CN102903917B - Aqueous electrolyte rechargeable zinc ion battery - Google Patents
Aqueous electrolyte rechargeable zinc ion battery Download PDFInfo
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- CN102903917B CN102903917B CN201210380142.6A CN201210380142A CN102903917B CN 102903917 B CN102903917 B CN 102903917B CN 201210380142 A CN201210380142 A CN 201210380142A CN 102903917 B CN102903917 B CN 102903917B
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- Prior art keywords
- zinc
- ion battery
- zinc ion
- battery
- electrolyte
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- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000003792 electrolyte Substances 0.000 title claims abstract description 20
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011701 zinc Substances 0.000 claims abstract description 17
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 9
- -1 copper (nickel) ferricyanide Chemical compound 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 3
- 239000011230 binding agent Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 11
- 239000011532 electronic conductor Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000007774 positive electrode material Substances 0.000 claims description 11
- 239000011258 core-shell material Substances 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 238000005260 corrosion Methods 0.000 claims description 7
- 230000007797 corrosion Effects 0.000 claims description 7
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- 239000002134 carbon nanofiber Substances 0.000 claims description 2
- 239000002041 carbon nanotube Substances 0.000 claims description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 4
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 239000010406 cathode material Substances 0.000 abstract 2
- 239000006183 anode active material Substances 0.000 abstract 1
- 239000010405 anode material Substances 0.000 abstract 1
- 239000006182 cathode active material Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- IYRDVAUFQZOLSB-UHFFFAOYSA-N copper iron Chemical compound [Fe].[Cu] IYRDVAUFQZOLSB-UHFFFAOYSA-N 0.000 description 9
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- 238000007599 discharging Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- PANJMBIFGCKWBY-UHFFFAOYSA-N iron tricyanide Chemical compound N#C[Fe](C#N)C#N PANJMBIFGCKWBY-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses an aqueous electrolyte rechargeable zinc ion battery, belonging to the technical field of battery preparation. The battery disclosed herein is characterized in that: the cathode active material mainly comprises zinc ions (Zn<2+>)- intercalated and -removed copper (nickel) ferricyanide, the anode active material mainly comprises zinc, and the electrolyte which is liquid or gel comprises soluble salts of zinc as the solute and water as the solvent. According to the invention, the zinc ions can be intercalated in the copper (nickel) ferricyanide cathode material lattices or be removed from the copper (nickel) ferricyanide cathode material lattices, simultaneously the anode material mainly comprising zinc is subject to oxidation or reduction, thus the battery has the characteristics of high specific capacity and rapid charging, and the battery can be widely applied in the fields of portable mobile terminal, equipment, miniature electric vehicle and automobile starting battery, etc.
Description
Technical field
The invention belongs to battery preparation technology field, be specifically related to a kind of aqueous solution electrolysis liquid Rechargeable zinc ion battery.
Background technology
Along with the fast development of global economy, supply and the environmental problem of fossil fuel become increasingly conspicuous, and therefore the comprehensive high-efficiency ground development and utilization of new green power has become guarantee national energy resource security, implements the key link of the national energy strategy of sustainable development.Compare primary cell, secondary cell repeatedly can carry out charge and discharge cycles, can make full use of raw material, so practical more economically.The rechargeable battery be most widely used at present is lithium ion battery.Lithium ion battery utilizes lithium ion as energy-accumulating medium store electrical energy, by the embedding of lithium ion between positive and negative pole material and the discharge and recharge deviating to realize battery.Along with the development of human society and the progress of science and technology, the kind of mobile electronic product and electric vehicle and quantity will constantly increase, also increase the demand of secondary cell, therefore development of new rechargeable battery is very necessary and significant thereupon.
Zinc is a kind of active metal, has cheapness, is easy to get, the feature such as process safety, therefore receives increasing concern using zinc metal as the secondary cell of negative material.It is positive pole with manganese dioxide that Chinese invention patent application CN101540417A makes public for the first time a kind of, take zinc as negative pole, with the Rechargeable zinc ion battery that the solution containing zinc ion is electrolyte, when charging, zinc ion deviates from manganese dioxide, through electrolyte then at cathode deposition, during electric discharge, there is reversible reaction.Owing to utilizing zinc and zinc ion as active material, electrode reaction is two electron reactions, and this battery has higher specific capacity.But because the lattice constant of manganese dioxide is less, the embedding of zinc ion is deviate from more difficult, cause battery embed at the zinc ion of charge/discharge and deviate from process rate comparatively slowly, make Zinc ion battery performance need to be improved further.
Therefore, in order to improve Rechargeable zinc ion battery performance further, find and novelly have good embedding/deviate from performance to zinc ion, cheap, the positive electrode of wide material sources becomes the important technology direction of improving Rechargeable zinc ion battery performance further.
Summary of the invention
The object of this invention is to provide a kind of aqueous solution electrolysis liquid Rechargeable zinc ion battery.
A kind of aqueous solution electrolysis liquid Rechargeable zinc ion battery, this battery is made up of positive pole, negative pole, diaphragm material between the above two and the electrolyte with ionic conductivity; Wherein positive pole comprises the positive electrode active materials on collector and collector, and negative pole comprises the negative active core-shell material on collector and collector; Positive electrode active materials is KMFe (CN)
6the film material that powder, electronic conductor and binding agent are made; Negative active core-shell material is the film material that zinc powder, corrosion inhibiter, electronic conductor and binding agent are made; Electrolyte be with the soluble-salt of zinc be solute, water be solvent the liquid state with ionic conductivity or gel state material, its pH value is in 4 ~ 7.
KMFe (CN)
6in M be Cu or Ni element.
In positive electrode active materials, the addition of electronic conductor, binding agent is respectively less than 10% of positive electrode active materials quality.
In negative active core-shell material, the addition of corrosion inhibiter is less than 1% of negative active core-shell material quality, and the addition of electronic conductor, binding agent is respectively less than 10% of negative active core-shell material quality.
Above-mentioned electrodes conduct agent is graphite, carbon black, acetylene black, carbon nano-fiber or carbon nano-tube.
Above-mentioned corrosion inhibiter is the oxide of indium or hydroxide or copper.
Above-mentioned binding agent is polytetrafluoroethylene, poly-inclined tetrafluoroethene or cellulose.
The soluble-salt of above-mentioned zinc is zinc nitrate, zinc sulfate or zinc chloride.
The Rechargeable zinc ion battery that the present invention proposes, its battery structure can be button, column type or square structure.
Beneficial effect of the present invention is: 1) adopt zinc metal as battery cathode, and its activity is high, cheap, be easy to get, pollution-free; 2) utilize that the insoluble iron cyanide is cheap as positive electrode, preparation technology is simple; 3) to adopt containing the aqueous solution of zinc ion as electrolyte, prepare simple and easy, do not fire, nontoxic; 4) Rechargeable zinc ion battery of the present invention, utilize the reversible embedding of zinc ion in positive electrode lattice or deviate from, negative material simultaneously based on Zn-ef ficiency carries out the energy storage mechnism be oxidized or zinc ion reduces in negative terminal surface, and have employed special electrolyte, this battery has the feature of specific capacity height and quickly-chargeable, and it has the advantages such as manufacturing process is simple, cost is low, have extended cycle life simultaneously.
Accompanying drawing explanation
Fig. 1 is that iron copper cyanider electrode is at 1mol L
-1znSO
4the cyclic voltammogram of electrolyte.
Fig. 2 is that Rechargeable zinc ion battery is at 200 mAg
-1first time charging and discharging curve under current density.
Fig. 3 is Rechargeable zinc ion battery at 200 mAg
-1cycle charge-discharge curve under current density.
Fig. 4 is Rechargeable zinc ion battery at 150 mAg
-1charging and discharging curve under current density.
Embodiment
Embodiment 1
Iron copper cyanider KCuFe (CN)
6preparation
The potassium ferricyanide solution of certain density copper sulphate (copper chloride, zinc sulfate, zinc chloride, nickelous sulfate, nickel chloride etc.) solution and same concentrations is dropwise instilled in the deionized water stirred continuously simultaneously, after question response is complete, by be mixed with brown precipitate suspension-turbid liquid through ultrasonic oscillation after 30 minutes, leave standstill 8 hours, then sediment is leached, and after repeatedly cleaning with deionized water, put into baking oven and dry, obtained iron copper cyanider powder.
Iron copper cyanider, electronic conductor graphite powder and binding agent are gathered after inclined tetrafluoroethene mixes with the mass ratio of 18:1:1 and be coated on carbon element collector, be cut into a certain size, obtain iron copper cyanider electrode slice in oven for drying.Single electrode test adopts iron copper cyanider electrode slice to be work electrode, is auxiliary electrode, detects using saturated calomel electrode as reference electrode with metal foil electrodes.Iron copper cyanider electrode is at 1mol L
-1znSO
4as shown in Figure 1, sweep speed is 10mV s to cyclic voltammogram in the aqueous solution
-1, can find out and have an oxidation peak and a reduction peak to occur, corresponding to zinc ion deviating from and embedding in iron copper cyanider lattice.
Embodiment 2
Zinc powder, electronic conductor graphite powder and binding agent are gathered after inclined tetrafluoroethene mixes with the mass ratio of 18:1:1 and be coated on carbon element collector, be cut into a certain size, obtain zinc electrode in oven for drying.The iron copper cyanider electrode prepared with embodiment 1 is for positive pole, and take zinc electrode as negative pole, electrolyte is 1mol L
-1znSO
4the aqueous solution is assembled into the Rechargeable zinc ion battery of flexible package.
Obtained Zinc ion battery is at 200 mAg
-1constant current first time charging and discharging curve is shown in Fig. 2 (with positive electrode active materials Mass Calculation), and as shown in the figure, between voltage range 2.0 ~ 2.2V, occurred a charging platform, had a discharge platform clearly at about 0.75V, coulombic efficiency is 81%.Obtained Zinc ion battery is at 200 mAg
-1as shown in Figure 3, as seen from the figure, made Zinc ion battery has good cycle characteristics to constant current charge-discharge cyclic curve (with positive electrode active materials Mass Calculation).If through structure optimization, this battery charging and discharging characteristic and cyclical stability also will have obvious lifting.
Embodiment 3
Zinc powder, conductive agent graphite powder, binding agent being gathered after inclined tetrafluoroethene and corrosion inhibiter copper powder mix with the mass ratio of 83:8:8:1 is coated on carbon element collector, in oven for drying, is cut into a certain size, obtained zinc electrode.The iron copper cyanider electrode prepared with embodiment 1 is for positive pole, and take zinc electrode as negative pole, electrolyte is 1mol L
-1znSO
4the aqueous solution is assembled into the Rechargeable zinc ion battery of flexible package.Obtained Zinc ion battery is at 150mA g
-1constant current charge-discharge curve (with positive electrode active materials Mass Calculation) is shown in Fig. 4, and as shown in the figure, between voltage range 2.1 ~ 2.2V, occurred a charging platform, had a discharge platform clearly at about 0.75V, coulombic efficiency is 78%.If through structure optimization, this battery charging and discharging characteristic and cyclical stability also will have obvious lifting.
Claims (7)
1. an aqueous solution electrolysis liquid Rechargeable zinc ion battery, this battery is made up of positive pole, negative pole, diaphragm material between the above two and electrolyte; Wherein positive pole comprises the positive electrode active materials on collector and collector, and negative pole comprises the negative active core-shell material on collector and collector, it is characterized in that, positive electrode active materials is KMFe (CN)
6the film material that powder, electronic conductor and binding agent are made; Negative active core-shell material is the film material that zinc powder, corrosion inhibiter, electronic conductor and binding agent are made; Electrolyte be with the soluble-salt of zinc be solute, the water liquid state with ionic conductivity that is solvent, its pH value is 4 ~ 7; Described KMFe (CN)
6in M be Cu or Ni element.
2. electrolyte Rechargeable zinc ion battery according to claim 1, is characterized in that, in positive electrode active materials, the addition of electronic conductor, binding agent is respectively less than 10% of positive electrode active materials quality.
3. electrolyte Rechargeable zinc ion battery according to claim 1, it is characterized in that, in negative active core-shell material, the addition of corrosion inhibiter is less than 1% of negative active core-shell material quality, and the addition of electronic conductor, binding agent is respectively less than 10% of negative active core-shell material quality.
4. electrolyte Rechargeable zinc ion battery according to claim 1, is characterized in that, described electronic conductor is graphite, carbon black, carbon nano-fiber or carbon nano-tube.
5. electrolyte Rechargeable zinc ion battery according to claim 1, is characterized in that, described corrosion inhibiter is the oxide of indium or the hydroxide of indium or copper.
6. electrolyte Rechargeable zinc ion battery according to claim 1, is characterized in that, described binding agent is polytetrafluoroethylene, Kynoar or cellulose.
7. electrolyte Rechargeable zinc ion battery according to claim 1, is characterized in that, the soluble-salt of described zinc is zinc nitrate, zinc sulfate or zinc chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210380142.6A CN102903917B (en) | 2012-10-09 | 2012-10-09 | Aqueous electrolyte rechargeable zinc ion battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210380142.6A CN102903917B (en) | 2012-10-09 | 2012-10-09 | Aqueous electrolyte rechargeable zinc ion battery |
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| Publication Number | Publication Date |
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| CN102903917A CN102903917A (en) | 2013-01-30 |
| CN102903917B true CN102903917B (en) | 2015-04-15 |
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| CN201210380142.6A Expired - Fee Related CN102903917B (en) | 2012-10-09 | 2012-10-09 | Aqueous electrolyte rechargeable zinc ion battery |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103972479A (en) * | 2014-05-27 | 2014-08-06 | 中国科学院宁波材料技术与工程研究所 | Ion battery |
| CN103972582B (en) * | 2014-05-27 | 2016-03-30 | 中国科学院宁波材料技术与工程研究所 | A kind of secondary cell |
| BR112016029592A2 (en) * | 2014-06-16 | 2017-08-22 | Ttsb S R L | rechargeable battery containing zinc ions |
| GB2553128B (en) | 2016-08-24 | 2020-02-26 | Dst Innovations Ltd | Rechargeable power cells |
| CN107516735B (en) * | 2017-08-21 | 2019-08-23 | 湖南科技大学 | A kind of secondary iron base composite material-iron copper cyanider battery and its manufacturing method |
| CN114335518A (en) * | 2017-10-30 | 2022-04-12 | 宁德时代新能源科技股份有限公司 | Positive active material, preparation method thereof and sodium ion battery |
| CN108448168B (en) * | 2018-03-14 | 2021-01-15 | 华中科技大学 | Electrolyte for water-based zinc ion secondary battery and preparation method and application thereof |
| CN110364692A (en) * | 2018-04-10 | 2019-10-22 | 中国科学院上海硅酸盐研究所 | Composite zinc cathode with multiphase material |
| CN110364771A (en) * | 2018-04-10 | 2019-10-22 | 中国科学院上海硅酸盐研究所 | A kind of water system zinc ion soft-package battery and preparation method thereof |
| CN108847476A (en) * | 2018-06-07 | 2018-11-20 | 哈尔滨工业大学（威海） | Preparation method of zinc ion battery anode |
| CN111653788A (en) * | 2020-07-14 | 2020-09-11 | 无锡永华电池有限公司 | Alkaline battery negative electrode material |
| CN112164802A (en) * | 2020-09-30 | 2021-01-01 | 国网上海市电力公司 | Application of metal material and zinc-based battery taking metal as negative electrode |
| CN113097518B (en) * | 2021-03-18 | 2024-06-04 | 苏州柔能纳米科技有限公司 | Electrolyte for flexible neutral zinc-manganese battery and preparation method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6558849B2 (en) * | 2001-04-19 | 2003-05-06 | Zinc Matrix Power, Inc. | Battery separator with copper-containing inorganic salt |
| CN102097661A (en) * | 2009-12-11 | 2011-06-15 | 清华大学深圳研究生院 | Rechargeable zinc ion battery using zinc manganate as anode |
| JP5999675B2 (en) * | 2010-08-30 | 2016-09-28 | 国立研究開発法人産業技術総合研究所 | Electrode material for lithium ion secondary battery using defect-free Prussian blue analogue |
| CN102522553A (en) * | 2011-12-31 | 2012-06-27 | 武汉大学 | Sodium ion battery positive material |
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