CN106400584A - Use of magnetic ink in paper - Google Patents
Use of magnetic ink in paper Download PDFInfo
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- CN106400584A CN106400584A CN201610848919.5A CN201610848919A CN106400584A CN 106400584 A CN106400584 A CN 106400584A CN 201610848919 A CN201610848919 A CN 201610848919A CN 106400584 A CN106400584 A CN 106400584A
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- magnetic ink
- ink
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/22—Addition to the formed paper
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention provides a use of magnetic ink in paper. The magnetic ink is directionally arranged through a magnetic orientation printing plate to form stereoscopic patterns. The magnetic ink comprises paramagnetic ink or diamagnetic ink. The paramagnetic ink or diamagnetic ink comprises, by weight, 10-95 parts of a film-forming substance, 1-25 parts of a ferromagnetic material or diamagnetic substance-containing pigment capable of being directionally aligned in a magnetic field, 1-10 parts of auxiliaries and 0-88 parts of a solvent. The ferromagnetic material or diamagnetic substance-containing pigment capable of being directionally aligned in a magnetic field utilizes a light reflective pigment as a base material, and the ferromagnetic material or the diamagnetic substance is adhered to the base material.
Description
Technical field
The present invention relates to a kind of application in paper for magnetic ink.
Background technology
Three to fourth century of Christian era, paper substantially instead of silks, letter and become the unique writing material of China, effectively promote
The propagation of Jin Liao China science and culture and development.In the early Medieval China period in three to sixth century of Christian era, China's papermaking technology is constantly removed from office
Newly.In terms of raw material, in addition to original fiber crops, paper mulberry, expand to Cortex Mori, rattan peel papermaking again.In processing and manufacturing technology, strengthen
Alkali liquor steaming and decocting and pounding is smash, and improves the quality of paper, occurs in that the processing paper such as coloured paper, coating paper, loaded sheet.At present due to magnetic oil
The appearance of ink, adds paramagnet brown iron oxide so that the development again step in the flue forward of papery technology, such as in ink
Abroad have and magnetic ink is used in RMB, carries magnetic paper-bill, bankbook and identity card etc., but these magnetic oils
Only being embodied on record using function of ink, less to the appearance effects of papery.
Content of the invention
The technical problem to be solved in the present invention is a kind of application in paper for the magnetic ink providing.
Application in paper for the magnetic ink that the present invention provides, described magnetic ink combines magnetic orientation forme orientation row
Row, form space pattern, and described magnetic ink includes paramagnetism ink or diamagnetism ink, described paramagnetism ink or diamagnetism
Ink includes following components by weight：
10 95 parts of film forming matters, the pigment containing ferromagnetic material or diamagnetic material that can align in magnetic field
1 25 parts and auxiliary agent 1-10 part and solvent 0-88 part；
Wherein, in magnetic field can oriented alignment the pigment containing ferromagnetic material or containing diamagnetic material pigment with reflective
Class pigment is base material, and described base material is attached with ferromagnetic material or diamagnetic material.
Further improve as the present invention：Described film forming matter includes resin, oils and fatss, rubber, inorganic macromolecule material,
Described resin is the mixture selected from one or more of epoxy resin, polyurethane, acrylic acid and celluosic resin.
Further improve as the present invention：Described ferromagnetic material is brown iron oxide.
Further improve as the present invention：Described diamagnetic material is nanometer diamagnetism metal, described nanometer diamagnetism
Metal is prepared by Stober Hydrolyze method.
Further improve as the present invention：In described Stober Hydrolyze method, the mass fraction of ammonia is 10-35%.
Further improve as the present invention：In described Stober Hydrolyze method, the volume fraction of tetraethyl orthosilicate is 1-5%.
Further improve as the present invention：Described diamagnetism metal is selected from gold, silver, copper, bismuth, silicon dioxide, chlorination
The mixture of one or more of aluminum and/or zinc.
Further improve as the present invention：Described auxiliary agent is selected from silicone levelling agent, fluorine class levelling agent, organosilicon
Defoamer and adhesive agent；Described solvent is the mixing selected from one or more of esters, ketone, alcohols and ether organic solvent
Thing.
Further improve as the present invention：Described it is attached by water plating, plating, ion plating, Vacuum Deposition, chemical plating and has
The method closing plating is realized；Described reflectorized material class pigment is pearlescent pigment, aluminium pigment or glass pigment.
Further improve as the present invention：Described application includes directly applying and indirect application：Described direct application is
Magnetic ink is applied directly to apply on material, then forms space pattern in oriented formation；Described indirect application is by magnetic
Property ink is first constructed on thin-film material, is then needed on by one of thermal transfer, hot stamping and film coating process mode again
On application material；Described application material is paper.
Magnetic orientation forme affects the arrangement of magnetic paint inside magnetic ink by forming magnetic field, and it can be Magnet；
Reflectorized material class pigment is including but not limited to pearlescent pigment, aluminium pigment and glass pigment.Reflective class substrate material is in tiny
Shape, has good reflecting effect；Generation concave-convex sense is because the pigment with diamagnetic material, and the effect through magnetic field is again
Form concavo-convex diamagnetism coat of colo(u)r, the principle of reflection according to light finally presents the vision with strong concave-convex sense after arrangement
Effect.The mixture of one or more of gold, silver, copper and/or zinc is included but is not limited in diamagnetism metal.
In paper printing, can be constructed by various ways such as silk-screen, roller coat, transfer print, overlay films now.Worked it out
Paper have that glossiness is good, the features such as third dimension is strong, pattern enriches.Can be applicable to the fields such as gift wrap, cigarette bag wine bag.Its
The product appearance style of middle cigarette bag wine bag does not change for many years, and yield is huge, has the wide market space.
Brief description
Fig. 1 is：The pattern effect figure that the magnetic ink of test 1 produces.
Fig. 2 is：The pattern effect figure that the magnetic ink of test 2 produces.
Fig. 3 is：The pattern effect figure that the magnetic ink of test 3 produces.
Specific embodiment
A kind of magnetic ink should be used as further more in the paper present invention being provided below by way of specific embodiment
Detailed description：
Material is all molecular, and molecule is by former molecular.Electronics outside atomic nucleus ceaselessly does track fortune
Move and spin motion, and nuclear spin, this all forms microcosmic electric current.Each microcosmic electric current is equivalent to a small load
Streamline circle, thus there is certain magnetic moment.The magnetic moment of most of material atom cores is more much smaller than electron magnetic moment, can ignore not
Meter, therefore the magnetic of material is with electronic magnetic moment, especially its spin magnetic moment plays a major role.The magnetic nature of material often with
The equivalent magnetic moment (or being called unit magnetic moment) of atom or molecule and the intensity of magnetization are illustrating.
When not having external magnetic field, the magnetic moment in atom cancels each other diamagnetic material, and the equivalent magnetic moment of atom is equal to zero,
Material does not externally show magnetic.In the presence of having external magnetic field, also will change around atomic nucleus rotating flow, original magnetic moment in atom
Poised state is destroyed, and a unbalanced magnetic moment occurs in each atom.According to Lenz's law, this electronics is subject to magnetic
The effect of power, its angular momentum changes, and that is, the angular velocity of its rotation will change, thus the microcosmic electricity in atom is uneven
Magnetic moment and outer magnetic field direction contrary, thus producing the phenomenon of counter field arrangement.Therefore, it is added with the pigment containing diamagnetic material
Ink, when the surface of magnetic field N/S contacts, makes pigment produce and repels and inversely arrange, carefully scutellate pigment is through the work in magnetic field
After arrangement, by the reflection of light thus being in the raised ink coating effect that radian projects.
In paramagnetism ink, it is coated with the oxide of ferrum and prepared metallic pigments, this metallic pigments on pearlescent pigment surface
Possess the feature of the oxide of ferrum, can be by attraction, form is tiny lamellar, has reflecting effect.This ink is in magnetic field N/S
Surface contact when, make this metallic pigments rearrangement, carefully scutellate metallic pigments through magnetic field effect arrangement after, pass through
The reflection of light is in the ink coating effect of radian depression.
Test 1
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes diamagnetism ink, and described diamagnetism ink includes following groups by weight
Point：
10 parts of film forming matters, can 1 part of the pigment containing diamagnetic material of counter field arrangement and 1 part of auxiliary agent and molten in magnetic field
0 part of agent；
Wherein, in magnetic field can oriented alignment the pigment containing diamagnetic material with reflective class pigment as base material, described base
Diamagnetic material is attached with material.
Described film forming matter includes resin, and described resin is selected from epoxy resin, polyurethane, acrylic acid and celluosic resin
Mixture.Diamagnetism metal is nanometer diamagnetism metal, and nanometer diamagnetism metal is prepared by Stober Hydrolyze method.
In Stober Hydrolyze method, the mass fraction of ammonia is 10%.In Stober Hydrolyze method, the volume fraction of tetraethyl orthosilicate is 1%.Inverse
Magnetic metal is selected from gold.Auxiliary agent is the mixture in fluorine class levelling agent, organic silicon defoamer and adhesive agent.Solvent is
Mixture selected from ketone, alcohols and ether organic solvent.The method being attached by Vacuum Deposition is realized.Described application includes directly
Application：Described direct application is to be applied directly to apply on material by magnetic ink, then forms space pattern in oriented formation；
Described application material is paper.Design sketch as shown in Fig. 2 pattern is in stereoeffect outwardly, and have as, third dimension is strong,
The migration of light feels weaker.
Test 2
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes paramagnetism ink, and described paramagnetism ink includes following groups by weight
Point：
95 parts of film forming matters, in magnetic field can along 25 parts of the pigment containing ferromagnetic material of magnetic field alignment and 10 parts of auxiliary agent and
88 parts of solvent；
Wherein, in magnetic field can oriented alignment the pigment containing ferromagnetic material with reflective class pigment as base material, described base
Ferromagnetic material is attached with material.
Described film forming matter includes resin, and described resin is selected from epoxy resin, polyurethane, acrylic acid and celluosic resin
Mixture.Ferromagnetic material is the oxide of ferrum.Solvent is the mixture selected from alcohols and ether organic solvent.It is attached by
The method of chemical plating is realized.Described application includes directly applying：Described direct application is to be applied directly to apply by magnetic ink
On material, then form space pattern in oriented formation；Described application material is paper.Design sketch is as shown in Fig. 2 pattern is in vertical
Body geometrical pattern effect.
Test 3
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes paramagnetism ink, and described paramagnetism ink includes following groups by weight
Point：
15 parts of film forming matters, can be along 2 parts of the pigment containing ferromagnetic material of magnetic field alignment and 2 parts of auxiliary agent and molten in magnetic field
8 parts of agent；
Wherein, in magnetic field can oriented alignment the pigment containing ferromagnetic material with reflective class pigment as base material, described base
Ferromagnetic material is attached with material.
Ferromagnetic material is brown iron oxide.Resin is included selected from epoxy resin, polyurethane and acrylic acid mixture.Auxiliary agent
It is selected from organic silicon defoamer.Solvent is selected from ether organic solvent.The method being attached by ion plating is realized.Described application bag
Include indirect application：Described indirect application is that magnetic ink is first constructed on thin-film material, then passes through thermal transfer, hot stamping again
It is needed on application material with one of film coating process mode；Described application material is paper.Design sketch is as shown in figure 3, scheme
Case is in dynamic three-dimensional pattern.
Embodiment 1
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes diamagnetism ink, and described diamagnetism ink includes following groups by weight
Point：
22 parts of film forming matters, can 12 parts of the pigment of diamagnetic material of counter field arrangement and 5 parts of auxiliary agent and molten in magnetic field
38 parts of agent；
Wherein, in magnetic field can oriented alignment the pigment containing diamagnetic material with reflective class pigment as base material, described base
Diamagnetic material is attached with material.
Described film forming matter includes oils and fatss.Diamagnetism metal is nanometer diamagnetism metal, and nanometer diamagnetism metal passes through
Stober Hydrolyze method prepares.In Stober Hydrolyze method, the mass fraction of ammonia is 12%.Positive silicic acid in Stober Hydrolyze method
The volume fraction of ethyl ester is 1.25%.Diamagnetism metal is the mixture selected from gold, silver, copper.Auxiliary agent is selected from silicone stream
Mixture in flat agent and adhesive agent.Solvent is the mixture in esters, alcohols and ether organic solvent.It is attached by
The method of water plating is realized.Described application includes indirect application：Described indirect application is thin-film material that magnetic ink is first constructed
On, then it is needed on application material by one of thermal transfer, hot stamping and film coating process mode again；Described application material
For paper.
Embodiment 2
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes diamagnetism ink, and described diamagnetism ink includes following groups by weight
Point：
35 parts of film forming matters, in magnetic field can 11 parts of the pigment containing diamagnetic material of counter field arrangement and 2 parts of auxiliary agent and
58 parts of solvent；
Wherein, in magnetic field can oriented alignment the pigment containing diamagnetic material with reflective class pigment as base material, described base
Diamagnetic material is attached with material.
Described film forming matter includes rubber.Diamagnetism metal is nanometer diamagnetism metal, and nanometer diamagnetism metal passes through
Stober Hydrolyze method prepares.In Stober Hydrolyze method, the mass fraction of ammonia is 11%.Positive silicic acid in Stober Hydrolyze method
The volume fraction of ethyl ester is 3%.Diamagnetism metal be selected from bismuth, silicon dioxide, chlorination aluminum and zinc mixture.Auxiliary agent be selected from
Silicone levelling agent, organic silicon defoamer and adhesive agent.Solvent is the mixing selected from esters, ketone and ether organic solvent
Thing.The method being attached by Vacuum Deposition is realized.Described application includes directly applying：Described direct application is that magnetic ink is direct
It is coated on application material, then form space pattern in oriented formation；Described application material is paper.
Embodiment 3
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes diamagnetism ink, and described diamagnetism ink includes following groups by weight
Point：
35 parts of film forming matters, in magnetic field can 15 parts of the pigment containing diamagnetic material of counter field arrangement and 6 parts of auxiliary agent and
78 parts of solvent；
Wherein, in magnetic field can oriented alignment the pigment containing diamagnetic material with reflective class pigment as base material, described base
Diamagnetic material is attached with material.
Described film forming matter includes inorganic macromolecule material.Resin includes the mixing selected from epoxy resin and celluosic resin
Thing.Diamagnetism metal is nanometer diamagnetism metal, and nanometer diamagnetism metal is prepared by Stober Hydrolyze method.Stober water
In solution, the mass fraction of ammonia is 25%.In Stober Hydrolyze method, the volume fraction of tetraethyl orthosilicate is 4%.Diamagnetism metal
It is the mixture selected from bismuth, silicon dioxide and zinc.Auxiliary agent is selected from silicone levelling agent, fluorine class levelling agent, organosilicon froth breaking
Agent and adhesive agent.Solvent is the mixture selected from alcohols and ether organic solvent.The method being attached by ion plating is realized.Described
Application includes indirect application：Described indirect application is that magnetic ink is first constructed on thin-film material, then again pass through thermal transfer,
One of hot stamping and film coating process mode is needed on application material；Described application material is paper.
Embodiment 4
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes diamagnetism ink, and described diamagnetism ink includes following groups by weight
Point：
25 parts of film forming matters, 7 parts of pigment and 8 parts of auxiliary agent and the solvent 45 of diamagnetic material can be arranged by counter field in magnetic field
Part；
Wherein, in magnetic field can oriented alignment the pigment containing diamagnetic material with reflective class pigment as base material, described base
Diamagnetic material is attached with material.
Described film forming matter includes resin, and described resin is selected from epoxy resin, polyurethane, acrylic acid mixture.Tree
Fat includes the mixture in epoxy resin, polyurethane, acrylic acid and celluosic resin.Diamagnetism metal is nanometer diamagnetism
Metal, nanometer diamagnetism metal is prepared by Stober Hydrolyze method.In Stober Hydrolyze method, the mass fraction of ammonia is
30%.In Stober Hydrolyze method, the volume fraction of tetraethyl orthosilicate is 3.2%.Diamagnetism metal is selected from gold, bismuth, titanium dioxide
Silicon, the mixture of chlorination aluminum and zinc.Auxiliary agent is the mixture selected from silicone levelling agent, organic silicon defoamer and adhesive agent.
Solvent is the mixture in ketone, alcohols and ether organic solvent.It is attached by electric plating method to realize.Described application bag
Include indirect application：Described indirect application is that magnetic ink is first constructed on thin-film material, then passes through thermal transfer, burn again
One of print, water transfer and film coating process mode is needed on application material；Described application material is paper.
Embodiment 5
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes diamagnetism ink, and described diamagnetism ink includes following groups by weight
Point：
85 parts of film forming matters, can 6 parts of the pigment containing diamagnetic material of counter field arrangement and 7 parts of auxiliary agent and molten in magnetic field
58 parts of agent；
Wherein, in magnetic field can oriented alignment the pigment containing diamagnetic material with reflective class pigment as base material, described base
Diamagnetic material is attached with material.
Described film forming matter includes resin, and described resin is selected from epoxy resin, polyurethane, acrylic acid and celluosic resin
Mixture.Resin includes the mixture selected from epoxy resin, polyurethane, acrylic acid and celluosic resin.Diamagnetism metal is
Nanometer diamagnetism metal, described nanometer diamagnetism metallic pigments are prepared by Stober Hydrolyze method.In Stober Hydrolyze method
The mass fraction of ammonia is 22%.In Stober Hydrolyze method, the volume fraction of tetraethyl orthosilicate is 2%.Diamagnetism metal be selected from
The mixture of gold, silver.Auxiliary agent is selected from silicone levelling agent, fluorine class levelling agent, organic silicon defoamer and adhesive agent.Solvent is
Mixture selected from esters, ketone, alcohols and ether organic solvent.The method being attached by water plating is realized.Described application includes
Indirect application：Described indirect application is that magnetic ink is first constructed on thin-film material, then again pass through thermal transfer, hot stamping and
One of film coating process mode is needed on application material；Described application material is paper.
Embodiment 6
Application in paper for the magnetic ink of the present embodiment, described magnetic ink aligns with reference to magnetic orientation forme,
Form space pattern, described magnetic ink includes paramagnetism ink, and described paramagnetism ink includes following groups by weight
Point：
75 parts of film forming matters, can be along 7 parts of the pigment containing ferromagnetic material of magnetic field alignment and 7 parts of auxiliary agent and molten in magnetic field
68 parts of agent；
Wherein, in magnetic field can oriented alignment the pigment containing ferromagnetic material with reflective class pigment as base material, described base
Ferromagnetic material is attached with material.The method being attached by water plating is realized.
Paramagnet is brown iron oxide, and resin is included in epoxy resin, polyurethane, acrylic acid and celluosic resin
Mixture.Auxiliary agent is selected from silicone levelling agent, organic silicon defoamer and adhesive agent.Solvent is to have selected from alcohols and ethers
The mixture of machine solvent.Described application includes indirect application：Described indirect application is thin-film material that magnetic ink is first constructed
On, then it is needed on application material by one of thermal transfer, hot stamping and film coating process mode again；Described application material
For paper.
The paper that above-described embodiment 1-6 is prepared is compared with the using effect of plain paper and is shown in Table 1；
The paper that table 1 embodiment 1-6 prepares is compared with the using effect of plain paper
| Embodiment | Paper of the present invention | Plain paper |
| Embodiment 1 | There are three-dimensional pattern effect, pattern evagination | No three-dimensional pattern effect |
| Embodiment 2 | There are three-dimensional pattern effect, pattern evagination | No three-dimensional pattern effect |
| Embodiment 3 | There are three-dimensional pattern effect, pattern evagination | No three-dimensional pattern effect |
| Embodiment 4 | There are three-dimensional pattern effect, pattern evagination | No three-dimensional pattern effect |
| Embodiment 5 | There are three-dimensional pattern effect, pattern evagination | No three-dimensional pattern effect |
| Embodiment 6 | There is three-dimensional pattern effect, pattern caves inward | No three-dimensional pattern effect |
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (10)
1. application in paper for the magnetic ink, described magnetic ink aligns with reference to magnetic orientation forme, forms space pattern,
It is characterized in that, described magnetic ink includes paramagnetism ink or diamagnetism ink, described paramagnetism ink or diamagnetism ink
Including following components by weight：
10 95 parts of film forming matters, the pigment 1 25 containing ferromagnetic material or diamagnetic material that can align in magnetic field
Part and auxiliary agent 1-10 part and solvent 0-88 part；
Wherein, in magnetic field can oriented alignment the pigment containing ferromagnetic material or containing diamagnetic material pigment with reflective class face
Expect for base material, described base material to be attached with ferromagnetic material or diamagnetic material.
2. application in paper for the magnetic ink according to claim 1 it is characterised in that：Described film forming matter includes setting
Fat, oils and fatss, rubber, inorganic macromolecule material, described resin is selected from epoxy resin, polyurethane, acrylic acid and celluosic resin
One or more of mixture.
3. application in paper for the magnetic ink according to claim 1 it is characterised in that：Described ferromagnetic material is oxygen
Change iron powder.
4. application in paper for the magnetic ink according to claim 1 it is characterised in that：Described diamagnetic material is to receive
Rice diamagnetism metal, described nanometer diamagnetism metal is prepared by Stober Hydrolyze method.
5. application in paper for the magnetic ink according to claim 4 it is characterised in that：In described Stober Hydrolyze method
The mass fraction of ammonia is 10-35%.
6. application in paper for the magnetic ink according to claim 4 it is characterised in that：In described Stober Hydrolyze method
The volume fraction of tetraethyl orthosilicate is 1-5%.
7. application in paper for the magnetic ink according to claim 4 it is characterised in that：Described diamagnetism metal is choosing
Mixture from one or more of gold, silver, copper, bismuth, silicon dioxide, aluminum chloride and/or zinc.
8. application in paper for the magnetic ink according to claim 1 it is characterised in that：Described auxiliary agent is selected from organic
Silicon class levelling agent, fluorine class levelling agent, organic silicon defoamer and adhesive agent；Described solvent is selected from esters, ketone, alcohols and ethers
The mixture of one or more of organic solvent.
9. application in paper for the magnetic ink according to claim 1 it is characterised in that：Described be attached by water plating,
Plating, ion plating, Vacuum Deposition, chemical plating and the method about plating are realized；Described reflectorized material class pigment is pearlescent pigment, aluminum face
Material or glass pigment.
10. application in paper for the magnetic ink according to claim 1 it is characterised in that：Described application includes directly
Application and indirect application：Described direct application is to be applied directly to apply on material by magnetic ink, then in oriented formation shape
Become space pattern；Described indirect application is that magnetic ink is first constructed on thin-film material, then passes through thermal transfer, hot stamping again
It is needed on application material with one of film coating process mode；Described application material is paper.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610848919.5A CN106400584A (en) | 2016-09-24 | 2016-09-24 | Use of magnetic ink in paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610848919.5A CN106400584A (en) | 2016-09-24 | 2016-09-24 | Use of magnetic ink in paper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106400584A true CN106400584A (en) | 2017-02-15 |
Family
ID=57998180
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610848919.5A Pending CN106400584A (en) | 2016-09-24 | 2016-09-24 | Use of magnetic ink in paper |
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| CN (1) | CN106400584A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110172271A (en) * | 2019-05-14 | 2019-08-27 | 佛山市沃特布恩新型材料有限公司 | A kind of dedicated nano-magnetic printing inks of aluminium sheet coiled material solid paint and preparation method thereof |
| CN111016480A (en) * | 2019-12-02 | 2020-04-17 | 东莞市嘉逸光电有限公司 | Process for printing color-changing LOGO through 3D magnetic ink and 3D magnetic ink |
Citations (6)
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