CN104805872B - Red mud Tailings Dam composite anti-penetrating structure - Google Patents
Red mud Tailings Dam composite anti-penetrating structure Download PDFInfo
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- CN104805872B CN104805872B CN201510228214.9A CN201510228214A CN104805872B CN 104805872 B CN104805872 B CN 104805872B CN 201510228214 A CN201510228214 A CN 201510228214A CN 104805872 B CN104805872 B CN 104805872B
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- 239000002131 composite material Substances 0.000 title claims abstract description 16
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 56
- 230000004888 barrier function Effects 0.000 claims abstract description 42
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 20
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 20
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 19
- 238000007334 copolymerization reaction Methods 0.000 claims abstract description 19
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 18
- 238000000926 separation method Methods 0.000 claims abstract description 18
- 239000010902 straw Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 12
- 239000004425 Makrolon Substances 0.000 claims abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 11
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 11
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 11
- 239000004927 clay Substances 0.000 claims abstract description 10
- 241000209140 Triticum Species 0.000 claims abstract description 9
- 235000021307 Triticum Nutrition 0.000 claims abstract description 9
- 239000010881 fly ash Substances 0.000 claims abstract description 3
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 64
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 32
- 235000019260 propionic acid Nutrition 0.000 claims description 32
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 32
- 239000007998 bicine buffer Substances 0.000 claims description 14
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 14
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 claims description 14
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 12
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 claims description 11
- CPDIOFYYTXQZRA-UHFFFAOYSA-N C(C=CC1=CC=CC=C1)(=O)C(C(=O)O)CSCCC(=O)O Chemical compound C(C=CC1=CC=CC=C1)(=O)C(C(=O)O)CSCCC(=O)O CPDIOFYYTXQZRA-UHFFFAOYSA-N 0.000 claims description 11
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 10
- 239000011083 cement mortar Substances 0.000 claims description 8
- 239000010883 coal ash Substances 0.000 claims description 8
- 239000006096 absorbing agent Substances 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000008397 galvanized steel Substances 0.000 claims description 4
- 239000012965 benzophenone Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 230000009102 absorption Effects 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 claims 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 239000002351 wastewater Substances 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 239000002585 base Substances 0.000 description 36
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical group OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 26
- 239000010410 layer Substances 0.000 description 23
- 239000000203 mixture Substances 0.000 description 19
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000004744 fabric Substances 0.000 description 7
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 6
- 230000008595 infiltration Effects 0.000 description 6
- 238000001764 infiltration Methods 0.000 description 6
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 241000522254 Cassia Species 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 150000003851 azoles Chemical class 0.000 description 3
- 125000005605 benzo group Chemical group 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910001570 bauxite Inorganic materials 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UPLPHRJJTCUQAY-WIRWPRASSA-N 2,3-thioepoxy madol Chemical compound C([C@@H]1CC2)[C@@H]3S[C@@H]3C[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@](C)(O)[C@@]2(C)CC1 UPLPHRJJTCUQAY-WIRWPRASSA-N 0.000 description 1
- IELAVJDOWOPAMD-UHFFFAOYSA-N 4-n-hexylbenzene-1,4-diamine Chemical compound CCCCCCNC1=CC=C(N)C=C1 IELAVJDOWOPAMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004895 Lipoproteins Human genes 0.000 description 1
- 108090001030 Lipoproteins Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000006353 environmental stress Effects 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D31/00—Protective arrangements for foundations or foundation structures; Ground foundation measures for protecting the soil or the subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/002—Ground foundation measures for protecting the soil or subsoil water, e.g. preventing or counteracting oil pollution
- E02D31/006—Sealing of existing landfills, e.g. using mining techniques
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2300/00—Materials
- E02D2300/0045—Composites
-
- E—FIXED CONSTRUCTIONS
- E02—HYDRAULIC ENGINEERING; FOUNDATIONS; SOIL SHIFTING
- E02D—FOUNDATIONS; EXCAVATIONS; EMBANKMENTS; UNDERGROUND OR UNDERWATER STRUCTURES
- E02D2450/00—Gaskets
- E02D2450/10—Membranes
- E02D2450/105—Membranes impermeable
Landscapes
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Paleontology (AREA)
- Civil Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention discloses a kind of red mud Tailings Dam composite anti-penetrating structure; including the impervious barrier being arranged in side slope and the flexible cover sheet being arranged on impervious barrier and the rigid course being arranged at below impervious barrier; separation layer is additionally provided between the rigid course and impervious barrier; the separation layer is mixed by wheat straw or straw with clay, and the antiseepage layer material includes makrolon, polytetrafluoroethylene (PTFE), polybutylene terephthalate, flyash, sledge mill glass, graft copolymerization acrylic acid derivative, antioxidant, ultra-violet absorber, age resistor；Used impervious material physics, stable chemical performance, cryogenic property, ageing resistace are excellent, right angle tear resistance is strong, joint reliability is high, whole impervious barrier structural strength is high, with very strong tensile strength and elongation percentage, to adapt to locally wear intensity to the anti-top of sandstone in large-area storage yard, it is ensured that wastewater from red mud will not penetrate into underground during use in stockyard.
Description
Technical field
The present invention relates to the processing of Tailings Dam, more particularly to a kind of red mud Tailings Dam composite anti-penetrating structure.
Background technology
The raw material of aluminum smelting industry is usually bauxite, remaining remaining mineral after being extracted to the active ingredient of bauxite
Residue is Aluminum mine tailing, normally referred to as red mud.Red mud is that a kind of particle of red similar soil forms material, its mineral
Form more complicated, mainly contain the mineral matters such as aluminum oxide, iron oxide and silica, typically exhibit stronger alkalescence and corrosion
Property.Due to red mud and wherein liquid body exudate (wastewater from red mud) has strong basicity and corrosivity, and it has very strong destructiveness to environment,
Pair there is very havoc power with the animals and plants closed on, therefore the safe stockpiling problem of red mud seems and is even more important.Store up the place of red mud
As Aluminum Tailings Dam or red mud Tailings Dam, in southwest, usual addressing makes full use of landform nature Cheng Ku in mountain area, then auxiliary
Help progress is necessary manually to build a dam.It is its stability and permeability resistance for the problem of reservoir area and dam body maximum, wherein again with steady
Qualitative question is attached most importance to, once red mud Tailings Dam dam break, a large amount of red muds and wastewater from red mud will leak, and this can be to the life of neighbouring resident
Property safety and surrounding enviroment cause huge threat.In order to prevent the outside seepage of the harmful substance in industrial tailings from being made to soil
Into pollution, so to carry out Anti-seeping technology to industrial tailings, antiseepage cloth is set generally in massif side slope, covered on antiseepage cloth
Certain thickness yellow clay makes real, it is therefore an objective to avoids antiseepage cloth from being directly exposed in atmospheric environment, prevents from making because exposing to the weather
The too fast aging of antiseepage cloth, but during practice of construction, due under the influence of slope height and soil self gravitation, covering
The effect that antiseepage cloth in side slope can be torn, particularly when abundant rainfall, the soil that is covered on antiseepage cloth
Easily it is washed, antiseepage cloth is easily damaged, and directly affects anti-seepage effect.
The content of the invention
In view of this, it is an object of the invention to provide a kind of red mud Tailings Dam composite anti-penetrating structure, used antiseepage
Material Physics, stable chemical performance, cryogenic property, ageing resistace are excellent, and right angle tear resistance is strong, and joint reliability is high, whole
Individual impervious barrier structural strength is high, has very strong tensile strength and elongation percentage, to adapt in large-area storage yard locally to sandstone
Anti- top wear intensity, it is ensured that wastewater from red mud will not penetrate into underground during use in stockyard.
The red mud Tailings Dam composite anti-penetrating structure of the present invention, including the impervious barrier being arranged in side slope and it is arranged at impervious barrier
On flexible cover sheet and the rigid course that is arranged at below impervious barrier, also set up between the rigid course and impervious barrier
There is separation layer, the separation layer is mixed by wheat straw or straw with clay, and the antiseepage layer material includes following by weight
Component：20-30 parts makrolon, 10-20 parts polytetrafluoroethylene (PTFE), 5-12 parts polybutylene terephthalate, 10-15 part fine coal
Ash, 1-10 part sledge mills glass, 1-5 part graft copolymerizations acrylic acid derivative, 1-5 parts antioxidant, 0.5-3 parts ultra-violet absorber,
1-3 part age resistor；
Further, the flexible cover sheet is in flexible steel silk screen, flexible galvanized steel wire netting, high-strength polyester fibers flexible net
One kind；
Further, the antioxidant is double cinnamoyl thiobis propionic acid fat, stearic bicine diester base thiobis propionic acid fat, four
One or both of [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol ester thing mixed above；
Further, the ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone, (2'- hydroxyls -5'- is tertiary pungent by 2-
Base phenyl) BTA, one or both of HMPA thing mixed above；
Further, the age resistor is N- phenyl-N`- cyclohexyl p-phenylenediamine, N- phenyl-N`- isopropyls-to benzene two
One or both of amine, styrenated diphenylamine thing mixed above；
Further, the graft copolymerization acrylic acid derivative be butyl acrylate, one kind in single base methyl acrylate or
Two kinds；
Further, the antiseepage layer material includes following components by weight：25 parts of makrolon, 15 parts of polytetrafluoroethyl-nes
Alkene, 8 parts of polybutylene terephthalates, 12 parts of flyash, 6 parts of sledge mill glasses, 3 parts of graft copolymerization acrylic acid derivatives, 3 parts it is anti-
Oxygen agent, 2 parts of ultra-violet absorbers, 2 parts of age resistor；
Further, the rigid course is cement mortar.
Beneficial effects of the present invention：The red mud Tailings Dam composite anti-penetrating structure of the present invention, flexible protective layer is to red-mud settlement
During play cushioning effect to tension caused by impervious barrier, mitigate red mud and peel off damage to caused by impervious barrier, rigidly guarantor
Sheath can play a part of reinforce basic unit, avoid basic unit from settling, used antiseepage layer material have good heat resistance and
Cold resistance, chemical stability is good, has higher rigidity and toughness, and mechanical strength is good, resisting environmental stress and cracking with it is tear-resistant strong
Degree performance is good, and with the rising of density, mechanical performance and barrier property can be improved accordingly, heat-resisting, and tensile strength is also higher；Can
Acid and alkali resistance, organic solvent etc. corrode, and have outstanding anti-aging, uvioresistant, antidecomposition ability, exposed can use, right angle resists
Lancinating is strong, and joint reliability is high, and whole impervious barrier structural strength is high, has very strong tensile strength and elongation percentage, with suitable
Answer in large-area storage yard and intensity locally is worn to the anti-top of sandstone, it is ensured that wastewater from red mud will not penetrate into ground during use in stockyard
Under.
Brief description of the drawings
The invention will be further described with reference to the accompanying drawings and examples：
Fig. 1 is the structural representation of the present invention.
Embodiment
Embodiment one
The red mud Tailings Dam composite anti-penetrating structure of the present embodiment, including the impervious barrier 2 being arranged in side slope and be arranged at it is anti-
Flexible cover sheet 1 on infiltration layer 2 and the rigid course 4 for being arranged at the lower section of impervious barrier 2, the rigid course 4 and impervious barrier 2
Between be additionally provided with separation layer 3, the separation layer 3 is mixed by wheat straw or straw with clay, the material of impervious barrier 2 by weight
Amount part includes following components：25 parts of makrolon, 15 parts of polytetrafluoroethylene (PTFE), 8 parts of polybutylene terephthalates, 12 parts of fine coal
Ash, 6 parts of sledge mill glasses, 3 parts of graft copolymerization acrylic acid derivatives, 3 parts of antioxidant, 2 parts of ultra-violet absorbers, 2 parts of age resistor.
In the present embodiment, the flexible cover sheet 1 is flexible steel silk screen.
In the present embodiment, the antioxidant is double cinnamoyl thiobis propionic acid fat, in the present embodiment, by double Chinese cassia trees
The double propionic acid fat of acyl thiocarbamates replace with stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level fourths according to equivalent weight part
Base -4- hydroxy phenyls) propionic acid] one kind in pentaerythritol ester, or replace with double cinnamoyl thiobis third by equivalent weight part
Sour fat mixes with stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters
Compound；Products obtained therefrom property has no significant difference.
In the present embodiment, the ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone, will in the present embodiment
2-hydroxy-4-n-octoxybenzophenone replaces with 2- (2'- hydroxyl -5'- t-octyls phenyl) benzo three according to equivalent weight part
One kind in azoles, HMPA, or replace with 2-hydroxy-4-n-octoxybenzophenone and 2- by equivalent weight part
(2'- hydroxyl -5'- t-octyls phenyl) BTA, the mixture of HMPA；Products obtained therefrom property has no obvious poor
Not.
In the present embodiment, the age resistor is N- phenyl-N`- cyclohexyl p-phenylenediamine, in the present embodiment, by the N- benzene
Base-N`- cyclohexyl p-phenylenediamine replaces with N- phenyl-N`- isopropyls-p-phenylenediamine, styrol two according to equivalent weight part
One kind in aniline, or by equivalent weight part replace with N- phenyl-N`- cyclohexyl p-phenylenediamine and N- phenyl-N`- isopropyls-
The mixture of p-phenylenediamine, styrenated diphenylamine；Products obtained therefrom property has no significant difference.
In the present embodiment, the graft copolymerization acrylic acid derivative is butyl acrylate, in the present embodiment, by the propylene
Acid butyl ester replaces with single base methyl acrylate according to equivalent weight part, or replaces with butyl acrylate and list according to equivalent weight part
The mixture of base methyl acrylate, products obtained therefrom property have no significant difference.
The rigid course 3 is cement mortar.
Embodiment two
The red mud Tailings Dam composite anti-penetrating structure of the present embodiment, including the impervious barrier 2 being arranged in side slope and be arranged at it is anti-
Flexible cover sheet 1 on infiltration layer 2 and the rigid course 4 for being arranged at the lower section of impervious barrier 2, the rigid course 4 and impervious barrier 2
Between be additionally provided with separation layer 3, the separation layer 3 is mixed by wheat straw or straw with clay, the material of impervious barrier 2 by weight
Amount part includes following components：20 parts of makrolon, 10 parts of polytetrafluoroethylene (PTFE), 5 parts of polybutylene terephthalates, 10 parts of fine coal
Ash, 1 part of sledge mill glass, 1 part of graft copolymerization acrylic acid derivative, 1 part of antioxidant, 0.5 part of ultra-violet absorber, 1 part of age resistor.
In the present embodiment, flexible galvanized steel wire netting.
In the present embodiment, the antioxidant is stearic bicine diester base thiobis propionic acid fat, will be described double stearic in the present embodiment
The double propionic acid fat of acyl thiocarbamates replace with double cinnamoyl thiobis propionic acid fat, four [β-(3,5- three-level fourths according to equivalent weight part
Base -4- hydroxy phenyls) propionic acid] one kind in pentaerythritol ester, or replace with stearic bicine diester base thiobis third by equivalent weight part
Sour fat mixes with double cinnamoyl thiobis propionic acid fat, four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters
Compound；Products obtained therefrom property has no significant difference.
In the present embodiment, the ultra-violet absorber is 2- (2'- hydroxyl -5'- t-octyls phenyl) BTA, this implementation
In example, 2- (2'- hydroxyl -5'- t-octyls phenyl) BTA is replaced with into 2- hydroxyl -4- n-octyloxies according to equivalent weight part
One kind in benzophenone, HMPA, or replace with 2- (2'- hydroxyl -5'- t-octyls phenyl) by equivalent weight part
BTA and 2-hydroxy-4-n-octoxybenzophenone, the mixture of HMPA；Products obtained therefrom property has no bright
Significant difference is other.
In the present embodiment, the age resistor is N- phenyl-N`- isopropyls-p-phenylenediamine, in the present embodiment, by the N-
Phenyl-N`- isopropyls-p-phenylenediamine replaces with N- phenyl-N`- cyclohexyl p-phenylenediamine, styrol according to equivalent weight part
One kind in diphenylamines, or replace with N- phenyl-N`- isopropyls-p-phenylenediamine and N- phenyl-N`- hexamethylenes by equivalent weight part
The mixture of base p-phenylenediamine, styrenated diphenylamine；Products obtained therefrom property has no significant difference.
In the present embodiment, the graft copolymerization acrylic acid derivative is single base methyl acrylate, in the present embodiment, will described in
Single base methyl acrylate replaces with butyl acrylate according to equivalent weight part, or replaces with butyl acrylate according to equivalent weight part
With the mixture of single base methyl acrylate, products obtained therefrom property has no significant difference.
The rigid course 3 is cement mortar.
Embodiment three
The red mud Tailings Dam composite anti-penetrating structure of the present embodiment, including the impervious barrier 2 being arranged in side slope and be arranged at it is anti-
Flexible cover sheet 1 on infiltration layer 2 and the rigid course 4 for being arranged at the lower section of impervious barrier 2, the rigid course 4 and impervious barrier 2
Between be additionally provided with separation layer 3, the separation layer 3 is mixed by wheat straw or straw with clay, the material of impervious barrier 2 by weight
Amount part includes following components：30 parts of makrolon, 20 parts of polytetrafluoroethylene (PTFE), 12 parts of polybutylene terephthalates, 15 parts of fine coal
Ash, 10 parts of sledge mill glasses, 5 parts of graft copolymerization acrylic acid derivatives, 5 parts of antioxidant, 3 parts of ultra-violet absorbers, 3 parts of age resistor；
In the present embodiment, the flexible cover sheet 1 is high-strength polyester fibers flexible net.
In the present embodiment, the antioxidant is four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters,
In the present embodiment, by described four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters according to equivalent weight part
One kind in stearic bicine diester base thiobis propionic acid fat, double cinnamoyl thiobis propionic acid fat is replaced with, or is replaced by equivalent weight part
It is changed to four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters and stearic bicine diester base thiobis propionic acid fat, double
Cinnamoyl thiobis propionic acid lipoprotein mixture；Products obtained therefrom property has no significant difference.
In the present embodiment, the ultra-violet absorber is HMPA, in the present embodiment, by hexamethyl phosphinylidyne three
Amine replaces with 2- (2'- hydroxyl -5'- t-octyls phenyl) BTA, 2- hydroxyl -4- n-octyloxy hexichol according to equivalent weight part
One kind in ketone, or replace with HMPA and 2- (2'- hydroxyl -5'- t-octyls phenyl) benzene by equivalent weight part
And the mixture of triazole, 2-hydroxy-4-n-octoxybenzophenone；Products obtained therefrom property has no significant difference.
In the present embodiment, the age resistor is styrenated diphenylamine, in the present embodiment, by the styrenated diphenylamine
One in N- phenyl-N`- isopropyls-p-phenylenediamine, N- phenyl-N`- cyclohexyl p-phenylenediamine is replaced with according to equivalent weight part
Kind, or replace with styrenated diphenylamine and N- phenyl-N`- isopropyls-p-phenylenediamine, N- phenyl-N`- rings by equivalent weight part
The mixture of hexyl p-phenylenediamine；Products obtained therefrom property has no significant difference.
In the present embodiment, the graft copolymerization acrylic acid derivative is butyl acrylate, in the present embodiment, by the propylene
Acid butyl ester replaces with single base methyl acrylate according to equivalent weight part, or replaces with butyl acrylate and list according to equivalent weight part
The mixture of base methyl acrylate, products obtained therefrom property have no significant difference.
The rigid course 3 is cement mortar
Example IV
The red mud Tailings Dam composite anti-penetrating structure of the present embodiment, including the impervious barrier 2 being arranged in side slope and be arranged at it is anti-
Flexible cover sheet 1 on infiltration layer 2 and the rigid course 4 for being arranged at the lower section of impervious barrier 2, the rigid course 4 and impervious barrier 2
Between be additionally provided with separation layer 3, the separation layer 3 is mixed by wheat straw or straw with clay, the material of impervious barrier 2 by weight
Amount part includes following components：20 parts of makrolon, 20 parts of polytetrafluoroethylene (PTFE), 5 parts of polybutylene terephthalates, 15 parts of fine coal
Ash, 1 part of sledge mill glass, 5 parts of graft copolymerization acrylic acid derivatives, 1 part of antioxidant, 3 parts of ultra-violet absorbers, 1 part of age resistor.
In the present embodiment, the flexible cover sheet 1 is flexible steel silk screen.
In the present embodiment, the antioxidant is double cinnamoyl thiobis propionic acid fat, in the present embodiment, by double Chinese cassia trees
The double propionic acid fat of acyl thiocarbamates replace with stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level fourths according to equivalent weight part
Base -4- hydroxy phenyls) propionic acid] one kind in pentaerythritol ester, or replace with double cinnamoyl thiobis third by equivalent weight part
Sour fat mixes with stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters
Compound；Products obtained therefrom property has no significant difference.
In the present embodiment, the ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone, will in the present embodiment
2-hydroxy-4-n-octoxybenzophenone replaces with 2- (2'- hydroxyl -5'- t-octyls phenyl) benzo three according to equivalent weight part
One kind in azoles, HMPA, or replace with 2-hydroxy-4-n-octoxybenzophenone and 2- by equivalent weight part
(2'- hydroxyl -5'- t-octyls phenyl) BTA, the mixture of HMPA；Products obtained therefrom property has no obvious poor
Not.
In the present embodiment, the age resistor is N- phenyl-N`- cyclohexyl p-phenylenediamine, in the present embodiment, by the N- benzene
Base-N`- cyclohexyl p-phenylenediamine replaces with N- phenyl-N`- isopropyls-p-phenylenediamine, styrol two according to equivalent weight part
One kind in aniline, or by equivalent weight part replace with N- phenyl-N`- cyclohexyl p-phenylenediamine and N- phenyl-N`- isopropyls-
The mixture of p-phenylenediamine, styrenated diphenylamine；Products obtained therefrom property has no significant difference.
In the present embodiment, the graft copolymerization acrylic acid derivative is butyl acrylate, in the present embodiment, by the propylene
Acid butyl ester replaces with single base methyl acrylate according to equivalent weight part, or replaces with butyl acrylate and list according to equivalent weight part
The mixture of base methyl acrylate, products obtained therefrom property have no significant difference.
The rigid course 3 is cement mortar.
Embodiment five
The red mud Tailings Dam composite anti-penetrating structure of the present embodiment, including the impervious barrier 2 being arranged in side slope and be arranged at it is anti-
Flexible cover sheet 1 on infiltration layer 2 and the rigid course 4 for being arranged at the lower section of impervious barrier 2, the rigid course 4 and impervious barrier 2
Between be additionally provided with separation layer 3, the separation layer 3 is mixed by wheat straw or straw with clay, the material of impervious barrier 2 by weight
Measuring part includes 30 parts of makrolon of following components, 10 parts of polytetrafluoroethylene (PTFE), 12 parts of polybutylene terephthalates, 10 parts of fine coal
Ash, 10 parts of sledge mill glasses, 1 part of graft copolymerization acrylic acid derivative, 5 parts of antioxidant, 0.5 part of ultra-violet absorber, 3 parts it is anti-old
Agent.
In the present embodiment, flexible galvanized steel wire netting.
In the present embodiment, the antioxidant is stearic bicine diester base thiobis propionic acid fat, will be described double stearic in the present embodiment
The double propionic acid fat of acyl thiocarbamates replace with double cinnamoyl thiobis propionic acid fat, four [β-(3,5- three-level fourths according to equivalent weight part
Base -4- hydroxy phenyls) propionic acid] one kind in pentaerythritol ester, or replace with stearic bicine diester base thiobis third by equivalent weight part
Sour fat mixes with double cinnamoyl thiobis propionic acid fat, four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters
Compound；Products obtained therefrom property has no significant difference.
In the present embodiment, the ultra-violet absorber is 2- (2'- hydroxyl -5'- t-octyls phenyl) BTA, this implementation
In example, 2- (2'- hydroxyl -5'- t-octyls phenyl) BTA is replaced with into 2- hydroxyl -4- n-octyloxies according to equivalent weight part
One kind in benzophenone, HMPA, or replace with 2- (2'- hydroxyl -5'- t-octyls phenyl) by equivalent weight part
BTA and 2-hydroxy-4-n-octoxybenzophenone, the mixture of HMPA；Products obtained therefrom property has no bright
Significant difference is other.
In the present embodiment, the age resistor is N- phenyl-N`- isopropyls-p-phenylenediamine, in the present embodiment, by the N-
Phenyl-N`- isopropyls-p-phenylenediamine replaces with N- phenyl-N`- cyclohexyl p-phenylenediamine, styrol according to equivalent weight part
One kind in diphenylamines, or replace with N- phenyl-N`- isopropyls-p-phenylenediamine and N- phenyl-N`- hexamethylenes by equivalent weight part
The mixture of base p-phenylenediamine, styrenated diphenylamine；Products obtained therefrom property has no significant difference.
In the present embodiment, the graft copolymerization acrylic acid derivative is single base methyl acrylate, in the present embodiment, will described in
Single base methyl acrylate replaces with butyl acrylate according to equivalent weight part, or replaces with butyl acrylate according to equivalent weight part
With the mixture of single base methyl acrylate, products obtained therefrom property has no significant difference.
The rigid course 3 is cement mortar.
Embodiment six
The red mud Tailings Dam composite anti-penetrating structure of the present embodiment, including the impervious barrier 2 being arranged in side slope and be arranged at it is anti-
Flexible cover sheet 1 on infiltration layer 2 and the rigid course 4 for being arranged at the lower section of impervious barrier 2, the rigid course 4 and impervious barrier 2
Between be additionally provided with separation layer 3, the separation layer 3 is mixed by wheat straw or straw with clay, the material of impervious barrier 2 by weight
Amount part includes following components：28 parts of makrolon, 12 parts of polytetrafluoroethylene (PTFE), 5 parts of polybutylene terephthalates, 15 parts of fine coal
Ash, 6 parts of sledge mill glasses, 2.5 parts of graft copolymerization acrylic acid derivatives, 2.5 parts of antioxidant, 3 parts of ultra-violet absorbers, 3 parts it is anti-old
Agent.
In the present embodiment, the flexible cover sheet 1 is flexible steel silk screen.
In the present embodiment, the antioxidant is double cinnamoyl thiobis propionic acid fat, in the present embodiment, by double Chinese cassia trees
The double propionic acid fat of acyl thiocarbamates replace with stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level fourths according to equivalent weight part
Base -4- hydroxy phenyls) propionic acid] one kind in pentaerythritol ester, or replace with double cinnamoyl thiobis third by equivalent weight part
Sour fat mixes with stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters
Compound；Products obtained therefrom property has no significant difference.
In the present embodiment, the ultra-violet absorber is 2-hydroxy-4-n-octoxybenzophenone, will in the present embodiment
2-hydroxy-4-n-octoxybenzophenone replaces with 2- (2'- hydroxyl -5'- t-octyls phenyl) benzo three according to equivalent weight part
One kind in azoles, HMPA, or replace with 2-hydroxy-4-n-octoxybenzophenone and 2- by equivalent weight part
(2'- hydroxyl -5'- t-octyls phenyl) BTA, the mixture of HMPA；Products obtained therefrom property has no obvious poor
Not.
In the present embodiment, the age resistor is N- phenyl-N`- cyclohexyl p-phenylenediamine, in the present embodiment, by the N- benzene
Base-N`- cyclohexyl p-phenylenediamine replaces with N- phenyl-N`- isopropyls-p-phenylenediamine, styrol two according to equivalent weight part
One kind in aniline, or by equivalent weight part replace with N- phenyl-N`- cyclohexyl p-phenylenediamine and N- phenyl-N`- isopropyls-
The mixture of p-phenylenediamine, styrenated diphenylamine；Products obtained therefrom property has no significant difference.
In the present embodiment, the graft copolymerization acrylic acid derivative is butyl acrylate, in the present embodiment, by the propylene
Acid butyl ester replaces with single base methyl acrylate according to equivalent weight part, or replaces with butyl acrylate and list according to equivalent weight part
The mixture of base methyl acrylate, products obtained therefrom property have no significant difference.
The rigid course 3 is cement mortar.
Finally illustrate, above example is only to illustrate the technical scheme of the present embodiment and unrestricted, although reference
The present embodiment is described in detail for preferred embodiment, it will be understood by those within the art that, can be to this implementation
The technical scheme of example is modified or equivalent substitution, and without departing from the objective and scope of the present embodiment technical scheme, it all should
Cover among the right of the present embodiment.
Claims (3)
- A kind of 1. red mud Tailings Dam composite anti-penetrating structure, it is characterised in that：Including the impervious barrier being arranged in side slope and it is arranged at Flexible cover sheet on impervious barrier and the rigid course being arranged at below impervious barrier, between the rigid course and impervious barrier Separation layer is additionally provided with, the separation layer is mixed by wheat straw or straw with clay, and the antiseepage layer material wraps by weight Include following components：20-30 parts makrolon, 10-20 parts polytetrafluoroethylene (PTFE), 5-12 parts polybutylene terephthalate, 10-15 parts Flyash, 1-10 part sledge mills glass, 1-5 part graft copolymerizations acrylic acid derivative, 1-5 parts antioxidant, 0.5-3 part ultraviolet radiation absorptions Agent, 1-3 part age resistor；The graft copolymerization acrylic acid derivative be butyl acrylate, one kind in single base methyl acrylate or Two kinds；The flexible cover sheet is one kind in flexible steel silk screen, flexible galvanized steel wire netting, high-strength polyester fibers flexible net；Institute It is double cinnamoyl thiobis propionic acid fat, stearic bicine diester base thiobis propionic acid fat, four [β-(3,5- three-level butyl -4- to state antioxidant Hydroxy phenyl) propionic acid] one or both of pentaerythritol ester thing mixed above；The ultra-violet absorber is 2- hydroxyls -4- Oxy-octyl benzophenone, 2- (2'- hydroxyl -5'- t-octyls phenyl) BTA, one kind in HMPA or two Kind thing mixed above；The age resistor be N- phenyl-N`- cyclohexyl p-phenylenediamine, N- phenyl-N`- isopropyls-p-phenylenediamine, One or both of styrenated diphenylamine thing mixed above.
- 2. red mud Tailings Dam composite anti-penetrating structure according to claim 1, it is characterised in that：The antiseepage layer material is by weight Amount part includes following components：25 parts of makrolon, 15 parts of polytetrafluoroethylene (PTFE), 8 parts of polybutylene terephthalates, 12 parts of fine coal Ash, 6 parts of sledge mill glasses, 3 parts of graft copolymerization acrylic acid derivatives, 3 parts of antioxidant, 2 parts of ultra-violet absorbers, 2 parts of age resistor.
- 3. the red mud Tailings Dam composite anti-penetrating structure described in a claim 1, it is characterised in that：The rigid course is cement Mortar.
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| CN107653916A (en) * | 2017-10-30 | 2018-02-02 | 滨州学院 | A kind of waterproof clay liner of super-hydrophobic self-healing |
| CN108863285B (en) * | 2018-08-20 | 2020-11-13 | 中钢集团马鞍山矿山研究总院股份有限公司 | Composite tailing sand plastic anti-seepage material and construction process thereof |
| CN108867712B (en) * | 2018-08-20 | 2020-03-31 | 中钢集团马鞍山矿山研究院有限公司 | Side slope, pit bottom and substrate seepage prevention method based on tailing composite seepage prevention material |
| CN114455893B (en) * | 2022-01-27 | 2023-06-09 | 中国地质科学院矿产综合利用研究所 | Method for treating pollution of electrolytic manganese slag tailing pond by cementing controlled release |
| CN115142441B (en) * | 2022-07-05 | 2024-05-10 | 浙江省环保集团有限公司 | A barrier layer protection device for domestic waste landfill side slope excavation |
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| JPS5725382A (en) * | 1980-07-23 | 1982-02-10 | Seiichi Yamazaki | Waterstopping agent for underwater boring |
| CN2863912Y (en) * | 2006-01-09 | 2007-01-31 | 中国铝业股份有限公司 | Bayer red mud yard seepage control structure |
| CN201512779U (en) * | 2009-10-22 | 2010-06-23 | 北京高能时代环境技术股份有限公司 | Seepage control structure used in red mud disposal sites |
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