CN104479833A - High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof - Google Patents
High-efficiency safe environment-friendly all-synthetic cutting fluid and preparation method thereof Download PDFInfo
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- CN104479833A CN104479833A CN201410779931.6A CN201410779931A CN104479833A CN 104479833 A CN104479833 A CN 104479833A CN 201410779931 A CN201410779931 A CN 201410779931A CN 104479833 A CN104479833 A CN 104479833A
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Abstract
The invention discloses a high-efficiency safe environment-friendly all-synthetic cutting fluid and a preparation method thereof. The cutting fluid consists of the following components in percentage by weight: 20-30% of synthetic ester, 4-8% of surfactant, 5-15% of antirust agent, 2-10% of pH regulator, 0-3% of corrosion inhibitor and the balance of deionized water. The preparation method comprises the following specific steps: adding the pH regulator into part of the deionized water and stirring uniformly; adding the corrosion inhibitor and the antirust agent in turn and stirring until solid powder is completely dissolved; after uniformly mixing and stirring the synthetic ester, adding the surfactant of the proportion and stirring for 15 minutes till uniformity; pouring a semi-finished product into the reaction system and stirring uniformly; repeatedly flushing the preparation container with the rest deionized water, and completely beating the flushing liquid back into the reaction system; and continuously stirring the reaction system until the solution is uniform and transparent to obtain a finished product. In the invention, the prepared all-synthetic cutting fluid has excellent lubricating and antirust and corrosion inhibition properties as well as good stability at high and low temperature to avoid color change, and avoids stimulation to the skin of a human body; and moreover, the all-synthetic cutting fluid has good biological stability and is safe, environment-friendly and non-irritant.
Description
Technical field
The present invention relates to a kind of high-effect safety and environmental protection fully synthetic cutting fluid, the invention still further relates to a kind of preparation method of high-effect safety and environmental protection fully synthetic cutting fluid, belong to metal working fluid arts.
Background technology
Synthesis liquid compares with emulsion, long service life, cooling and cleaning performance excellent, applicable high speed cutting.Because solution is transparent, there is good visibility, be particularly suitable for the modern manufacturing machines such as numerically-controlled machine or machining center uses.Synthetic cutting fluid puts into the workpiece visibility being that a little economy or rapid heat dissipation or cleaning are strong and fabulous, is easy to controlled working size, its stability and resistance to corrosion stronger than emulsion.But because oilness is not good enough, this will cause sticking together and wearing and tearing of lathe movable part, and the thick residue that synthesis liquid stays can affect the motion of machine parts, and the faying surface of these parts also can be made to produce corrosion.
At present, much new product development all can provide best oilness and corrosion protection around complete synthesis product and be easy to liquid waste disposal and launch.By emulsifying technology together with complete synthesis Chemical bond, by using emulsifying agent by the water inlet of the water insoluble lubricants of synthesis breast, formed containing base oil and the formula of easy liquid waste disposal.
Such as patent CN201110442603 provides a kind of fully synthetic cutting fluid of self-emulsifying type, substitutes traditional polyether lubricant with high performance self-emulsifying ester, develops a kind of based on renewable raw materials or high performance and long service life fully synthetic cutting fluid.But use the inhibiter of phosphorus containing components in its formula, and phosphorus easily causes growing of fungi in system, makes product smelly rotten.The oil using a large amount of tensio-active agents easily to cause system to wash away on guide rail because cleaning is too strong in above-mentioned patent formulation or cause paint flake, impact normally works running, causes lathe corrosion, brings unnecessary loss to client.Be equipped with pyrrolotriazine derivatives or morpholine derivative etc. as sterilant in this formula simultaneously, and actual use in the very easily variable color and make stoste color burn of this series bactericidal agent, and then have influence on the visibility of working fluid, be unfavorable for the surface observation of workpiece; Sterilant easily produces pungency to human body skin in addition.
Summary of the invention
The object of the invention is to for deficiency of the prior art, a kind of high-effect safety and environmental protection fully synthetic cutting fluid and preparation method thereof is provided, there is excellent lubrication or antirust corrosion inhibition, high/low temperature good stability, not easy to change, human body skin is had no stimulation, can not cause lathe paint and peel off, biologically stable is good, and safety and environmental protection is non-stimulated.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of high-effect safety and environmental protection fully synthetic cutting fluid, and its innovative point is: be made up of the weight percent of following component:
Synthetic ester 20-30%
Tensio-active agent 4-8%
Rust-preventive agent 5-15%
PH value regulator 2-10%
Inhibiter 0-3%
Deionized water surplus
Further, described synthetic ester is one in the synthetic ester of Vegetable oil lipoprotein or animal grease or oleic acid ester and modification thereof or any several mixture.
Further, described tensio-active agent is one in fatty acid amide or aliphatic acid polyethenoxy ether or fatty alcohol-polyoxyethylene ether or any several mixture.
Further, described rust-preventive agent is by the one in binary or triprotic acid and carboxylate salt thereof or borate and modified carboxylate or any several mixture.
Further, described pH value regulator is one in trolamine or diglycolamine or monoisopropanolamine or AMP-95 or any several mixture.
Further, described inhibiter is one in siloxanes ketone or metasilicate or molybdate or benzotriazole and its derivative or any several mixture.
Another object of the present invention is to provide a kind of preparation method of high-effect safety and environmental protection fully synthetic cutting fluid, and its innovative point is: concrete steps are as follows:
(1) pH value regulator adding proportional quantity in 40% proportional quantity deionized water stirs; Add inhibiter or rust-preventive agent to be more successively stirred to pressed powder and to dissolve completely;
(2) by after the synthetic ester mixing and stirring of proportional quantity, add proportional quantity tensio-active agent, stir 15 minutes to even;
(3) work in-process in step (2) are poured in the reaction system of step (1), stir;
(4) all the other 60% proportional quantity deionized waters repeat rinse step (2) container that makes, and washing lotion are all returned in the reaction system of step (1), and it is transparent that the reaction system of step (1) continues stirring until dissolution homogeneity, namely makes finished product.
Beneficial effect of the present invention is as follows:
(1) the present invention is designed by special formulation, and obtained fully synthetic cutting fluid has excellent lubrication or antirust corrosion inhibition, high/low temperature good stability, not easy to change, human body skin is had no stimulation, can not cause lathe paint and peel off, biologically stable is good, and safety and environmental protection is non-stimulated.
(2) the present invention is not containing formaldehyde release-type and other types sterilant, system stable performance, and long-time storage color is not easily deepened, long service life, can not cause the situations such as the paint flake of human body skin stimulation and lathe.
(3) the present invention adopts Biostatic type self-emulsifying ester as emulsifying agent and lubrication or antirust main body, effectively compensate for the deficiency in the antirust or lubricity of conventional synthesis cutting fluid, has splendid high/low temperature stability, can select different alkali flexibly.
(4) tensio-active agent that the present invention selects is the low or anti-water hardness tolerance strong Biostatic type tensio-active agent of foam.Coordinate self-emulsifying ester to use, strengthen the emulsion dispersion ability of cutting fluid, improve the stability in hard water energy of its working fluid.
(5) rust-preventive agent of the present invention is one or more in binary or triprotic acid and carboxylate salt thereof or borate and modified carboxylate.Wherein modified carboxylate is novel carboxylic acid salt rust-preventive agent, compares common carboxylate salt, and foam is low or rust-preventing characteristic is stronger, compatible with most of lubricant, has excellent biologically stable.
(6) inhibiter of the present invention is one or more in siloxanes ketone or metasilicate or molybdate or benzotriazole and its derivative, wherein use siloxanes ketone inhibiter, be particularly suitable for the processing of aluminum alloy material, avoid the generation of finished surface hickie or color spot.
(7) special, most of functional additive of the present invention all has synergy in performance, and excellent cooling and extreme boundary lubrication performance, be particularly suitable for the processing of the difficult Material Processing such as Stainless Steel and superalloy.Not containing P or S or Cl, and additive mostly is Biostatic type, therefore controls microorganism without the need to interpolation sterilant specially, and environmental protection is non-stimulated.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is elaborated.
Embodiment 1
The high-effect fully synthetic cutting fluid of a kind of safety and environmental protection, is grouped into by the one-tenth of following weight percents:
Synthetic ester 21%
Tensio-active agent 6%
Rust-preventive agent 7%
PH value regulator 10%
Inhibiter 1%
Deionized water 55%
Wherein, synthetic ester is the mixture of plant oil modified high molecular polymerization ester and plant oil modified low molecule synthetic ester, and both mass ratioes are 2:1;
Tensio-active agent is fatty acid amide 5% or C
16-18soxylat A 25-7 1%;
Rust-preventive agent is DC11 2% or tribasic carboxylic acid 5%;
PH value regulator is monoisopropanolamine 3% or trolamine 7%;
Inhibiter is Starso 1%.
The preparation method of the high-effect fully synthetic cutting fluid of above-mentioned safety and environmental protection, comprises the following steps:
(1) in 40% group component deionized water, add monoisopropanolamine or the trolamine of group component, stir; Add Starso or DC11 or tribasic carboxylic acid salt to be again stirred to pressed powder and to dissolve completely;
(2) fatty acid amide or the C16-18 Soxylat A 25-7 of group component will be added after the plant oil modified high molecular polymerization ester of group component and low molecule synthetic ester mixing and stirring, stir 15 minutes to even;
(3) work in-process in step 2 are poured in the reaction system of step 1, stir;
(4) all the other 60% group component deionized waters repeat the container that rinse steps 2 make, and return in the reaction system of step 1 by washing lotion, and it is transparent that the reaction system of step 1 continues stirring until dissolution homogeneity, namely makes finished product.
Embodiment two
The high-effect fully synthetic cutting fluid of a kind of safety and environmental protection, is grouped into by the one-tenth of following weight percents:
Synthetic ester 25%
Tensio-active agent 8%
Rust-preventive agent 6%
PH value regulator 10%
Inhibiter 1.5%
Deionized water surplus
Wherein, synthetic ester is plant oil modified high molecular polymerization ester 15% or tricarboxymethyl propane oleate 10%;
Tensio-active agent is fatty acid amide 6% or isomeric alcohol polyethenoxy ether 2%;
Rust-preventive agent is borate 2% or modified carboxylate 4%;
PH value regulator is monoisopropanolamine 3% or trolamine 7%;
Inhibiter is siloxanes ketone 1.3% or benzotriazole 0.2%.
The preparation method of the high-effect fully synthetic cutting fluid of above-mentioned safety and environmental protection, comprises the following steps:
1 or in 40% group component deionized water, add monoisopropanolamine or the trolamine of group component, stir; Add group component siloxanes ketone or benzotriazole to be stirred to pressed powder and to dissolve completely, then add the borate of group component or modified carboxylate stirs;
2 or fatty acid amide or the isomeric alcohol polyethenoxy ether of group component will be added after the plant oil modified high molecular polymerization ester of group component and tricarboxymethyl propane oleate mixing and stirring, stir 15 minutes to evenly;
3 or work in-process in step 2 are poured in the reaction system of step 1, stir;
4 or all the other 60% group component deionized waters repeat the container that rinse steps 2 make, and return in the reaction system of step 1 by washing lotion, it is transparent that the reaction system of step 1 continues stirring until dissolution homogeneity, namely makes finished product.
Embodiment three
The high-effect fully synthetic cutting fluid of a kind of safety and environmental protection, is grouped into by the one-tenth of following weight percents:
Synthetic ester 20%
Tensio-active agent 5%
Rust-preventive agent 12%
PH value regulator 8%
Inhibiter 2.2%
Deionized water surplus
Wherein, synthetic ester is plant oil modified low molecule synthetic ester 10% or tricarboxymethyl propane oleate 10%;
Tensio-active agent is fatty acid amide 4% or isomeric alcohol polyethenoxy ether 1%;
Rust-preventive agent is borate 5% or DC11 2% or tribasic carboxylic acid salt 5%;
PH value regulator is diglycolamine 4% or trolamine 4%;
Inhibiter is benzotriazole 0.2% or siloxanes ketone 2%.
The preparation method of the high-effect fully synthetic cutting fluid of above-mentioned safety and environmental protection, comprises the following steps:
1 or in 40% group component deionized water, add diglycolamine and the trolamine mixing and stirring of group component; Add group component siloxanes ketone or benzotriazole or DC11 or tribasic carboxylic acid salt to be stirred to pressed powder and to dissolve completely, then the borate adding group component stirs;
2 or fatty acid amide or the isomeric alcohol polyethenoxy ether of group component will be added after the plant oil modified low molecule synthetic ester of group component and tricarboxymethyl propane oleate mixing and stirring, stir 15 minutes to evenly;
3 or work in-process in step 2 are poured in the reaction system of step 1, stir;
4 or all the other 60% group component deionized waters repeat the container that rinse steps 2 make, and return in the reaction system of step 1 by washing lotion, it is transparent that the reaction system of step 1 continues stirring until dissolution homogeneity, namely makes finished product.
Embodiment four
The high-effect fully synthetic cutting fluid of a kind of safety and environmental protection, is grouped into by the one-tenth of following weight percents:
Synthetic ester 28%
Tensio-active agent 8%
Rust-preventive agent 6%
PH value regulator 7%
Inhibiter 2%
Deionized water surplus
Wherein, synthetic ester is plant oil modified high molecular polymerization ester 15% or plant oil modified low molecule synthetic ester 5% or tricarboxymethyl propane oleate 8%;
Tensio-active agent is fatty acid amide 6% or isomeric alcohol polyethenoxy ether 1% or C16-18 Soxylat A 25-7 1%;
Rust-preventive agent is borate 2% or modified carboxylate 4%;
PH value regulator is trolamine 7%;
Inhibiter is benzotriazole 0.2% or siloxanes ketone 1.8%.
The preparation method of the high-effect fully synthetic cutting fluid of above-mentioned safety and environmental protection, comprises the following steps:
1 or in 40% group component deionized water, add the trolamine mixing and stirring of group component; Add group component siloxanes ketone or benzotriazole to be stirred to pressed powder and to dissolve completely, then add the borate of group component or modified carboxylate stirs;
2 or the fatty acid amide of group component or isomeric alcohol polyethenoxy ether or C will be added after the plant oil modified high molecular polymerization ester of group component or plant oil modified low molecule synthetic ester and tricarboxymethyl propane oleate mixing and stirring
16-18soxylat A 25-7, stirs 15 minutes to even;
3 or work in-process in step 2 are poured in the reaction system of step 1, stir;
4 or all the other 60% group component deionized waters repeat the container that rinse steps 2 make, and return in the reaction system of step 1 by washing lotion, it is transparent that the reaction system of step 1 continues stirring until dissolution homogeneity, namely makes finished product.
Checking: above embodiment is by contrasting from the correlated performance of other two kinds of different fully synthetic cutting fluids on the market, and correlation data is as follows:
According to above-mentioned data, the excellent product performance of above embodiment, is suitable for the processing of the non-ferrous metal such as processing and aluminium alloy of the difficult Material Processing such as Stainless Steel and superalloy.
Excellent lubricating properties of the present invention, the antirust cycle is long, and stoste high/low temperature stability is better, even if summer high temperature weather also can make the working fluid of diluent present water white state and not affect its visibility.PH value is relatively generally complete synthesis lower, avoids the skin irritation of high ph-values to workman and the corrodibility of aluminium alloy, and higher base number and system Biostatic type additive effectively suppress growing of microorganism.
Claims (7)
1. a high-effect safety and environmental protection fully synthetic cutting fluid, is characterized in that: be made up of the weight percent of following component:
Synthetic ester 20-30%
Tensio-active agent 4-8%
Rust-preventive agent 5-15%
PH value regulator 2-10%
Inhibiter 0-3%
Deionized water surplus.
2. high-effect safety and environmental protection fully synthetic cutting fluid according to claim 1, is characterized in that: described synthetic ester is one in the synthetic ester of Vegetable oil lipoprotein or animal grease or oleic acid ester and modification thereof or any several mixture.
3. high-effect safety and environmental protection fully synthetic cutting fluid according to claim 1, is characterized in that: described tensio-active agent is one in fatty acid amide or aliphatic acid polyethenoxy ether or fatty alcohol-polyoxyethylene ether or any several mixture.
4. high-effect safety and environmental protection fully synthetic cutting fluid according to claim 1, is characterized in that: described rust-preventive agent is by the one in binary or triprotic acid and carboxylate salt thereof or borate and modified carboxylate or any several mixture.
5. high-effect safety and environmental protection fully synthetic cutting fluid according to claim 1, is characterized in that: described pH value regulator is one in trolamine or diglycolamine or monoisopropanolamine or AMP-95 or any several mixture.
6. high-effect safety and environmental protection fully synthetic cutting fluid according to claim 1, is characterized in that: described inhibiter is one in siloxanes ketone or metasilicate or molybdate or benzotriazole and its derivative or any several mixture.
7. a preparation method for high-effect safety and environmental protection fully synthetic cutting fluid according to claim 1, is characterized in that: concrete steps are as follows:
(1) pH value regulator adding proportional quantity in 40% proportional quantity deionized water stirs; Add inhibiter or rust-preventive agent to be more successively stirred to pressed powder and to dissolve completely;
(2) by after the synthetic ester mixing and stirring of proportional quantity, add proportional quantity tensio-active agent, stir 15 minutes to even;
(3) work in-process in step (2) are poured in the reaction system of step (1), stir;
(4) all the other 60% proportional quantity deionized waters repeat rinse step (2) container that makes, and washing lotion are all returned in the reaction system of step (1), and it is transparent that the reaction system of step (1) continues stirring until dissolution homogeneity, namely makes finished product.
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| CN105001964A (en) * | 2015-07-02 | 2015-10-28 | 武汉航天航科石油化学有限公司 | Microemulsified cutting fluid |
| CN105754699A (en) * | 2016-03-28 | 2016-07-13 | 启东尤希路化学工业有限公司 | Water-based type lubricating antifriction agent for ultra-large type die-casting machine |
| CN106118809A (en) * | 2016-06-16 | 2016-11-16 | 黎啟明 | A kind of pivoting support antirust oil and preparation method |
| CN106520294A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | Castor-oil plant base environment-friendly cutting fluid composition |
| CN106566641A (en) * | 2016-10-28 | 2017-04-19 | 广东富行洗涤剂科技有限公司 | Totally-synthesized highlight waterborne cutting fluid |
| CN106675753A (en) * | 2016-12-26 | 2017-05-17 | 广东山之风环保科技有限公司 | Compound glass cutting fluid |
| CN107353995A (en) * | 2017-07-23 | 2017-11-17 | 武汉诺通润滑科技有限公司 | A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof |
| CN108410565A (en) * | 2018-02-09 | 2018-08-17 | 富兰克润滑科技（太仓）有限公司 | A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application |
| CN110923727A (en) * | 2019-12-12 | 2020-03-27 | 广东红日星实业有限公司 | Grinding fluid cleaning agent and preparation method thereof |
| CN112226270A (en) * | 2020-10-30 | 2021-01-15 | 安徽鑫诺斯润滑科技有限公司 | Universal type total-synthesis nonferrous metal cutting fluid and preparation method thereof |
| CN115029175A (en) * | 2022-06-09 | 2022-09-09 | 希玛石油制品（镇江）有限公司 | Zinc alloy cutting fluid free of phosphorus and boron and preparation method thereof |
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Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105001964A (en) * | 2015-07-02 | 2015-10-28 | 武汉航天航科石油化学有限公司 | Microemulsified cutting fluid |
| CN105754699B (en) * | 2016-03-28 | 2018-07-27 | 启东尤希路化学工业有限公司 | Ultra-large type die casting machine lubricates anti-friction composition with aqua type |
| CN105754699A (en) * | 2016-03-28 | 2016-07-13 | 启东尤希路化学工业有限公司 | Water-based type lubricating antifriction agent for ultra-large type die-casting machine |
| CN106118809A (en) * | 2016-06-16 | 2016-11-16 | 黎啟明 | A kind of pivoting support antirust oil and preparation method |
| CN106118809B (en) * | 2016-06-16 | 2019-03-22 | 泰伦特生物工程股份有限公司 | A kind of pivoting support antirust oil and preparation method |
| CN106566641A (en) * | 2016-10-28 | 2017-04-19 | 广东富行洗涤剂科技有限公司 | Totally-synthesized highlight waterborne cutting fluid |
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| CN106520294A (en) * | 2016-11-04 | 2017-03-22 | 广西大学 | Castor-oil plant base environment-friendly cutting fluid composition |
| CN106675753A (en) * | 2016-12-26 | 2017-05-17 | 广东山之风环保科技有限公司 | Compound glass cutting fluid |
| CN106675753B (en) * | 2016-12-26 | 2020-09-08 | 广东山之风环保科技有限公司 | Composite glass cutting fluid |
| CN107353995A (en) * | 2017-07-23 | 2017-11-17 | 武汉诺通润滑科技有限公司 | A kind of environment-friendly type fully synthetic cutting fluid and preparation method thereof |
| CN108410565A (en) * | 2018-02-09 | 2018-08-17 | 富兰克润滑科技（太仓）有限公司 | A kind of antibacterial complexing agent applied to metalworking fluid, preparation method and application |
| CN110923727A (en) * | 2019-12-12 | 2020-03-27 | 广东红日星实业有限公司 | Grinding fluid cleaning agent and preparation method thereof |
| CN112226270A (en) * | 2020-10-30 | 2021-01-15 | 安徽鑫诺斯润滑科技有限公司 | Universal type total-synthesis nonferrous metal cutting fluid and preparation method thereof |
| CN115029175A (en) * | 2022-06-09 | 2022-09-09 | 希玛石油制品（镇江）有限公司 | Zinc alloy cutting fluid free of phosphorus and boron and preparation method thereof |
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