat production gas generating agent according to claim 1 or 2, it is characterised in that: the process auxiliaries are clay, nitridation
One of silicon or combination.
4. cleaning heat production gas generating agent according to claim 1 or 2, it is characterised in that: the process auxiliaries are kaolin, nitrogen
One of SiClx or combination.
5. a kind of manufacturing method of cleaning heat production gas generating agent of any of claims 1 or 2, it is characterised in that: include the following steps:
(1) material after sieving, drying is added to the mixer after weighing proportionally；
(2) 20 mesh ~ 80 mesh standard sieves will be crossed by mixed powder, according to the requirement to the medicament difference starting time, medicinal powder is straight
Tipping uses after filling out the tablet for using or being pressed into different-thickness and diameter.
6. a kind of application method of cleaning heat production gas generating agent of any of claims 1 or 2, it is characterised in that: for directly by powdery
Mixture is pressed into paper tube to use or be fitted into paper tube after being granulated and use.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510682388.2A CN106608775B (en) | 2015-10-21 | 2015-10-21 | A kind of cleaning heat production gas generating agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510682388.2A CN106608775B (en) | 2015-10-21 | 2015-10-21 | A kind of cleaning heat production gas generating agent |
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| CN106608775A CN106608775A (en) | 2017-05-03 |
| CN106608775B true CN106608775B (en) | 2019-06-04 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107760282A (en) * | 2017-07-19 | 2018-03-06 | 贵州盛卓科科技有限公司 | Liquid carbon dioxide fracturing device heating agent |
| CN114539011B (en) * | 2022-02-21 | 2023-03-28 | 张延松 | Safe and efficient high-energy expanding agent and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5545272A (en) * | 1995-03-03 | 1996-08-13 | Olin Corporation | Thermally stable gas generating composition |
| CN1236767A (en) * | 1998-04-15 | 1999-12-01 | 大赛璐化学工业株式会社 | Gas generating composition for air bag |
| CN1544271A (en) * | 2003-11-13 | 2004-11-10 | 西安北方庆华电器（集团）有限责任公 | Gas generating powder used for gas generator of automobile safety airbag and preparation method thereof |
| CN1644574A (en) * | 2004-12-16 | 2005-07-27 | 中国航天科技集团公司第四研究院第四十二研究所 | Non-nitrine gas generating agent and production thereof |
| CN102666439A (en) * | 2009-11-27 | 2012-09-12 | 国立大学法人东京大学 | Gas-generating agent composition |
-
2015
- 2015-10-21 CN CN201510682388.2A patent/CN106608775B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5545272A (en) * | 1995-03-03 | 1996-08-13 | Olin Corporation | Thermally stable gas generating composition |
| CN1236767A (en) * | 1998-04-15 | 1999-12-01 | 大赛璐化学工业株式会社 | Gas generating composition for air bag |
| CN1544271A (en) * | 2003-11-13 | 2004-11-10 | 西安北方庆华电器（集团）有限责任公 | Gas generating powder used for gas generator of automobile safety airbag and preparation method thereof |
| CN1644574A (en) * | 2004-12-16 | 2005-07-27 | 中国航天科技集团公司第四研究院第四十二研究所 | Non-nitrine gas generating agent and production thereof |
| CN102666439A (en) * | 2009-11-27 | 2012-09-12 | 国立大学法人东京大学 | Gas-generating agent composition |
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